last modified：2026/03/14
Professor MATSUO Junichi
Faculty, Affiliation
Faculty of Pharmacy, Institute of Medical, Pharmaceutical and Health Sciences
College and School Educational Field
Division of Frontier Engineering, Graduate School of Natural Science and Technology
Division of Natural System, Graduate School of Natural Science and Technology
School of Pharmaceutical Sciences, College of Medical, Pharmaceutical and Health Sciences
School of Pharmacy, College of Medical, Pharmaceutical and Health Sciences
Laboratory
Synthetic Organic Chemistry TEL:076-234-4439 FAX:076-234-4439
Academic Background
【Academic background(Doctoral/Master's Degree)】
The University of Tokyo Doctor Graduate School, Division of Pharmaceutical Sciences 199903 Completed
【Academic background(Bachelor's Degree)】
The University of Tokyo 199403
【Degree】
Ph.D.
Career
Japan Science and Technology Agency Researcher(1999/04/01-2000/03/31)
Tokyo University of Science Assistant Professor(2000/04/01-2002/03/31)
Kitasato Institute Resercher(2002/04/01-2005/08/31)
Kanazawa University(2005/09/01-)
Year & Month of Birth
1971/11
Academic Society
Award
○BCSJ Award(2002/02)
○Incentive Award in Synthetic Organic Chemistry(2004/02)
○Ninomiya Award(2004/11)
○The Pharmaceutical Society of Japan Award for Young Scientists(2008/03)
○Daiichi-Sankyo Award in Synthetic Organic Chemisry(2009/02)
Specialities
Chemical pharmacy
Speciality Keywords
Organic Reactions, Organic Synthesis
Research Themes
Development of New Organic Reactions
Total Synthesis of Bioactive Compounds
Books
Papers
- A Novel Chiral PentamineLigand for Enantioselective alpha-Alkylation of Acyclic Lithium Amide Enolates. Optimization of Chiral Ligands for Asymmetric Reactions Using Solid-Phase Organic Synthesis Kazunori Odashima, Shu Kobayashi ORGANIC LETTERS 1 345-348 1999
- Lewis Acid Catalyst in Supercritical Carbon Dioxide. Use of Scandium Tris(heptadecafluorooctanesulfonate) as a Lewis Acid Catalyst in Diels-Alder and Aza Diels-Alder Reactions Takehiro Tsuchiya, Kazurori Odashima, and Shu Kobayashi CHEMISTRY LETTERS 178-179 2000
- Gallium Nonafluorobutanesulfonate as an Efficient Catalyst in Friedel-Crafts Acylation Kazunori Odashima, and Shu Kobayashi SYNLETT 403-405 2000
- A New and One-Pot Synthesis of alpha,beta-Unsaturated Ketones by Dehydrogenation of Various Ketones with N-tert-Butyl Phenylsulfinimidoyl Chloride Teruaki Mukaiyama, and Hideo Kitagawa CHEMISTRY LETTERS 1250-1251 2000
- Aromatic iodination with iodine monochloride by using a catalytic amount of ferrocenium tetrakis(3,5-bis(trifluoromethyl)phenyl)borate Teruaki Mukaiyama, Hideo Kitagawa TETRAHEDRON LETTERS 41 9383-9386 2000
- Benzylation of Alcholic Hydroxyl Groups with Benzyl Mesylate by Using a Catalytic Amount of Lithium Tetrakis(pentafluorophenyl)borate in the Coexistence of Lithium Triflate and Magnesium Oxide Masakazu Nakano, and Teruaki Mukaiyama CHEMISTRY LETTERS 1352-1353 2000
- A Mild and Efficient Oxidation of Alcohols with N-tert-Butylphenylsulfinimidoyl Chloride in the Coexistence of Zinc Oxide Hideo Kitagawa, Daisuke Iida, and Teruaki Mukaiyama CHEMISTRY LETTERS 150-151 2001
- Catalytic Friedel-Crafts Acylation of Aniline Derivatives Shu Kobayashi, Ichiro Komoto ADVANCED SYNTHESIS & CATALYSIS 343 71-74 2001
- Oxidation of Various Secondary Amines to Imines with N-tert-Butylphenylsulfinimidoyl Chloride Teruaki Mukaiyama, Asahi Kawana, Yoshio Fukuda CHEMISTRY LETTERS 390-391 2001
- An Efficient Method for the p-Methoxybenzylation of Hydroxy Groups with 2-(4-methoxybenzyloxy)-3-nitropyridine Masakazu Nakano, Wataru Kikuchi, and Teruaki Mukaiyama CHEMISTRY LETTERS 424-425 2001
- Oxidation of Primary Alkyl Triflates to the Corresponding Aldehydes via Alkoxy(N-tert-butylamino)(methyl)sulfonium Triflates Hideo Kitagawa, Daisuke Iida, and Teruaki Mukaiyama CHEMISTRY LETTERS 580-581 2001
- Oxidative Deamination of Various Primary Amines to the Corresponding Carbonyl Compounds by Using N-tert-Butylphenylsulfinimidoyl Chloride Asahi Kawana, Yoshio Fukuda, and Teruaki Mukaiyama CHEMISTRY LETTERS 712-713 2001
- Catalytic Oxidation of Various Alcohols to the Corresponding Carbonyl Compounds with N-Chlorosuccinimide Using a Catalytic Amount of Sulfenamide Teruaki Mukaiyama, Daisuke Iida, and Hideo Kitagawa CHEMISTRY LETTERS 846-847 2001
- A convenient method for the synthesis of nitrones by oxidation of N,N-disubstituted hydroxylamines with N-t-butylbenzenesulfinimidoyl chloride Tsuyoshi Shibata, Hideo Kitagawa, and Teruaki Mukaiyama ARKIVOC 58-65 2001
