Professor HAYASHI Yoshihito
Faculty, Affiliation
Faculty of Chemistry, Institute of Science and Engineering Inorganic Chemistry
Vice-Dean of Graduate School of Natural Science
College and School Educational Field
Division of Material Chemistry, Graduate School of Natural Science and Technology
Division of Material Chemistry, Graduate School of Natural Science and Technology
Course in Chemistry, School of Chemistry, College of Science and Engineering
Laboratory
Inorganic Chemistry TEL:076-264-5695 FAX:076-264-5742
Academic Background
【Academic background(Doctoral/Master's Degree)】
Osaka City University Doctor Graduate School, Division of Natural Science Chemistry
【Academic background(Bachelor's Degree)】
Osaka City University
【Degree】
Ph.D.
Career
Institute for Molecular Science Technical assistant(1987/12/01-)
Kanazawa University Faculty of Science(1990/10/01-)
Colorado State University Department of Chemistry Postdoctoral fellow(1996/07/01-)
Kanazawa University Faculty of Science(1990/05/01-)
Kanazawa University Faculty of Science(2002/04/01-)
Kanazawa University Graduate School of Natural Science(2004/04/01-)
Kanazawa University Graduate School of Natural Science(2007/04/01-)
Year & Month of Birth
Academic Society
Chemical Society of Japan
Coordination Chemistry
American Chemical Society
Award
Specialities
Inorganic Chemistry、Inorganic Chemistry
Speciality Keywords
Polyoxometalates, Oxide Cluster, Vanadium, Inorganic Complexes
Research Themes
Synthesis and Properties of Metal Oxide Cluster
Development of crown ether type all-inorganic complex of polyoxovanadates
Synthetic studies of spherical and bowl type oxide cluster
Books
- Y. Hayashi, M. Katayama and K. Ozutsumi Vanadium Catalysis The Royal Society of Chemistry 2021
- Yoshihito Hayashi Vanadium Catalysis The Royal Society of Chemistry 2021/01
Papers
- Synthesis of Water-Soluble Planar Cobalt(II), Nickel(II), and Copper(II) Hydroxo Clusters Using a (1,4,7-Triazacyclononane)cobalt(III) Complex as a Hydrolysis-Terminating Group Sugiarto, Y. Imai and Y. Hayashi Inorg. Chem. 2022
- Induced Fitting and Polarization of a Bromine Molecule in an Electrophilic Inorganic Molecular Cavity and Its Bromination Reactivity Y. Kikukawa, K. Seto, D. Watanabe, H. Kitajima, M. Katayama, S. Yamashita, Y. Inada and Y. Hayashi Angew. Chem. Int. Ed. 59 14399 2020
- A chloride capturing system via proton-induced structure transformation between opened- and closed-forms of dodecavanadates Y. Inoue, Y. Kikukawa, S. Kuwajima and Y. Hayashi Dalton Trans. 45 7563-7569 2016
- Discretew Spherical Hexadecavanadates Incorporating a Bromide with Oxidative Bromination Activity Dalton Trans. 42 33 11804-11811 2013/09
- Lanthanide Complexes of Macrocyclic Polyoxovanadates: Synthesis, Characterization, and Structure Elucidation by X-ray Crystallography and EXAFS Spectroscopy INORGANIC CHEMISTRY 51 2 784-793 2012/01
- Formation of V(V) Spherical Polyoxovanadates and Interconversion Reactions of Dodecavanadate Species Kenji Okaya, Tetsuhiro Kobayashi, Yuki Koyama, Yoshihito Hayashi, and Kiyoshi Isobe 34 5156-5163 2009/09
- Early-Lanthanide Complexes with All-Inorganic Macrocyclic Polyoxovanadate Ligands EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2013 10 1876-1881 2013/04
- Cyclic Polyvanadates Incorporating Template Transition Metal Cationic Species: Synthesis and Structures of Hexavanadate [PdV6O18]4–, Octavanadate [Cu2V8O24]4–, and Decavanadate [Ni4V10O30(OH)2(H2O)6]4– 44 2524 2005/05
- Hetero and lacunary polyoxovanadate chemistry: Synthesis, reactivity and structural aspects. COORDINATION CHEMISTRY REVIEWS 2011/08
- Synthesis and Characterization of Chloride-incorporated Deodecavanadate from Dicopper Complex of Macrocyclic Octadecavanadate CHEMISTRY LETTERS 708 2010/06
- Dinuclear Manganese and Cobalt Complexes with Cyclic Polyoxovanadate Ligands: Synthesis and Characterization of [Mn2V10O30]6– and [Co2(H2O)2V10O30]6–. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 34 34 5156 2009/10
- Tetrahedral Cobalt(II) and Zinc(II) Chloride with Tetravanadate through a Tripod Coordination Mode CHEMISTRY LETTERS 218 2009/03
- Synthesis of a bowl-type dodecavanadate by the coupling reaction of alkoxohexavanadate and discovery of a chiral octadecavanadate K. Domae, D. Uchimura, Y. Koyama, S. Inami, Y. Hayashi*, K. Isobe, H. Kameda, and T. Shimoda PURE AND APPLIED CHEMISTRY 81 7 1323-1330 2009/10
- Synthesis and Structure of a New Reduced Isopolyvanadate, [V17O42]4- Chem. Lett., 2000, 770-771. 9 770-771 2000/09
