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Researcher Information

last modified:2017/05/23

Professor UKAJI Yutaka

Mail Laboratory Website

Faculty, Affiliation

Faculty of Chemistry, Institute of Science and Engineering

College and School Educational Field

Division of Material Chemistry, Graduate School of Natural Science and Technology
Division of Material Sciences, Graduate School of Natural Science and Technology

Laboratory

Lab. of Organic Chemistry

Academic Background

【Academic background(Doctoral/Master's Degree)】
The University of Tokyo Doctor 198612 Unfinished course
【Academic background(Bachelor's Degree)】
The University of Tokyo 198203

Career

Kanazawa University(2005/07/01-)
Kanazawa University(1994/01/01-2005/06/30)
Kanazawa University(1991/04/01-1993/12/31)
Mie University(1987/01/01-1991/03/31)

Year & Month of Birth

1960/02

Academic Society


Synthetic Organic Chemistry Japan

Award

○BCSJ Award(2010/12/01)
○BCSJ Award(2010/12/01)
○BCSJ Award(2010/12/01)
○BCSJ Award(2010/12/01)
○BCSJ Award(2010/12/01)
○BCSJ Award(2010/12/01)
○NOVARTIS Foundation (Japan) for the Promotion of Science(2006/02)
○NOVARTIS Foundation (Japan) for the Promotion of Science(2006/02)
○NOVARTIS Foundation (Japan) for the Promotion of Science(2006/02)
○Sasakawa Scientific Research Grant(1994/03)

Specialities

Organic chemistry、Synthetic chemistry、Functional solid state chemistry

Speciality Keywords

Research Themes

Asymmetric Synthesis

Developement of Novel Asymmetric Reactions Utilizing Tartaric Acid Esters

Development of Efficient Synthetic Reactions

Developement of Efficient Reactions Utilizing Palladium-Copper System
Stereoselective Reactions Based on syn-effect
Developement of Multicomponent Reactions

Development of Functionalized Materials

Syntheses of Phytochromobilin Derivatives

Books

  •  Development of New Methods for the Construction of Heterocycles Based on Cycloaddition Reaction of 1,3-Dipoles, “Methods and Applications of Cycloaddition Reactions in Organic Syntheses.” ed. by N. Nishiwaki, Wiley, Inc., 2013, Chap. 11, Y. Ukaji, T. Soeta, 263–282. (分担)
  •  Addition reaction / Cycloaddition involving oxidation (N=N, N=O; no C-C bond formed). Y. Ukaji, “Comprehensive Chirality.” ed. by H. Yamamoto, E. Carreira, Elsevier, Oxford, 2012, Chap. 6.22(分担).
  •  Acetogenin (polypriopionate) Derived Auxiliaries/Tartaric Acid. Y. Ukaji, T. Soeta, “Comprehensive Chirality.” ed. by H. Yamamoto, E. Carreira, Elsevier, Oxford, 2012, Chap. 4.06(分担).
  •  「1,3-双極子付加環化反応」,「Reformatsky反応」,「Simmons-Smith反応」,宇梶 裕,『日本のトップドラック』(東京化学同人)(分担)

Papers

  •  Development of a One-Pot Synthetic Method for Multifunctional Oxazole Derivatives Using Isocyanide Dichloride. T. Soeta, A. Matsumoto, Y. Sakata, Y. Ukaji, J. Org. Chem. 2017, 82, in press. J. Org. Chem
  •  Formal Total Synthesis of Manzacidin C Based on Asymmetric 1,3-Dipolar Cycloaddition of Azomethine Imines. T. M. T. Tong, T. Soeta, T. Suga, K. Kawamoto, Y. Hayashi, Y. Ukaji, J. Org. Chem. 2017, 82, 1969−1976. J. Org. Chem
  •  Palladium-Catalyzed C-H Alkenylation of C-Aryl Nitrones. M. Hasegawa, A. Nomoto, T. Suga, T. Soeta, Y. Ukaji, Chem. Lett. 2017, 46, 45–47. Chem. Lett.
  •  Palladium-Catalyzed Intermolecular Alkoxy-Alkoxycarbonylation of Vinylphenols in the Presence of Copper Salt: Unexpected Cooperative Effect of Tin Salt. N. H. T. Phan, T. Furuya, T. Soeta, Y. Ukaji, Chem. Lett. 2016, 45, 1431-1433. Chem. Lett.
  •  Efficient Synthesis of Benzothiophenes by [4+1] Cycloaddition of 2-Mercaptobenzaldehyde Derivatives with Isocyanides. T. Soeta, S. Shitaya, T. Okuno, S. Fujinami, Y. Ukaji, Tetrahedron 2016, 72, 7901-7905. Tetrahedron