- Scandium Perfluoroalkanesulfonate-Catalyzed Diels-Alder Reactions in an Organic Solvent Shu Kobayashi, Takehiro Tsuchiya, Ichiro Komoto JOURNAL OF ORGANOMETALLIC CHEMISTRY 624 392-394 2001
- A New Method for Oxidation of Various Alcohols to the Corresponding Carbonyl Compounds by Using N-t-Butylbenzenesulfinimidoyl Chloride Daisuke Iida, Kazuya Tatani, and Teruaki Mukaiyama BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 75 223-234 2002
- Polymer-supported Sulfinimidoyl Chloride as a Useful Reagent for Oxidation of Various Alcohols to the Corresponding Carbonyl Compounds Asahi Kawana, Khanitha Pudhom, and Teruaki Mukaiyama CHEMISTRY LETTERS 250-251 2002
- Efficient Method for the Preparation of Aromatic Bromides and Iodides by Ferrocenium Tetrakis[3,5-bis(trifluoromethyl)phenyl]borate-Catalyzed Halogenation with Bromine and Iodine Monochloride Hideo Kitagawa, Tsuyoshi Shibata, and Teruaki Mukaiyama BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 75 339-345 2002
- Catalytic Friedel-Crafts Acylation of Heteroaromatics Ichiro Komoto, Shu Kobayashi TOPICS IN CATALYSIS 19 43-47 2002
- Trimethylaluminum-promoted 1,4-Addition Reaction of Cuprates to Six or Eight-membered Cyclic 2-Hydroxylmethyl Enones Khanitha Pudhom, and Teruaki Mukaiyama HETEROCYCLES 59 445-451 2003
- N-t-Butylbenzenesulfenamide-catalyzed Oxidation of Alcohols to the Corresponding Carbonyl Compounds with N-Chlorosuccinimide Daisuke Iida, and Teruaki Mukaiyama TETRAHEDRON 59 6739-6750 2003
- Sulfenamide-catalyzed Oxidation of Primary and Secondary Alcohols with Molecular Bromine Asahi Kawana, Hiroyuki Yamanaka, and Teruaki Mukaiyama CHEMISTRY LETTERS 32 182-183 2003
- A Convenient Method for the Synthesis of 2-Arylaziridines from Styrene Derivatives via 2-Arylethenyl(diphenyl)sulfonium Salts Hiroyuki Yamanaka, Asahi Kawana, and Teruaki Mukaiyama CHEMISTRY LETTERS 32 392-393 2003
- Polymer-supported Sulfinimidoyl Chlorides: A Convenient Reagent for Oxidation of Alcohols Asahi Kawana, Hiroyuki Yamanaka, and Hiroaki Kamiyama BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 76 1433-1440 2003
- A Convenient Method for the Synthesis of beta,gamma-Unsaturated Amines from Alkenes via alpha,beta-Unsaturated Diphenylsulfonium Salts Hiroyuki Yamanaka, Asahi Kawana, and Teruaki Mukaiyama CHEMISTRY LETTERS 32 626-627 2003
- New Methods for the Preparations of 2-Arylaziridines, alpha-imidostyrenes, and allylamines from olefins via diphenylvinylsulfonium Triflates Hiroyuki Yamanaka, Asahi Kawana, and Teruaki Mukaiyama ARKIVOC 42-65 2004
- A Facile One-pot Benzylation of Sodium Enolates Using Trifluoromethansulfonic Anhydride and Diphenyl Sulfoxide Tomofumi Takuwa, Jim Yoshitaka Onishi, and Teruaki Mukaiyama CHEMISTRY LETTERS 33 8-9 2004
- Stereoselective Construction of BC-ring unit of 19-Hydroxytaxol by Samarium(II) Iodide-mediated Double Aldol Cyclizations Yasuyuki Ogawa, Khanitha Pudhom, and T. Mukaiyama CHEMISTRY LETTERS 33 124-125 2004
- Synthesis of cis-2-Fluorocyclopropylamine by Stereoselective Cyclopropanation Under Phase-transfer Conditions Yu-ichirou Tani, and Yu-ichirou Hayakawa CHEMISTRY LETTERS 33 464-467 2004
- Stereoselective Synthesis of 19-Hydroxytaxoid Using Intramolecular Pinacol Coupling Reaction Teruaki Mukaiyama, Yasuyuki Ogawa, Kiichi Kuroda, CHEMISTRY LETTERS 33 1412-1413 2004
- One-pot dehydrogenation of carboxylic acid derivatives to alpha,beta-unsaturated carbonyl compounds under mild conditions Yayoi Aizawa TETRAHEDRON LETTERS 46 407-410 2005
- Stereoselective Synthesis of 19-Hydroxytaxoid by Utilizing Samarium(II) Iodide-Mediated Double Aldol Cyclization Yasuyuki Ogawa, Kiichi Kuroda, and Teruaki Mukaiyama BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 78 677-697 2005
- One-pot beta-substitution of enones with alkyl groups to beta-alkyl enones Yayoi Aizawa CHEMICAL COMMUNICATIONS 2399-2401 2005
- Catalytic and stereoselective glycosylation with glycosyl N-trichloroacetylcarbamate Tatsuya Shirahata, and Satoshi Omura TETRAHEDRON LETTERS 47 267-271 2006
- Radical Cyclizations of N-Allylic or N-vinylic alpha,alpha,alpha-Trichloroacetamides in 1,4-Dimethylpiperazine Hiroyuki Ishibashi, Shigeki Haruki, Masahiko Uchiyama, Osamu Tamura TETRAHEDRON LETTERS 47 6263-6266 2006
- A mild and convenient synthesis of N-carbobenzyloxy ketimines Yumi Tanaki, Aimi Kido and Hiroyuki Ishibashi CHEMICAL COMMUNICATIONS 2896-2898 2006
- Stereoselective Synthesis of trans-3a-Aryloctahydro-indoles Using Cyclization of N-Vinylic alpha-(Methylthio)acetamides Miho Saito, Masahiko Uchiyama, and Hiroyuki Ishibashi HETEROCYCLES 68 69-72 2006
