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Researcher Information

last modified:2017/05/23

Professor HAYASHI Yoshihito

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Faculty, Affiliation

Faculty of Chemistry, Institute of Science and Engineering Inorganic Chemistry

College and School Educational Field

Division of Material Chemistry, Graduate School of Natural Science and Technology
Division of Material Sciences, Graduate School of Natural Science and Technology

Laboratory

Inorganic Chemistry TEL:076-264-5695 FAX:076-264-5742

Academic Background

【Academic background(Doctoral/Master's Degree)】
Osaka City University Doctor Chemistry
【Degree】
Ph.D.

Career

Institute for Molecular Science Technical assistant(1987/12/01-)
Kanazawa University Faculty of Science(1990/10/01-)
Colorado State University Department of Chemistry Postdoctoral fellow(1996/07/01-)
Kanazawa University Faculty of Science(1990/05/01-)
Kanazawa University Faculty of Science(2002/04/01-)
Kanazawa University Graduate School of Natural Science(2004/04/01-)
Kanazawa University Graduate School of Natural Science(2007/04/01-)

Year & Month of Birth

Academic Society

Chemical Society of Japan
Coordination Chemistry
American Chemical Society

Award

Specialities

Inorganic Chemistry、Inorganic Chemistry

Speciality Keywords

Polyoxometalates, Oxide Cluster, Vanadium, Inorganic Complexes

Research Themes

Synthesis and Properties of Metal Oxide Cluster

Synthesis and Properties of Metal Oxide Cluster

Development of crown ether type all-inorganic complex of polyoxovanadates

Synthetic studies of spherical and bowl type oxide cluster

Books

  •  Reduced polyoxovanadates in non-aqueous media: Condensation reaction of polyoxovanadates by reductive or oxidative coupling Research Signpost 15 2007/10
  •  T. Kurata, A. Uehara, Y. Hayashi, and Kiyoshi Isobe Stepwise synthesis of disk- and ball-shaped polyoxovanadates: All-inorganic coordination chemistry of polyoxovanadates American Chemical Society (Oxford University Press) 974 408 2007/01

Papers

  •  2CH3CNフ(n-Bu4N)2[{Ir(1,5-COD)}6W4O16]・2CH3CN: A Hybrid Inorganic-Organometallic, Flexible Cavity Host, Acetonitrile-Guest Complex Composed of a [W4O4]n+ Tetratungstate Cube and Six Polyoxoanion-Supported (1,5-COD)Ir+ Organometallic Groups. J. Am. Chem. Soc., 119, 11401-11407 (1997). 119 11401-11407 1997
  •  A Polyoxoanion-Based Iron(II) Catechol Extradiol Dioxygenase: Oxygenation of 3,5-Di-tert-butylcatechol by the Polyoxoanion-supported Iron(II) Complex (n-Bu4N)7[(CH3CN)xFeIIP2W15Nb3O62] Inorg. Chim. Acta, 291, 426-437 (1999). 291 426-437 1999
  •  A Stepwise Growth of Polyoxovanadate by Reductive Coupling Reaction with Organometallic Palladium Complex: Formation of [{(h3-C4H7)Pd}2V4O12]2-, [V10O26]4-, and [V15O36(Cl)]4- Chem. Lett., 2001, 170-171. 4 170-171 2001/04
  •  Formation of Metal-Oxygen Chain Structures by Bridging Dichromate and Coordination Compounds: [MLnCr2O7]・ (MLn=Cu2+(bipy), Ni2+(en)2, and Ni2+(bipy)2) Chem. Lett., 1998, 899-900. 9 899-900 1998
  •  Oxygenation Catalysis by All-Inorganic, Oxidation-Resistant, Dawson-Type Polyoxoanion-Supported Transition Metal Precatalysts, [(CH3CN)xM]n+ Plus P2W15Nb3O629- (M = MnII, FeII, CoII, NiII, CuI, CuII, ZnII) Inorg. Chem., 38, 2579-2591 (1999). 38 2579-2591 1999