show all

  •  Ugi-type Multicomponent Reaction of Nitrile Imines, Isocyanides, and Isocyanates: Effective Synthesis of 1,2,4-Triazinedione Derivatives. T. Soeta, S. Takashita, Y. Sakata, Y. Ukaji, Asian J. Org. Chem. 2016, 5, 1041–1047.
  •  Chiral NHC Ligands Bearing a Pyridine Moiety in Copper-Catalyzed 1,2-Addition of Dialkylzinc Reagents to β-Aryl-α,β-unsaturated N-Tosylaldimines. T. Soeta, T. Ishizaka, Y. Ukaji, J. Org. Chem. 2016, 81, 2817–2826.
  •  Magnesium-Alkoxide Directed Photoaddition of Tetrahydrofyrans to γ, γ-Disubstituted Allylic Alcohols. Y. Watanabe, T. Sakai, H. Maeda, M. Segi, T. Soeta, Y. Ukaji,Heterocycles 2016, 93, accepted.
  •  Silver-Catalyzed Allylation of Ketones and Intramolecular Cyclization via Carbene Intermediates from Cyclopropenes Under Ambient Conditions. T. Nakano, K. Endo, Y. Ukaji, Chem. –Asian J. 2016, 11, 713–721.
  •  Phosphinic Acid-Promoted Addition Reaction of Isocyanides to (Z)-Hydroximoyl Chlorides: Efficient Synthesis of α-(Hydroxyimino)amides. T. Soeta, S. Takashita, Y. Sakata, Y. Ukaji, Org. Biomol. Chem. 2016, 14, 694-700.
  •  (Z)-Selective Enol Triflation of alpha-Alkoxyacetoaldehydes: Application to Synthesis of (Z)-Allylic Alcohols via Cross-Coupling Reaction and [1,2]-Wittig Rearrangement. F. Kurosawa, T. Nakano, T. Soeta, K. Endo, Y. Ukaji, J. Org. Chem. 2015, 80, 5696−5703.
  •  A One-Pot O-Sulfinative Passerini/Oxidation Reaction: Synthesis of α-(Sulfonyloxy)amide Derivatives. T. Soeta, S. Matsuzaki, Y. Ukaji, J. Org. Chem. 2015, 80, 3688–3694.
  •  One-Carbon Homologation of Pyrrole Carboxaldehyde via Wittig Reaction and Mild Hydrolysis of Vinyl Ether – Toward the Synthesis of a Sterically Locked Phytochrome Chromophore, R. Sakata, T. Soeta, Y. Ukaji, Heterocycles 2015, 91, 593-603.
  •  Copper(I)—Catalyzed Carbometalation of Unfuncionalized Cyclopropenes Using Organozinc and Grignard Reagents, T. Nakano, K. Endo, Y. Ukaji, Synlett 2015, 26, 671-675.
  •  1,3-双極子を活用する複素環合成の新展開, Development of New Synthetic Methods for Heterocycles Utilizing 1,3-Dipoles, Y. Ukaji, T. Soeta, J. Synth. Org. Chem. Jpn. 2015, 73(1), 65–75.
  •  Regioselective Introduction of Substituents to the meso-Position of Pyrromethenone Derivative – Application to the Synthesis of Sterically Fixed Phytochrome Chromophore Anchored to the C15 meso-Position, Y. Tanaka, R. Iwamoto, R. Sakata, T. Soeta, K. Endo, S. Fujinami, K. Inomata, Y. Ukaji, Heterocycles 2015, 90, 883–892.
  •  Ring Enlargement Reaction of C,N-Cyclic-N’-Acyl Azomethine Imines with Sulfonium Ylide: An Efficient Synthesis of 3-Benzazepine Derivatives. T. Soeta, T. Ohgai, T. Sakai, S. Fujinami, Y. Ukaji, Org. Lett. 2014, 16, 4854–4857.
  •  Chiral NHC Ligands Bearing a Pyridine Moiety for the Copper-Catalyzed Alkylation of N-Sulfonylimines with Dialkylzinc Reagents. T. Soeta, T. Ishizaka, Y. Tabatake, Y. Ukaji, Chem. –Eur. J. 2014, 20, 16773–16778.
  •  Desymmetrization of meso-Methylenecyclopropanes by a Palladium-Catalyzed Asymmetric Ring-Opening Bis(alkoxycarbonylation) Reaction, Y. Yonezawa, T. Furuya, T. Aratani, S. Fujinami, K. Inomata, Y. Ukaji, Tetrahedron: Asymmetry 2014, 25, 936–943.