- Oxidative Mannich Reaction of N-Carbobenzyloxy Amines with 1,3-Dicarbonyl Compounds Yumi Tanaki, Hiroyuki Ishibashi ORGANIC LETTERS 8 4371-4374 2006
- Mild preparation of alkenes from phenyl sulfides: one-pot elimination of phenylthio group via sulfilimine at ambient temperature Takaaki Kozai, and Hiroyuki Ishibashi ORGANIC LETTERS 8 6095-6098 2006
- One-pot oxidative Mannich-type reaction of lactams with alkyl malonates Yumi Tanaki, and Hiroyuki Ishibashi TETRAHEDRON LETTERS 48 3233-3236 2007
- One-pot carbon-carbon bond formation at the beta-position of cyclic ketones: oxidative Michael addition with alkyl malonates Hiroki Kawai, and Hiroyuki Ishibashi TETRAHEDRON LETTERS 48 3155-3158 2007
- Stereoselective synthesis of cis and trans-fused 3a-aryloctahydroindoles using cyclization of N-vinylic alpha-(methylthio)acetamides: synthesis of (-)-mesembrane Miho Saito, and Hiroyuki Ishibashi TETRAHEDRON 63 4865-4873 2007
- A practical synthesis of enantiopure N-carbobenzyloxy-N'-phthaloyl-cis-1,2-cyclohexanediamine by asymmetric reductive amination and the Curtius rearrangement Masahiko Okano, Kosuke Takeuchi, Hiroyuki Tanaka and Hiroyuki Ishibashi TETRAHEDRON-ASYMMETRY 18 1906-1910 2007
- Synthesis of 13a-methylphenanthroindolizidines using radical cascade cyclization: synthetic studies towards (rac)-hypoestestatin 1 Kosuke Takeuchi, Atsuko Ishita, and Hiroyuki Ishibashi TETRAHEDRON 63 11101-11107 2007
- One-pot oxidative carbon-carbon bond formation of 3-benzylic and 3-allylic indoles with carbon nucleophiles Yumi Tanaki and Hiroyuki Ishibashi TETRAHEDRON 64 5262-5267 2008
- Oxazaborolidine-catalyzed enantioselective reduction of alpha-methylene ketones to allylic alcohols Takaaki Kozai, Osamu Nishikawa, Yu Hattori and Hiroyuki Ishibashi JOURNAL OF ORGANIC CHEMISTRY 73 6902-6904 2008
- Lewis Acid-Catalyzed Intermolecular [4+2] Cycloaddition of 3-Alkoxycyclobutanones to Aldehydes and Ketones Shun Sasaki, Hiroyuki Tanaka, and Hiroyuki Ishibashi JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 130 11600-11601 2008
- A novel chiral pentamine ligand for enantioselective alpha-alkylation of acyclic lithium amide enolates. Optimization of chiral ligands for asymmetric reactions using solid-phase organic synthesis J Matsuo,K Odashima,S Kobayashi ORGANIC LETTERS 1 2 345 1999/07
- Enantioselective alpha-alkylation of phenylacetic acid using a chiral bidentate lithium amide as a chiral auxiliary J Matsuo,K Koga CHEMICAL & PHARMACEUTICAL BULLETIN 45 12 2122 1997/12
- Lewis acid catalysis in supercritical carbon dioxide. Use of scandium tris(heptadecafluorooctanesulfonate) as a Lewis acid catalyst in Diels-Alder and aza Diels-Alder reactions J Matsuo,T Tsuchiya,K Odashima,S Kobayashi CHEMISTRY LETTERS 178-179 2 178 2000/02
- Enantioselective alkylation of lactams and lactones via lithium enolate formation using a chiral tetradentate lithium amide in the presence of lithium bromide J Matsuo,S Kobayashi,K Koga TETRAHEDRON LETTERS 39 52 9723 1998/12
- Lithium tetrakis(pentafluorophenyl)borate-catalyzed Friedel-Crafts benzylation reactions T Mukaiyama,M Nakano,W Kikuchi,J Matsuo CHEMISTRY LETTERS 1010-1011 9 1010 2000/09
- Aldol reaction of enol esters catalyzed by cationic species paired with tetrakis(pentafluorophenyl)borate M Yanagisawa,T Shimamura,D Iida,J Matsuo,T Mukaiyama CHEMICAL & PHARMACEUTICAL BULLETIN 48 11 1838 2000/11
- New methods for the preparations of 2-arylaziridines, alpha-imidostyrenes, and allylamines from olefins via diphenylvinylsulfonium triflates H Yamanaka,J Matsuo,A Kawana,T Mukaiyama ARKIVOC 42-65 42 2004
- Gallium nonafluorobutanesulfonate as an efficient catalyst in Friedel-Crafts acylation J Matsuo,K Odashima,S Kobayashi SYNLETT 403-405 3 403 2000/03
- A new and efficient method for oxidation of various alcohols by using N-tert-butyl phenylsulfinimidoyl chloride T Mukaiyama,J Matsuo,M Yanagisawa CHEMISTRY LETTERS 1072-1073 9 1072 2000/09
- Friedel-Crafts reactions catalyzed by rare earth metal trifluoromethanesulfonates A Kawada,S Mitamura,J Matsuo,T Tsuchiya,S Kobayashi BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 73 10 2325 2000/10
- A new and one-pot synthesis of alpha,beta-unsaturated ketones by dehydrogenation of various ketones with N-tert-butyl phenylsulfinimidoyl chloride T Mukaiyama,J Matsuo,H Kitagawa CHEMISTRY LETTERS 1250-1251 11 1250 2000/11