- 2CH3CNﾌ(n-Bu4N)2[{Ir(1,5-COD)}6W4O16]･2CH3CN: A Hybrid Inorganic-Organometallic, Flexible Cavity Host, Acetonitrile-Guest Complex Composed of a [W4O4]n+ Tetratungstate Cube and Six Polyoxoanion-Supported (1,5-COD)Ir+ Organometallic Groups. J. Am. Chem. Soc., 119, 11401-11407 (1997). 119 11401-11407 1997
- A Polyoxoanion-Based Iron(II) Catechol Extradiol Dioxygenase: Oxygenation of 3,5-Di-tert-butylcatechol by the Polyoxoanion-supported Iron(II) Complex (n-Bu4N)7[(CH3CN)xFeIIP2W15Nb3O62] Inorg. Chim. Acta, 291, 426-437 (1999). 291 426-437 1999
- A Stepwise Growth of Polyoxovanadate by Reductive Coupling Reaction with Organometallic Palladium Complex: Formation of [{(h3-C4H7)Pd}2V4O12]2-, [V10O26]4-, and [V15O36(Cl)]4- Chem. Lett., 2001, 170-171. 4 170-171 2001/04
- Self-assembled All-inorganic Chiral Polyoxovanadate: Spontaneous Resolution of Nitrate-incorporated Octadecavanadate CHEMISTRY LETTERS 578 2008
- Synthesis and Properties of Di-m-superoxo Dinuclear Cobalt(II, III) Complex. Chem. Lett., 1997, 1255-1256. 12 1255-1256 1997
- Stepwise Synthesis of Disk and Ball Shaped Polyoxovanadates: All-Inorganic Coordination Chemistry of Polyoxovanadates" in Vanadium the Versatile Metal Y. Hayashi, T. Shinguchi, T. Kurata, and K. Isobe. ACS Symp. Ser. 974 2007/06
- Formation of Metal-Oxygen Chain Structures by Bridging Dichromate and Coordination Compounds: [MLnCr2O7]･ (MLn=Cu2+(bipy), Ni2+(en)2, and Ni2+(bipy)2) Chem. Lett., 1998, 899-900. 9 899-900 1998
- Oxygenation Catalysis by All-Inorganic, Oxidation-Resistant, Dawson-Type Polyoxoanion-Supported Transition Metal Precatalysts, [(CH3CN)xM]n+ Plus P2W15Nb3O629- (M = MnII, FeII, CoII, NiII, CuI, CuII, ZnII) Inorg. Chem., 38, 2579-2591 (1999). 38 2579-2591 1999
- Three-Dimensional Polymers with Metal-Oxygen and Metal-Ligand Chains: [Mn(II)(4,4'-bipy)2(Cr2O7)(H2O)2] and [Co(II)(4,4'-bipy)2(Cr2O7)] Chem. Lett., 2001, 562-563. 562-563 2001
Conference Presentations
- All-inorganic metal oxido- and hydroxido-clusters with inorganic protection groups(conference：ACS Award for Distinguished Service in the Advancement of Inorganic Chemistry)(2019/04/01)
- Coordination-mode dependent catalytic activity on under- and dodecavanadates(conference：11th International Vanadium Symposium, Uruguay 2018)(2018/11/05)
- Shape Responsive Ionic Dodecavanadium Bowls(conference：The 2nd International Symposium on Coordination Ionic Compounds )(2018/12/07)
- Flexible All-inorganic Dodecavanadate Bowls(conference：2018 Nankai International Symposium on Advanced Materials)(2018/11/12)
- Molybdate speciation by terminating condensation steps with Co(III) coordination complexes(conference：International Conference on Coordination Chemistry, ICCC2018)(2018/07/30)
- Vanadium Chemistry of Polyoxometalates(conference：Asian Meeting on Metal Oxide Assemblies 2017 (AMMOA 2017))(2017/05/09)
- A New Cyclic-Decavanadate as Crown-ether Type Ligands(conference：The 10th International Vanadium Symposium(V10))(2016/11/06)
Others
- Polyoxovanadates in Non-aqueous Media: Condensation Reaction of Polyoxovanadates by Reductive or Oxidative Coupling Reaction Y. Hayashi, Y. Koyama, T. Shinguchi, and K. Isobe Research Signpost 2007
Arts and Fieldwork
Patent
Theme to the desired joint research
○Application of hetero-polyoxovanadate molecule
Grant-in-Aid for Scientific Research
○「クラウンエーテル型バナデート配位子を有するランタニド錯体の化学」(2011-2013)
○「テンプレートを利用した半球状バナジウム酸化物分子の構築反応」(2004-2007)
○「キラルバナジウム酸化物ナノチューブ分子の構築」(2019-2021)
Competitive research funding,Contribution
Collaborative research,Consignment study
○ERATO Shimoda Nano Liquid Project(2007-)
Classes (Bachelors)
○General Materials Chemistry A(2022)
○Experiments in Basic Chemistry B(2022)
○Fundamentals of Inorganic Chemistry A(2022)
○Experiments in Basic Chemistry B(2022)
○Structural Inorganic Chemistry(2017)
○Safety in Chemistry(2017)
○Fundamentals of Inorganic Chemistry(2017)
○Experiments in Basic Chemistry B(2017)
○Inorganic Chemistry II(2017)
○Chemistry for Education(2016)
○Chemistry for Education(2016)
Classes (Graduate Schools)
○Material Creation Chemistry II(2022)
○Inorganic Structural Chemistry(2022)
○Seminar in Material Creation(2022)
○Inorganic Chemistry for Education(2022)
○Inorganic Structural Chemistry(2017)
○Seminar in Material Creation(2017)
○Material Creation Chemistry II(2017)
○Inorganic Synthetic Chemistry(2017)
○Seminar in Material Creation(2017)
○Inorganic Synthetic Chemistry(2017)
○Inorganic Synthetic Chemistry(2017)
○Inorganic Synthetic Chemistry(2017)