  •  The Lewis Acid-Catalyzed [3+1+1] Cycloaddition of Azomethine Ylides with Isocyanides, T. Soeta, Y. Miyamoto, S. Fujinami, Y. Ukaji, Tetrahedron 2014, 70, 6623–6629.
  •  [4+1] Cycloaddition of N-Acyl Imine Derivatives with Isocyanides: Efficient Synthesis of 5-Aminooxazoles and 5-Aminothiazoles. T. Soeta, K. Tamura, Y. Ukaji, Tetrahedron 2014, 70, 3005–3010.
  •  Catalytic Tandem C–C Bond Formation/Cleavage of Cyclopropene for Allylzincation of Aldehydes or Aldimine Using Organozinc Reagents. T. Nakano, K. Endo, Y. Ukaji, Org. Lett. 2014, 16, 1418–1421.
  •  A One-Pot O-Phosphinative Passerini/Pudovik Reaction: Efficient Synthesis of Highly Functionalized α-(Phosphinyloxy)amide Derivatives, T. Soeta, S. Matsuzaki, Y. Ukaji, Chem. -Eur. J. 2014, 20, 5007–5012.
  •  Carboxylic Acid-Free Novel Isocyanide Based Reactions, T. Soeta, Y. Ukaji, Chem. Rec. 2014, 14, 101–116. 13
  •  Desymmetrization of 1,4-Pentadien-3-ol by the Asymmetric 1,3-Dipolar Cycloaddition of Azomethine Imines. M. Yoshida, N. Sassa, T. Kato, S. Fujinami, T, Soeta, K. Inomata, Y. Ukaji, Chem. –Eur. J. 2014 20, 2058–2064
  •  tereoselective Synthesis of (2Z,4E)-2,4-Pentadien-1-ols via Sequential 1,4-Elimination Reaction and [1,2]-Wittig Rearrangement Starting from (E)-4-Alkoxy-2-butenyl Benzoates, T. Nakano, T. Soeta, K. Endo, K. Inomata, Y. Ukaji, J. Org. Chem. 2013, 78, 12654−12661.
  •  Dramatic Silver(I) Oxide-Promoted Chemoselective Cross-Coupling Reaction of (Diborylmethyl)trimethylsilane, K. Endo, F. Kurosawa, Y. Ukaji, Chem. Lett. 2013, 42, 1363-1365. CHEMISTRY LETTERS 2013/11
  •  Chemoselective Carbozincation of Cyclopropene for C–C Bond Formation and Cleavage Sequence in Single Operation, K. Endo, T. Nakano, S. Fujinami, Y. Ukaji, Eur. J. Org. Chem. 2013, 6514–6518.  EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
  •  Magnesium-Tartramide Complex Mediated Asymmetric Strecker-Type Reaction of Nitrones Using Cyanohydrin, T. Sakai, T. Soeta, K. Endo, S. Fujinami, Y. Ukaji, ORGANIC LETTERS 15 2422–2425 2013/05
  •  N-Heterocyclic Carbene Catalyzed Oxidative Coupling of Aldehydes with Carbodiimides under Aerobic Conditions: Efficient Synthesis of N-Acylureas. T. Soeta, Y. Tabatake, S. Fujinami, Y. Ukaji.  ORGANIC LETTERS 15 2088–2091 2013/05
  •  One-pot Stereoselective Syntheses of 2-Acylaziridines and 2-Acylpyrrolidines from N-(Propargylic)hydroxylamines. Y. Miyamoto, N. Wada, T. Soeta, S. Fujinami, K. Inomata, Y. Ukaji Chemistry ? An Asian Journal 8 824–831 2013/04
  •  Three-Component Reaction of C,N-Cyclic N’-Acyl Azomethine Imine, Isocyanide, and Azide Compounds: Effective Synthesis of 1,5-Disubstituted Tetrazoles with Tetrahydroisoquinoline Skeletons., T. Soeta, K. Tamura, S. Fujinami, Y. Ukaji Organic & Biomolecular Chemistry 11 13 2168–2174 2013/03
  •  Direct Oxidation of 4-Methylpyrrole-2-carboxylates with DDQ in the Presence of a Glycol, K. Takahashi, R. Iwamoto, R. Sakata, T. Soeta, K. Inomata, Y. Ukaji  HETEROCYCLES 86 2 1031–1038 2012/12
  •  The Chlorosilane-Promoted Addition Reaction of Isocyanides to 3,4-Dihydroisoquinoline N-Oxides, T. Soeta, S. Fujinami, Y. Ukaji  JOURNAL OF ORGANIC CHEMISTRY 77 21 9878–9883 2012/11