- N-tert-butylbenzenesulfenamide-catalyzed oxidation of alcohols to the corresponding carbonyl compounds with N-chlorosuccinimide J Matsuo,D Iida,H Yamanaka,T Mukaiyama TETRAHEDRON 59 35 6739 2003/08
- A convenient method for the synthesis of beta,gamma-unsaturated Amines from alkenes via alpha,beta-unsaturated diphenylsulfonium salts H Yamanaka,J Matsuo,A Kawana,T Mukaiyama CHEMISTRY LETTERS 32 7 626 2003/07
- Sulfenamide-catalyzed oxidation of primary and secondary alcohols with molecular bromine J Matsuo,A Kawana,H Yamanaka,T Mukaiyama CHEMISTRY LETTERS 32 2 182 2003/02
- Efficient method for the preparation of aromatic bromides and iodides by ferrocenium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate-catalyzed halogenation with bromine and iodine monochloride H Kitagawa,T Shibata,J Matsuo,T Mukaiyama BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 75 2 339 2002/02
- Polymer-supported sulfinimidoyl chloride as a useful reagent for oxidation of various alcohols to the corresponding carbonyl compounds J Matsuo,A Kawana,K Pudhom,T Mukaiyama CHEMISTRY LETTERS 250-251 2 250 2002/02
- A new method for oxidation of various alcohols to the corresponding carbonyl compounds by using N-t-butylbenzenesulfinimidoyl chloride J Matsuo,D Iida,K Tatani,T Mukaiyama BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 75 2 223 2002/02
- Catalytic Friedel-Crafts acylation of heteroaromatics Komoto, I,J Matsuo,S Kobayashi TOPICS IN CATALYSIS 19 1 43 2002
- Oxidative deamination of various primary amines to the corresponding carbonyl compounds by using N-tert-butylphenylsulfinimidoyl chloride J Matsuo,A Kawana,Y Fukuda,T Mukaiyama CHEMISTRY LETTERS 712-713 7 712 2001/07
- An efficient method for the p-methoxybenzylation of hydroxy groups with 2-(4-methoxybenzyloxy)-3-nitropyridine M Nakano,W Kikuchi,J Matsuo,T Mukaiyama CHEMISTRY LETTERS 424-425 5 424 2001/05
- Oxidation of various secondary amines to imines with N-tert-butylphenylsulfinimidoyl chloride T Mukaiyama,A Kawana,Y Fukuda,J Matsuo CHEMISTRY LETTERS 390-391 5 390 2001/05
- Scandium perfluoroalkanesulfonate-catalyzed Diels-Alder reactions in an organic solvent S Kobayashi,T Tsuchiya,Komoto, I,J Matsuo JOURNAL OF ORGANOMETALLIC CHEMISTRY 624 1-2 392 2001/04
- A mild and efficient oxidation of alcohols with N-tert-butylphenylsulfinimidoyl chloride in the coexistence of zinc oxide J Matsuo,H Kitagawa,D Iida,T Mukaiyama CHEMISTRY LETTERS 150-151 2 150 2001/02
- A convenient method for the synthesis of nitrones by oxidation of N,N-disubstituted hydroxylamines with N-t-butylbenzenesulfinimidoyl chloride ARKIVOC 58-65 2001
- Catalytic Friedel-Crafts acylation of aniline derivatives S Kobayashi,Komoto, I,J Matsuo ADVANCED SYNTHESIS & CATALYSIS 343 1 71 2001/01
- Aromatic iodination with iodine monochloride by using a catalytic amount of ferrocenium tetrakis(3,5-bis(trifluoromethyl)phenyl)borate T Mukaiyama,H Kitagawa,J Matsuo TETRAHEDRON LETTERS 41 49 9383 2000/12
- Benzylation of alcoholic hydroxyl groups with benzyl mesylate by using a catalytic amount of lithium tetrakis(pentafluorophenyl)borate in the coexistence of lithium triflate and magnesium oxide M Nakano,J Matsuo,T Mukaiyama CHEMISTRY LETTERS 1352-1353 12 1352 2000/12
- Catalytic oxidation of various alcohols to the corresponding carbonyl compounds with N-chlorosuccinimide using a catalytic amount of sulfenamide T Mukaiyama,J Matsuo,D Iida,H Kitagawa CHEMISTRY LETTERS 846-847 8 846 2001/08
- Polymer-supported sulfinimidoyl chlorides: A convenient reagent for oxidation of alcohols J Matsuo,A Kawana,H Yamanaka,H Kamiyama BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 76 7 1433 2003/07
- Oxidation of primary alkyl triflates to the corresponding aldehydes via alkoxy(N-tert-butylamino)(methyl)sulfonium triflates H Kitagawa,J Matsuo,D Iida,T Mukaiyama CHEMISTRY LETTERS 580-581 6 580 2001/06
- Stereoselective construction of BC-ring unit of 19-hydroxytaxol by samarium(II) iodide-mediated double aldol cyclization J Matsuo,Y Ogawa,K Pudhom,T Mukaiyama CHEMISTRY LETTERS 33 2 124 2004/02
- A practical synthesis of enantiopure N-carbobenzyloxy-N '-phthaloyl-Cis-1,2-cyclohexanediamine by asymmetric reductive amination and the Curtius rearrangement Jun-Ichi Matsuo,Masahiko Okano,Kosuke Takeuchi,Hiroyuki Tanaka,Hiroyuki Ishibashi TETRAHEDRON-ASYMMETRY 18 16 1906 2007/08
- Asymmetric synthesis of 2-alkyl-4-hydroxycyclohex-2-en-1-ones by scandium(III) triflate-catalyzed fragmentation of 2-alkyl-3-iodo-1-oxocyclohexan-2,4-carbolactones Jun-ichi Matsuo,Mizuki Kawano,Kosuke Takeuchi,Hiroyuki Tanaka,Hiroyuki Ishibashi TETRAHEDRON LETTERS 50 17 1917 2009/04