show all

  •  Synthesis and Properties of Di-m-superoxo Dinuclear Cobalt(II, III) Complex. Chem. Lett., 1997, 1255-1256. 12 1255-1256 1997
  •  Synthesis and Structure of a New Reduced Isopolyvanadate, [V17O42]4- Chem. Lett., 2000, 770-771. 9 770-771 2000/09
  •  Three-Dimensional Polymers with Metal-Oxygen and Metal-Ligand Chains: [Mn(II)(4,4'-bipy)2(Cr2O7)(H2O)2] and [Co(II)(4,4'-bipy)2(Cr2O7)] Chem. Lett., 2001, 562-563. 562-563 2001
  •  Stepwise Synthesis of Disk and Ball Shaped Polyoxovanadates: All-Inorganic Coordination Chemistry of Polyoxovanadates" in Vanadium the Versatile Metal Y. Hayashi, T. Shinguchi, T. Kurata, and K. Isobe. ACS Symp. Ser. 974 2007/06
  •  Self-assembled All-inorganic Chiral Polyoxovanadate: Spontaneous Resolution of Nitrate-incorporated Octadecavanadate CHEMISTRY LETTERS 578 2008
  •  Synthesis of a bowl-type dodecavanadate by the coupling reaction of alkoxohexavanadate and discovery of a chiral octadecavanadate K. Domae, D. Uchimura, Y. Koyama, S. Inami, Y. Hayashi*, K. Isobe, H. Kameda, and T. Shimoda PURE AND APPLIED CHEMISTRY 81 7  1323-1330 2009/10
  •  Formation of V(V) Spherical Polyoxovanadates and Interconversion Reactions of Dodecavanadate Species Kenji Okaya, Tetsuhiro Kobayashi, Yuki Koyama, Yoshihito Hayashi, and Kiyoshi Isobe 34  5156-5163 2009/09
  •  A chloride capturing system via proton-induced structure transformation between opened- and closed-forms of dodecavanadates Y. Inoue, Y. Kikukawa, S. Kuwajima and Y. Hayashi Dalton Trans. 45 7563-7569 2016
  •  Discretew Spherical Hexadecavanadates Incorporating a Bromide with Oxidative Bromination Activity Dalton Trans. 42 33 11804-11811 2013/09
  •  Lanthanide Complexes of Macrocyclic Polyoxovanadates: Synthesis, Characterization, and Structure Elucidation by X-ray Crystallography and EXAFS Spectroscopy INORGANIC CHEMISTRY 51 2 784-793 2012/01
  •  Early-Lanthanide Complexes with All-Inorganic Macrocyclic Polyoxovanadate Ligands EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2013 10 1876-1881 2013/04
  •  Cyclic Polyvanadates Incorporating Template Transition Metal Cationic Species: Synthesis and Structures of Hexavanadate [PdV6O18]4–, Octavanadate [Cu2V8O24]4–, and Decavanadate [Ni4V10O30(OH)2(H2O)6]4– 44 2524 2005/05
  •  Hetero and lacunary polyoxovanadate chemistry: Synthesis, reactivity and structural aspects. COORDINATION CHEMISTRY REVIEWS 2011/08
  •  Synthesis and Characterization of Chloride-incorporated Deodecavanadate from Dicopper Complex of Macrocyclic Octadecavanadate CHEMISTRY LETTERS 708 2010/06
  •  Dinuclear Manganese and Cobalt Complexes with Cyclic Polyoxovanadate Ligands: Synthesis and Characterization of [Mn2V10O30]6– and [Co2(H2O)2V10O30]6–. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 34 34 5156 2009/10
  •  Tetrahedral Cobalt(II) and Zinc(II) Chloride with Tetravanadate through a Tripod Coordination Mode CHEMISTRY LETTERS 218 2009/03

Conference Presentations

  • A New Cyclic-Decavanadate as Crown-ether Type Ligands(conference:The 10th International Vanadium Symposium(V10))(2016/11/06)

Arts and Fieldwork

Patent

Theme to the desired joint research

○Application of hetero-polyoxovanadate molecule

Grant-in-Aid for Scientific Research

○「クラウンエーテル型バナデート配位子を有するランタニド錯体の化学」(2011-2013) 
○「テンプレートを利用した半球状バナジウム酸化物分子の構築反応」(2004-2007) 

Classes (Bachelors)

○Fundamentals of Inorganic Chemistry(2017)
○Structural Inorganic Chemistry(2017)
○Experiments in Basic Chemistry B(2017)
○Inorganic Chemistry II(2017)
○Safety in Chemistry(2017)
○Chemistry for Education(2016)
○Chemistry for Education(2016)

Classes (Graduate Schools)

○Inorganic Structural Chemistry(2017)
○Inorganic Synthetic Chemistry(2017)
○Inorganic Synthetic Chemistry(2017)
○Inorganic Synthetic Chemistry(2017)
○Inorganic Synthetic Chemistry(2017)
○Seminar in Material Creation(2017)
○Material Creation Chemistry II(2017)
○Seminar in Material Creation(2017)

International Project

International Students

Lecture themes

Others (Social Activities)

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