  •  An Asymmetric Intramolecular Stetter Reaction Catalyzed by a Chiral Triazolium Precatalyst Bearing a Pyridine Moiety, T. Soeta, Y. Tabatake, Y. Ukaji  TETRAHEDRON 68 49 10188–10193 2012/12
  •  Asymmetric Bis(alkoxycarbonylation) Reaction of Cyclic Olefins Catalyzed by Palladium in the Presence of Copper(I) Triflate, T. Aratani, K. Tahara, S. Takeuchi, S. Kitamura, M. Murai, S. Fujinami, K. Inomata, Y. Ukaji BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 85 11 1225–1232 2012/11
  •  Assembly of Synthetic Locked Phycocyanobilin Derivatives with Phytochrome in Vitro and in Vivo in Ceratodon purpureus and Arabidopsis, R. Yang, K. Nishiyama, A. Kamiya, Y. Ukaji, K. Inomata, T. Lamparter  PLANT CELL 24 5 1936–1951 2012/05
  •  [5+1] Cycloaddition of C,N-Cyclic N’-Acyl Azomethine Imines with Isocyanides, T. Soeta, K. Tamura, Y. Ukaji  T. Soeta, K. Tamura, Y. Ukaji ORGANIC LETTERS 14 5 1226–1229 2012/03
  •  Strecker-Type Reaction of Nitrones Using Cyanohydrin, T. Sakai, T. Soeta, K. Inomata, Y. Ukaji, T. Sakai, T. Soeta, K. Inomata, Y. Ukaji 85 1226–1229 2012/02
  •  Asymmetric Benzoin Condensation Promoted by Chiral Triazolium Precatalyst Bearing a Pyridine Moiety, T. Soeta, Y. Tabatake, K. Inomata, Y. Ukaji, TETRAHEDRON 68 894–899 2012/01
  •  Oxidation of Pyrrole-2-Carboxylates with o-Chloranil and its Synthetic Application, R. Sakata, R. Iwamoto, S. Fujinami, Y. Ukaji, K. Inomata HETEROCYCLES 82 2 1157–1162 2011/02
  •  Total Synthesis of Doubly Locked 5Za15Ea-Biliverdin Derivative; A Convergent Synthesis of the E-anti Dipyrrole Component Locked with a 7-Membered Ring L.-Y Chen, R. Iwamoto, Y. Ukaji, K. Inomata 40 632–634 2011/06
  •  Stereoselective One-Pot 1,4-Elimination and [1,2]-Wittig Rearrangement of (E)-d-(Arylmethoxy or Silylpropargyloxy)-Substituted Allylic Sulfones S. Horii, I. Ishimaru, Y. Ukaji, K. Inomata 40 521-523 2011/05
  •  Borinic Acid Catalyzed a-Addition to Isocyanide with Aldehyde and Water T. Soeta, Y. Kojima, Y. Ukaji, K. Inomata 52 2557–2559 2011/04
  •  Selective Transformation of N-(Propargylic)hydroxylamines into 4-Isoxazolines and Acylaziridines Promoted by Metal Salts N. Wada, K. Kaneko, Y. Ukaji, K. Inomata 40 5 440-442 2011/05
  •  Syntheses of Phycocyanobilin Derivatives Bearing a Sterically Locked 15Z-anti or 15E-anti C/D-Ring Components 83 1309–1322 2010/11
  •  Regioselective Oxidation of Pyrrole Derivatives with DDQ and Its Synthetic Application 2010, 39(3); 176-177 2010/03
  •  Syntheses of Phycocyanobilin Derivatives Bearing a Sterically Locked 15Z-anti or 15E-anti C/D-Ring Components 2010, 83(11) in press 2010/11
  •  O-Silylative Passerini Reaction: A New One-Pot Synthesis of α-Siloxyamides T. Soeta, Y. Kojima, Y. Ukaji, K. Inomata 12 4341–4343 2010/11
  •  Asymmetric 1,3-Dipolar Cycloaddition of Azomethine Imines to Homoallylic Alcohols 39 1036-1038 2010/10
  •  Regioselective Oxidation of Pyrrole Derivatives with DDQ and Its Synthetic Application R. Iwamoto, Y. Ukaji, K. Inomata 39 176-177 2010/03
  •  Recent Progress in Chiral Multinucleating System Utilizing Tartaric Acid Esters 10 173-187 2010/02