- Diels-Alder reaction of eight-membered cyclic siloxydienes Jun-ichi Matsuo,Shun Sasaki,Takaya Hoshikawa,Hiroyuki Ishibashi TETRAHEDRON 64 49 11224 2008/12
- Lewis acid-catalyzed intermolecular [4+2] cycloaddition of 3-alkoxycyclobutanones to aldehydes and ketones Jun-ichi Matsuo,Shun Sasaki,Hiroyuki Tanaka,Hiroyuki Ishibashi JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 130 35 11600 2008/09
- One-pot oxidative carbon-carbon bond formation of 3-benzylic and 3-allylic indoles with carbon nucleophiles Jun-ichi Matsuo,Yumi Tanaki,Hiroyuki Ishibashi TETRAHEDRON 64 22 5262 2008/05
- Stereocontrolled formal synthesis of (+/-)-platensimycin Jun-ichi Matsuo,Kosuke Takeuchi,Hiroyuki Ishibashi ORGANIC LETTERS 10 18 4049 2008/09
- Stereoselective synthesis of cis and trans-fused 3a-aryloctahydroindoles using cyclization of N-vinylic alpha-(methylthio)acetamides: synthesis of (-)-mesembrane Miho Saito,Jun-ichi Matsuo,Hiroyuki Ishibashi TETRAHEDRON 63 23 4865 2007/06
- One-pot carbon-carbon bond formation at the beta-position of cyclic ketones: oxidative Michael addition with alkyl malonates Jun-ichi Matsuo,Hiroki Kawai,Hiroyuki Ishibashi TETRAHEDRON LETTERS 48 18 3155 2007/04
- One-pot oxidative Mannich-type reaction of lactams with alkyl malonates Jun-ichi Matsuo,Yumi Tanaki,Hiroyuki Ishibashi TETRAHEDRON LETTERS 48 18 3233 2007/04
- Mild preparation of alkenes from phenyl sulfides: One-pot elimination of phenylthio group via sulfilimine at ambient temperature Jun-ichi Matsuo,Takaaki Kozai,Hiroyuki Ishibashi ORGANIC LETTERS 8 26 6095 2006/12
- Stereoselective synthesis of trans-3a-aryloctahydroindoles using cyclization of N-vinylic alpha-(methylthio)acetamides Miho Saito,Jun-ichi Matsuo,Masahiko Uchiyama,Hiroyuki Ishibashi HETEROCYCLES 69 1 69 2006/12
- Oxidative Mannich reaction of N-carbobenzyloxy amines with 1,3-dicarbonyl compounds Jun-ichi Matsuo,Yumi Tanaki,Hiroyuki Ishibashi ORGANIC LETTERS 8 19 4371 2006/09
- Radical cyclizations in 1,4-dimethylpiperazine Hiroyuki Ishibashi,Shigeki Haruki,Masahiko Uchiyama,Osamu Tamura,Jun-ichi Matsuo TETRAHEDRON LETTERS 47 35 6263 2006/08
- Catalytic and stereoselective glycosylation with glycosyl N-trichloroacetylcarbamate J Matsuo,T Shirahata,S Omura TETRAHEDRON LETTERS 47 3 267 2006/01
- One-pot dehydrogenation of carboxylic acid derivatives to alpha,beta-unsaturated carbonyl compounds J Matsuo LETTERS IN ORGANIC CHEMISTRY 2 7 576 2005/11
- Stereoselective synthesis of 19-hydroxytaxoid by utilizing samarium(II) iodide-mediated double aldol cyclization Y Ogawa,K Kuroda,J Matsuo,T Mukaiyama BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 78 4 677 2005/04
- One-pot beta-substitution of enones with alkyl groups to beta-alkyl enones J Matsuo,Y Aizawa CHEMICAL COMMUNICATIONS 2399-2401 18 2399 2005
- Stereoselective synthesis of 19-hydroxytaxoid using intramolecular pinacol coupling reaction T Mukaiyama,Y Ogawa,K Kuroda,JI Matsuo CHEMISTRY LETTERS 33 11 1412 2004/11
- New oxidations using sulfinimidoyl chlorides J Matsuo JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN 62 6 574 2004/06
- Synthesis of 13a-methylphenanthroindolizidines using radical cascade cyclization: synthetic studies toward (+/-)-hypoestestatin 1 Kosuke Takeuchi,Atsuko Ishita,Jun-ichi Matsuo,Hiroyuki Ishibashi TETRAHEDRON 63 45 11101 2007/11
- Synthesis of cis-2-fluorocyclopropylamine by stereoselective cyclopropanation under phase-transfer conditions J Matsuo,Y Tani,Y Hayakawa CHEMISTRY LETTERS 33 4 464 2004/04
- A facile one-pot benzylation of sodium enolates using trifluoromethansulfonic anhydride and diphenyl sulfoxide T Takuwa,JY Onishi,J Matsuo,T Mukaiyama CHEMISTRY LETTERS 33 1 8 2004/01
- Oxazaborolidine-catalyzed enantioselective reduction of alpha-methylene ketones to allylic alcohols Jun-ichi Matsuo,Takaaki Kozai,Osamu Nishikawa,Yu Hattori,Hiroyuki Ishibashi JOURNAL OF ORGANIC CHEMISTRY 73 17 6902 2008/09
- Lewis acid mediated reactions of allyl chalcogenides with ethyl glyoxylate Hirabayashi Kazunori,Sato Hideki,Kuriyama Yu,Matsuo Jun-ichi,Sato Soichi,Shimizu Toshio,Kamigata Nobumasa CHEMISTRY LETTERS 36 7 826 2007/07/05
- Tin(IV) Chloride Catalyzed Cycloaddition Reactions between 3-Ethoxycyclobutanones and Allylsilanes Jun-ichi Matsuo,Shun Sasaki,Takaya Hoshikawa,Hiroyuki Ishibashi ORGANIC LETTERS 11 17 3822 2009/09
- A mild and convenient synthesis of N-carbobenzyloxy ketimines Jun-ichi Matsuo,Yumi Tanaki,Aimi Kido,Hiroyuki Ishibashi CHEMICAL COMMUNICATIONS 2896-2898 27 2896 2006