  •  Catalytic Asymmetric 1,3-Dipolar Cycloaddition of Azomethine Imines to Allyl Alcohol Utilizing Tartaric Acid Ester as a Chiral Auxiliary K. Tanaka, T. Kato, Y. Ukaji, K. Inomata 80 887-893 2010/01
  •  Ring-Opening Bis(alkoxycarbonylation) Reaction of Methylenecyclopropanes Catalyzed by Palladium in the Presence of Copper(I) Salt T. Aratani, Y. Ukaji, and K. Inomata 38 1, 46-47 2009/01
  •  One Pot Synthesis of Optically Active 4-Isoxazolines by Asymmetric Addition of Alkynylzinc Reagents to Nitrones Followed by Cyclization W. Wei, M. Kobayashi, Y. Ukaji, and K. Inomata HETEROCYCLES 78 3, in press 2009/03
  •  Asymmetric 1,3-Dipolar Cycloaddition Reaction of Azomethine Imines to Allyl Alcohol T. Kato, S. Fujinami, Y. Ukaji, and K. Inomata CHEMISTRY LETTERS 37(3)  342-343 2008/03
  •  Catalytic Asymmetric Dialkynylation Reaction of alpha-Dinitrone by Utilizing Tartaric Acid Ester as a Chiral Auxiliary M. Serizawa, S. Fujinami, Y. Ukaji, and K. Inomata TETRAHEDRON-ASYMMETRY 19(8)  921-931 2008
  •  Asymmetric Hetero Diels-Alder Reaction of Nitroso Compounds Utilizing Tartaric Acid Ester as a Chiral Auxiliary HETEROCYCLES 56 in press 2008
  •  Syn-Effect" in Nucleophilic Addition of Amines to (E)-1-Tosyl-1,3-butadiene and Ethyl (E)-2,4-Pentadienoate M. Yamazaki, S. K. Guha, Y. Ukaji, and K. Inomata 81(6) 740-753 2008/06
  •  Asymmetric Addition of Phenylzinc Reagents to C-Alkynyl Nitrones. Enantiomeric Enhancement by a Product-like Additive W. Wei, Y. Hamamoto, Y. Ukaji, and K. Inomata 19(4) 476-481 2008
  •  Catalytic Asymmetric Addition of Alkynylzinc Reagents to Nitrones A. Konishi, W. Wei, M. Kobayashi, S. Fujinami, Y. Ukaji, and K. Inomata CHEMISTRY LETTERS 36 1 44-45 2007/01
  •  Asymmetric Bis(alkoxycarbonylation) Reaction of Cyclic Olefins Catalyzed by Palladium in the Presence of Copper(I) Triflate T. Aratani, K. Tahara, S. Takeuchi, Y. Ukaji, and K. Inomata CHEMISTRY LETTERS 36 11 328-1329 2007/11
  •  Preparation of Novel N-Sulfonylated (S,S)-2,3-Diaminosuccinate-Type Chiral Auxiliaries and Application to an Asymmetric 1,3-Dipolar Cycloaddition Reaction of Nitrile Oxides to Allyl Alcohol M. Serizawa, Y. Ukaji, and K. Inomata TETRAHEDRON-ASYMMETRY 17 22 3075-3083 2006/11
  •  Enantioselective Diels-Alder Reaction of o-Quinodimethanes by Utilizing Tartaric Acid Ester as a Chiral Auxiliary M. Takinami, Y. Ukaji, and K. Inomata TETRAHEDRON-ASYMMETRY 17 10 1154-1560 2006/05
  •  Asymmetric 1,3-Dipolar Cycloaddition of Nitrones with an Electron-Withdrawing Group to Allylic Alcohols Utilizing Diisopropyl Tartrate as a Chiral Auxiliary X. Ding, K. Taniguchi, Y. Hamamoto, K. Sada, S. Fujinami, Y. Ukaji, and K. Inomata BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 79 7 1069-1083 2006/07
  •  Asymmetric Addition of Alkynylzinc Reagents to Nitrones Utilizing Tartaric Acid Ester as a Chiral Auxiliary W. Wei, M. Kobayashi, Y. Ukaji, and K. Inomata CHEMISTRY LETTERS 35 2 176-177 2006/02
  •  Syn-Effect" in Nucleophilic Addition of Amines to 1,3-Dienylsulfone M. Yamazaki, S. K. Guha, Y. Ukaji, and K. Inomata CHEMISTRY LETTERS 2006/05