- Synthesis of 8-Oxabicyclo[3.2.1]octanes by TiCl4-Mediated Reactions of 3-Alkoxycyclobutanones and Allenyl silanes T. Onnagawa,M. Yamazaki,T. Yoshimura,J. Matsuo Synlett 29 2717 2018
- Formal [4+2] cycloaddition of quinolines, pyridines, and isoquinolines with 3-ethoxycyclobutanones Tatsuo Onnagawa,Yusuke Shima,Tomoyuki Yoshimura,Jun-ichi Matsuo TETRAHEDRON LETTERS 57 27-28 3050 2016/07
- Friedel-Crafts Alkylation of Aromatics by TiCl 4 -Promoted Ring Cleavage of 3-Arylcyclobutanones Mayu Kanie,Tomoyuki Yoshimura,Jun-Ichi Matsuo Synthesis (Germany) 50 3 548 2018/02/01
- Synthesis of multisubstituted phenols by formal [4+2] cycloaddition of nucleophilic alkynes with 3-ethoxycyclobutanones Takeo Kuzuguchi,Yuto Yabuuchi,Tomoyuki Yoshimura,Jun-ichi Matsuo ORGANIC & BIOMOLECULAR CHEMISTRY 15 25 5268 2017/07
- An efficient procedure for preparation of 2-monoalkyl or 2-monoaryl-3-ethoxycyclobutanones Jun-ichi Matsuo,Ryosuke Okuno,Kosuke Takeuchi,Mizuki Kawano,Hiroyuki Ishibashi TETRAHEDRON LETTERS 51 29 3736 2010/07
- A New Synthesis of 2,3-Di- or 2,3,3-Trisubstituted 2,3-Dihydro-4-pyridones by Reaction of 3-Ethoxycyclobutanones and N-p-Toluenesulfonyl Imines Using Titanium(IV) Chloride: Synthesis of (+/-)-Bremazocine Jun-ichi Matsuo,Ryohei Okado,Hiroyuki Ishibashi ORGANIC LETTERS 12 14 3266 2010/07
- Titanium(IV) Chloride-Mediated Carbon-Carbon Bond-Forming Reaction between 3,3-Dialkylcyclobutanones and Aldehydes Jun-ichi Matsuo,Mizuki Kawano,Ryosuke Okuno,Hiroyuki Ishibashi ORGANIC LETTERS 12 17 3960 2010/09
- Indium(III) triflate-catalyzed reaction of 2-carbomethoxycyclobutanone with nitrones Jun-ichi Matsuo,Ryosuke Okuno,Hiroyuki Ishibashi TETRAHEDRON LETTERS 53 17 2257 2012/04
- Titanium(IV) Chloride-Mediated Ring Cleavage and Michael Addition of 3,3-Dialkylcyclobutanones and 3-[(Trimethylsilyl)methyl]-cyclobutanones Ryosuke Okuno,Jun-ichi Matsuo,Hiroyuki Ishibashi CHEMICAL & PHARMACEUTICAL BULLETIN 60 6 793 2012/06
- Synthesis of various 6-substituted 1,4,5,6-tetrahydropyridazines by substitution of a 1,4,5,6-tetrahydro-6-tosylhydrazinopyridazines Shunya Morita,Jun-ichi Matsuo TETRAHEDRON LETTERS 58 10 932 2017/03
- Formal [4+2] cycloaddition between 3-ethoxycyclobutanones and silyl enol ethers Jun-ichi Matsuo,Shoko Negishi,Hiroyuki Ishibashi TETRAHEDRON LETTERS 50 42 5831 2009/10
- Intramolecular formal [4+2] cycloaddition of 3-ethoxycyclobutanones and alkenes Jun-ichi Matsuo,Shun Sasaki,Takaya Hoshikawa,Hiroyuki Ishibashi CHEMICAL COMMUNICATIONS 46 6 934 2010
- Improved catalytic and stereoselective glycosylation with glycosyl N-trichloroacetylcarbamate: application to various 1-hydroxy sugars Tatsuya Shirahata,Jun-ichi Matsuo,Satoko Teruya,Nozomu Hirata,Taku Kurimoto,Nanao Akimoto,Toshiaki Sunazuka,Eisuke Kaji,Satoshi Omura CARBOHYDRATE RESEARCH 345 6 740 2010/04
- Asymmetric Synthesis of 2,3-Dihydro-4-pyranones by Reaction of Chiral 3-Alkoxycyclobutanone and Aldehydes Shoko Negishi,Hiroyuki Ishibashi,Jun-ichi Matsuo ORGANIC LETTERS 12 21 4984 2010/11
- Sequential one-pot glycosylation with glycosyl N-trichloroacetylcarbamate and trichloroacetate including dehydrative approach using 1-hydroxy sugars Tatsuya Shirahata,Asami Kojima,Satoko Teruya,Jun-ichi Matsuo,Masaki Yokoyama,Shogo Unagiike,Toshiaki Sunazuka,Kazuishi Makino,Eisuke Kaji,Satoshi Omura,Yoshinori Kobayashi TETRAHEDRON 67 35 6482 2011/09
- Ring Cleavage and Successive Aldol Reaction of 3-[(Trialkylsilyl)methyl]cyclobutanones Jun-ichi Matsuo,Kosuke Harada,Mizuki Kawano,Ryosuke Okuno,Hiroyuki Ishibashi ORGANIC LETTERS 13 22 5986 2011/11
- Formal [4+2] cycloaddition of cyclobutanones bearing alkyne-cobalt complex at their 3-positions Mizuki Kawano,Takaaki Kiuchi,Jun-ichi Matsuo,Hiroyuki Ishibashi TETRAHEDRON LETTERS 53 4 432 2012/01
- Formal [4+2] Cycloaddition of di-tert-Butyl 2-Ethoxycyclobutane-1,1-dicarboxylate with Ketones or Aldehydes and Tandem Lactonization Ryohei Okado,Aya Nowaki,Jun-ichi Matsuo,Hiroyuki Ishibashi CHEMICAL & PHARMACEUTICAL BULLETIN 60 1 21 2012/01
- Intramolecular [2+2] Cycloaddition of Homoallylketenes to Bicyclo[2.1.1]hexan-5-ones Takaya Hoshikawa,Kei Tanji,Jun-ichi Matsuo,Hiroyuki Ishibashi CHEMICAL & PHARMACEUTICAL BULLETIN 60 4 548 2012/04
- Regioselective Inter- and Intramolecular Formal [4+2] Cycloaddition of Cyclobutanones with Indoles and Total Synthesis of (+/-)-Aspidospermidine Mizuki Kawano,Takaaki Kiuchi,Shoko Negishi,Hiroyuki Tanaka,Takaya Hoshikawa,Jun-ichi Matsuo,Hiroyuki Ishibashi ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 52 3 906 2013