  •  Syn-Effect" in the 1,4-Eliminative Rearrangement of [3-Substituted-(E)-1-propenyl]oxiranes to the Corresponding 2,4-Dienyl Alcohols N. Takeda, T. Chayama, H. Takenaka, Y. Ukaji, and K. Inomata CHEMISTRY LETTERS 34 8 1140-1141 2005/08
  •  Palladium Catalyzed Elimination Reaction of Acyclic (E)-Allylic Acetates: The Stereochemistry Elucidated by "Syn-Effect. H. Takenaka, Y. Ukaji, and K. Inomata CHEMISTRY LETTERS 34 2 256-257 2005/02
  •  Syn-Effect in the Conversion of (E)-a,b-Unsaturated Esters into the Corresponding b,g-Unsaturated Esters and Aldehydes into Silyl Enol Ethers BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 77 12 2147-2157 2004/12
  •  Palladium Catalyzed Carbonylation of Homoallylic Amine Derivatives in the Presence of Copper Co-catalyst BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 76 6 1251-1256 2003/06
  •  Syn-Effect in the Desilylation Reaction of g-Silylated Allylic anc Vinylic Sulfones CHEMISTRY LETTERS 32 11 1158-1159 2003/11
  •  Syn-Effect in the Conversion of (E)-a,b-Unsaturated Esters to the Corresponding b,g-Unsaturated Esters CHEMISTRY LETTERS 32 8 778-779 2003/08
  •  The First Enantioselective Hetero Diels-Alder Reaction of Nitroso Compound Utilizing Tartaric Acid Ester as a Chiral Auxiliary CHEMISTRY LETTERS 32 7 582-583 2003/07
  •  Development of New Asymmetric Reactions Utilizing Tartaric Acid Ester as a Chiral Auxiliary: Design of an Efficient Chiral Multinucleating System SYNLETT 2003 8 1075-1087 2003/08
  •  Catalytic Asymmetric 1,3-Dipolar Cycloaddition of a Nitrone Bearing a Bulky Amide Moiety to g-Substituted Allylic Alcohols Chem. Lett. 302 2002
  •  A Catalytic Asymmetric 1,3-Dipolar Cycloaddition of Nitrones to Allyl Alcohol Chem. Lett. 468 2001
  •  Asymmetric Addition of Reformatsky-Type Reagent to Imines Utilizing Diisopropyl Tartrate as a Chiral Auxiliary Chem. Lett. 254 2001
  •  Asymmetric Bis(alkoxycarbonylation) Reaction of Terminal Olefins Catalyzed by Palladium in the Presence of Copper(I) Triflate and a Chiral Bioxazoline Ligand Bull. Chem. Soc. Jpn. 74 955 2001
  •  Asymmetric Addition of a Reformatsky-Type Reagent to 3,4-Dihydroisoquinoline N-Oxides Tetrahedron: Asymmetry, 11 733 2000
  •  Catalytic Asymmetric Addition of Dialkylzinc to Nitrones to 3,4-Dihydroisoquinoline N-Oxides Utilizing Tartaric Acid Ester as a Chiral Auxiliary Bull. Chem. Soc. Jpn. 73 447 2000
  •  Enantioselective Synthesis of Lythraceae Alkaloid Lasubine II via Optically Active 2-Isoxazoline HETEROCYCLES 52 563 2000
  •  Syn-Effect" in the Desulfonylation Reaction of a,a-Dialkylated (E)-Allyic Sulfones. Bull. Chem. Soc. Jpn. 70 381 1997
  •  Asymmetric 1,3-Dipolar Cycloaddition of Nitrile Oxides to g-Substituted Allylic Alcohols 1023 1998
  •  Catalytic Asymmetric Addition Reaction of Dialkylzinc to Nitrone Utilizing Tartaric Acid Ester as a Chiral Auxiliary Chem. Lett. 59 1997
  •  Development of New Asymmetric Reactions Utilizing Tartaric Acid Ester as a Chiral Auxiliary: Design of an Efficient Chiral Dinucleating System Reviews on Heteroatom Chemistry, 18 119 1998
  •  Enantio- and Diastereoselective Synthesis of Isoxazolidines by Asymmetric 1,3-Dipolar Cycloaddition of Nitrones Chem. Lett. 547 1997

Conference Presentations

Arts and Fieldwork

Patent

Theme to the desired joint research

Grant-in-Aid for Scientific Research

○「立体固定型発色団合成を基盤とするフィトクロムの構造と機能の解明」(2013-2015)
○「1,3-双極子を活用する複素環合成の革新」(2012-2015) 
○「不斉付加環化反応による高効率的・高選択的光学活性環状化合物の合成法の開発と応用」(1997-) 
○「酒石酸エステルを活用する二核キラル反応場の構築と光学活性化合物合成への応用」(1998-) 
○「酒石酸エステルを活用する二核キラル反応場の構築と光学活性化合物合成への応用」(1999-) 
○「キラル反応場の複核化に基づく新規不斉合成反応の開発」(2001-) 
○「複核キラル反応場における複合的制御を基盤とする不斉付加環化反応の革新」(2004-)
○「複核キラル反応場における複合的制御を基盤とする不斉付加環化反応の革新」(2005-)
○「シン効果の本質解明と応用」(2006-) 
○「シン効果の本質解明と応用」(2007-) 
○「複核キラル反応場の精密化・力量化による高効率的分子変換法の開発」(2006-) 
○「複核キラル反応場の精密化・力量化による高効率的分子変換法の開発」(2007-) 
○「複核キラル反応場の精密化・力量化による高効率的分子変換法の開発」(2008-) 
○「1,3-双極子の高次立体制御法の開発と光学活性複素環化合物合成への応用」(2009-) 
○「1,3-双極子の高次立体制御法の開発と光学活性複素環化合物合成への応用」(2009-2011) 

Classes (Bachelors)

○Experiments in Basic Chemistry B(2017)
○Fundamentals of Organic Chemistry(2017)
○Experiments in Basic Chemistry A(2017)
○Organic Chemistry I(2017)
○Fundamental Chemistry 1(2017)
○Practical Seminar for Teaching Profession C / Junior High School・High School(2017)
○Safety in Chemistry(2017)
○Safety in Chemistry(2016)
○Practical Seminar for Teaching Profession C / Junior High School・High School(2016)
○Organic Chemistry I(2016)
○Experiments in Basic Chemistry B(2016)
○Safety in Chemistry(2016)

Classes (Graduate Schools)

○Seminar in Material Creation(2017)
○Synthetic Organic Reactions(2017)
○Synthetic Organic Reactions(2017)
○Synthetic Organic Reactions(2017)
○Synthetic Organic Reactions(2017)
○Seminar in Material Creation(2017)
○Synthetic Organic Chemistry(2017)
○Material Creation Chemistry I(2017)
○Synthetic Organic Chemistry(2016)
○Seminar in Material Creation(2016)
○Seminar in Material Creation(2016)
○Synthetic Organic Reactions(2016)
○Material Creation Chemistry I(2016)

International Project

International Students

Lecture themes

Others (Social Activities)

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