- The Mukaiyama aldol reaction: 40years of continuous development Jun-Ichi Matsuo,Masahiro Murakami Angewandte Chemie - International Edition 52 35 9109 2013/08/26
- Chemoselective Formal [4+2] Cycloaddition of 3-Hydroxycyclobutanones with Enones Kosuke Harada,Aya Nowaki,Jun-ichi Matsuo ASIAN JOURNAL OF ORGANIC CHEMISTRY 2 11 923 2013/11
- 1,4-Zwitterionic intermediates formed by cleavage of a cyclobutane ring and their cycloaddition reactions Jun-ichi Matsuo TETRAHEDRON LETTERS 55 16 2589 2014/04
- Development of Formal [4+2] Cycloaddition Reactions by Using Cyclobutanones Bearing Donor Substituents at their 3-Positions Junichi Matsuo JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN 74 6 582 2016/06
- Formal [4+2] cycloaddition of 3-ethoxycyclobutanones with azo compounds Yusuke Shima,Jun-ichi Matsuo TETRAHEDRON LETTERS 57 36 4066 2016/09
- Synthesis of alpha-Halo-gamma-hydroxyenamides by Titanium Tetrahalide Mediated Addition of Aldehydes or Ketones to Ynamides Yuto Yabuuchi,Takeo Kuzuguchi,Tomoyuki Yoshimura,Jun-ichi Matsuo ORGANIC LETTERS 18 19 4951 2016/10
- Bronsted Acid Catalyzed Asymmetric Reduction of Ketones and Acyl Silanes Using Chiral anti-Pentane-2,4-diol Jun-ichi Matsuo,Yu Hattori,Hiroyuki Ishibashi ORGANIC LETTERS 12 10 2294 2010/05
- Trialkylamine-Mediated Intramolecular Acylation of Akenes with Carboxylic Acid Chlorides Jun-ichi Matsuo,Takaya Hoshikawa,Shun Sasaki,Hiroyuki Ishibashi CHEMICAL & PHARMACEUTICAL BULLETIN 58 4 591 2010/04
- Asymmetric reduction of aliphatic ketones and acyl silanes using chiral anti-pentane-2,4-diol and a catalytic amount of 2,4-dinitrobenzenesulfonic acid Jun-ichi Matsuo,Yu Hattori,Mio Hashizume,Hiroyuki Ishibashi TETRAHEDRON 66 32 6062 2010/08
- Intermolecular direct catalytic cross-Michael/Michael reactions and tandem Michael/Michael/aldol reactions to linear compounds Yuta Asaji,Hibiki Maruyama,Tomoyuki Yoshimura,Jun-ichi Matsuo Tetrahedron 122 132951 2022/09
- Orientation order of nonelectrically poled FTC-type chromophores in PMMA on SiO2 surfaces Atsushi Sugita,Miwa Tsuruoka,Yuta Kinoshita,Yushi Futagami,Tomoyuki Yoshimura,Jun-Ichi Matsuo Bulletin of the Chemical Society of Japan 93 1 119 2020
- Accelerating Effect of the Addition of HFIP on the Oxidation of Alcohols Using TEMPO/PIDA Shohei Hamada,Kaori Sakamoto,Wakana Oda,Yusuke Kobayashi,Jun-ichi Matsuo,Takumi Furuta Synlett 36 12 1775 2025/06/04
- Reduction and Hydrocyanation of Aziridines with C−C Bond Cleavage Yuki Kawamoto,Tomoyuki Yoshimura,Jun‐ichi Matsuo European Journal of Organic Chemistry 27 39 2024/08/21
- Aldol/Brook/Carbon Skeletal Rearrangement Cascade Reactions of β‐Silyl Ketones with Aldehydes Aya Nowaki,Mizuki Kawano,Fuka Hori,Yurika Fuse,Tomoyuki Yoshimura,Jun‐ichi Matsuo European Journal of Organic Chemistry 26 44 2023/10/24
- Bridged-Selective Intramolecular Diels–Alder Reactions in the Synthesis of Bicyclo[2.2.2]octanes Mika Hanashima,Toshiki Matsumura,Yuta Asaji,Tomoyuki Yoshimura,Jun-Ichi Matsuo Chemical and Pharmaceutical Bulletin 68 12 1201 2020/12/01
- Palladium-catalyzed stereoselective intramolecular cyclization and Suzuki coupling of N-arylsulfonyl-α-chloroenamides promoted by a γ-hydroxy group Yuto Yabuuchi,Kenta Sakamoto,Tomoyuki Yoshimura,Jun-ichi Matsuo Tetrahedron 74 30 4053 2018/07/26
- Strain-promoted azide–alkyne cycloaddition enhanced by secondary interactions Riko Yoshikawa,Shohei Hamada,Jun-ichi Matsuo Organic & Biomolecular Chemistry 23 8 1837 2025
- Thermal [2+2] Cycloaddition of Dihydropyrroles and Dimethyl Acetylenedicarboxylate Hibiki Maruyama,Shohei Hamada,Jun‐ichi Matsuo Journal of Heterocyclic Chemistry 2025/07/17
- Chemoselective arylation of dialkyl diselenides and application to the synthesis of a ε-N,N,N-trimethyllysine derivative R. Takahashi,K. Sakamoto,N. Umezawa,T. Umehara,J. Matsuo Eur. J. Org. Chem. 2020 42 6649 2020/11/15
- Formal [4+2] cycloaddition fo 3-phenylcyclobutanones with nitriles E. Igarashi,K. Sakamoto,T. Yoshimura,J. Matsuo Tetrahedron Lett. 60 13 2019
- Asymmetric Synthesis of a Bicyclo[4.3.0]nonene Derivative Bearing a Quaternary Carbon Stereocenter: Desymmetrization of σ-Symmetrical Diketones through Intramolecular Addition of an Alkenyl Anion Tomoyuki Yoshimura,Yuki Enami,Jun-ichi Matsuo Synthesis 2020/08/20
- Brønsted Acid-Catalyzed Cyclopropanation of Indoles Using α-Aryl-α-diazoacetates Kenta Sakamoto,Yuya Ikawa,Tomoyuki Yoshimura,Jun-ichi Matsuo European Journal of Organic Chemistry 2021 5 850 2021/02/05
- Intermolecular domino Michael/aldol reactions of α,β-unsaturated esters, aromatic aldehydes, and various nucleophiles promoted with a catalytic amount of a guanidine base in DMSO Shunya Morita,Tomoyuki Yoshimura,Jun-ichi Matsuo Tetrahedron 94 2021/08/13
- Asymmetric Cycloaddition Reactions of Aryne Intermediates with a Chiral Carbon–Carbon Axis: Syntheses of Axially Chiral Biaryl Compounds Tomoyuki Yoshimura,Ken-ichi Onda,Jun-ichi Matsuo Organic Letters 2023/12/06
- Catalytic intermolecular aldol reactions of transient amide enolates in domino Michael/aldol reactions of nitroalkanes, acrylamides, and aldehydes Shunya Morita,Tomoyuki Yoshimura,Jun-ichi Matsuo Green Chemistry 23 3 1160 2021
- Synthesis of 13–16‐Membered Cyclotetrapeptide Mimics by Ugi Reactions with Diacids and Diisonitriles Yurika Fuse,Sou Ookubo,Tomoyuki Yoshimura,Jun‐ichi Matsuo European Journal of Organic Chemistry 27 5 2024/01/10
- Formal [4+4] cycloaddition of 3-arylcyclobutanones with antracene and their acid-promoted intramolecular cyclization with skeltal rearrangement M. Kanie,Y. Ikawa,T. Yoshimura,J. Matsuo Tetrahedron Lett. 2019 2019
- Homostachydrine is a Xenobiotic Substrate of OCTN1/SLC22A4 and Potentially Sensitizes Pentylenetetrazole-Induced Seizures in Mice Misa Nishiyama,Noritaka Nakamichi,Tomoyuki Yoshimura,Yusuke Masuo,Tomoe Komori,Takahiro Ishimoto,Jun-ichi Matsuo,Yukio Kato Neurochemical Research 45 11 2664 2020/08/26
- Intramolecular Büchner reaction and oxidative aromatization with SeO2 or O2 Shunya Morita,Tomoyuki Yoshimura,Jun-ichi Matsuo Chemical and Pharmaceutical Bulletin 67 7 729 2019
- Reactions of Nitrosobenzenes with Cyclobutanones by Activation with a Lewis Acid Yusuke Shima,Emiko Igarashi,Tomoyuki Yoshimura,Jun-Ichi Matsuo Synlett 29 6 723 2018/04/03
- Cascade cyclization of 1,2,7,8-tetraones and total synthesis of (±)-nesteretal A Tomoka Dentani,Ayano Kawachi,Misaki Kato,Tomoyuki Yoshimura,Jun-ichi Matsuo Organic Chemistry Frontiers 9 14 3786 2022
- Two-Carbon Ring-Enlargement of Cyclic 1,3-Diketones to Cyclic 1,5-Diketones Shumpei Kanaya,Yuta Asaji,Tomoyuki Yoshimura,Jun-Ichi Matsuo Synlett 31 12 1201 2020/07/22
- Development of Nitrolactonization Mediated by Iron(III) Nitrate Nonahydrate Tomoyuki Yoshimura,Yuki Umeda,Risako Takahashi,Jun-ichi Matsuo Chemical and Pharmaceutical Bulletin 68 12 1220 2020/12/01
- Lewis acid-catalyzed formal [4+4] cycloaddition of cyclobutanones with silyloxydienes Yuna Nishi,Akira Saito,Shunpei Kanaya,Tomoyuki Yoshimura,Jun-ichi Matsuo Tetrahedron Letters 61 3 2020/01/16
- Alkoxide-catalyzed ring expansion of 1,3-cyclobutanediones with aldehydes Mizuki Yamazaki,Tomoyuki Yoshimura,Jun-ichi Matsuo Tetrahedron Letters 64 2021/02/02
- Concise Synthesis of Cycloheptatrienes from Aldehydes and the Wittig Reagent Prepared from Pyruvic Ester Tomoyuki Yoshimura,Kanta Chino,Jun-ichi Matsuo Tetrahedron Letters 153150 2021/05
- Construction of Indole Skeletons through Direct Catalytic Three-Component Domino Reactions of Vinylarenes, Aldehydes, and Pronucleophiles Jun-ichi Matsuo,Fuka Hori,Tomoyuki Yoshimura Synlett 33 15 1519 2022/05/31
Conference Presentations
Others
- New Oxidations Using Sulfinimidoyl Chlorides 62 574-583 2004
Arts and Fieldwork
Patent
Theme to the desired joint research
Grant-in-Aid for Scientific Research
○「窒素‐硫黄結合を活用する新しい酸化剤による実用的酸化反応の開発」(2001-)
○「ヘテロ環を含むスルフィンイミドイルクロリドを用いる新しい有機合成反応の開発」(2002-)
○「１９－ヒドロキシタキソールのタキソールの不斉全合成研究」(2004-)
○「窒素―硫黄結合の特性を活用する実用的合成反応の開発」(2007-)
○「１，４－双極性活性種を用いる新しい環化付加反応の開発と生理活性物質合成への応用」(2009-)
○「1,4-双極性活性種を用いる新しい環化付加反応の開発と生理活性物質合成への応用」(2009-2011)
○「新しい1,4-双極性活性種を用いる合成反応の開発」(2012-2014)
Competitive research funding,Contribution
Collaborative research,Consignment study
○Asymmetric oxidation of 24-oxocholesterol(2006-2009)
Classes (Bachelors)
○Lecture on Life in Campus and Society(2017)
○Freshman Seminar I(2017)
○Organic Chemistry 3(2017)
○Experiments in Organic Chemistry(2017)
○Introduction to Information Technology(2017)
○Seminar in Organic Chemistry 3(2017)
○Introduction to Information Technology(2016)
○Freshman Seminar I(2016)
○Laboratory Rotation 1(2016)
○Organic Chemistry 3(2016)
○Experiments in Organic Chemistry(2016)
○Seminar in Organic Chemistry 3(2016)
○Medicinal Chemistry(2016)
Classes (Graduate Schools)
○Advanced Organic Chemistry I(2017)
○Advanced Seminar on Pharmachemistry(2017)
○Introduction to Advanced Organic Chemistry(2017)
○Advanced Organic Chemistry III(2017)
○Advanced Course of Pharmachemistry(2017)
○Advanced Organic Chemistry II(2017)
○New Reactions for Organic Synthesis(2016)
○Advanced Organic Chemistry III(2016)