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Researcher Information

last modified:2017/05/23

Associate Professor YAMAGUCHI Takahiro

Laboratory Website

Faculty, Affiliation

Faculty of Chemistry, Institute of Science and Engineering

College and School Educational Field

Division of Material Chemistry, Graduate School of Natural Science and Technology
Division of Material Sciences, Graduate School of Natural Science and Technology
School of Chemistry, College of Science and Engineering

Laboratory

 TEL:076-234-4772 FAX:076-234-4800

Academic Background

【Academic background(Doctoral/Master's Degree)】
Japan Advanced Institute of Science and Technology Master 199503 Completed
【Academic background(Bachelor's Degree)】
Kanazawa University 1993

Career

Kanazawa University(2003-2006)
Kanazawa University(1995/04/01-2003/07/31)
Associate Professor(2006/04/01-)

Year & Month of Birth

1970/07

Academic Society


The electrochemical society of Japan
International Society of Electrochemistry

Award

Specialities

Electrochemistry、Functional solid state chemistry

Speciality Keywords

Electrochemistry

Research Themes

Functionalization of chemically modified electrode

Molecular recognition based on interfacial electron transfer has attracted a growing interest because of possible applications to chemical sensors, electroanalysis, electrocatalysis, and molecular electronic devices. To develop the promising electrode-modification strategies for detecting a target species selectively, it is necessary to understand both the effect of the film surface-analyte interaction and interfacial electron-transfer kinetics. We pursue a development of new functionalized film for electrochemical controlling electron transfer rate and material transport rate.

Development of non-platinum electrocatalysts for oxygen reduction

ORR Catalysts are being actively pursued for practical applications in hydrogen–oxygen fuel cells. In particular, the development of inexpensive catalysts, or non-precious metal catalysts, to replace those incorporating metals such as platinum has become a matter of great urgency due to an anticipated exhaustion of noble metals. We aim to develop an ordered network of metal porphyrin as an ORR cataryst having high activity and long-term stability. We also aim at establishment that electropolymerization method of metal-polypyrrol composite film for low cost and easily making one.

Books

Papers

  •  Electron Transfer rate of Redox Ion Controlled by Electrostatic Interaction with 4-aminothiophenol Monolayer on Gold Electrode T. Yamaguchi, K. Takahashi, T. Komura ELECTROCHEMISTRY 66 9 929-934 1998/09
  •  Electron Transfer Rate of Indigotetrasulfonate Ion Changed with Protonation of 4-aminothiophenol Monolayer-modified Electrode T.Yamaguchi, K.Takahashi, T.Komura ELECTROCHEMISTRY 67 8 843-849 1999/08
  •  Impedance Spectroscopy of Composite Monolayer Controlled Electron-transfer Rate T.Yamaguchi, K.Takahashi, T.Komura ELECTROCHEMISTRY 65 9 765-771 1997/09
  •  Electrocatalysis of Poly(2,5-dihydroxyaniline) Films for Hydroquinone in Solution W. Wang, T. Yamaguchi, K. Takahashi,T. Komura ELECTROCHEMISTRY 66 10 1032-1033 1998/10
  •  Catalytic Epoxidation of Cyclohexene by Covalently Linked Manganese Porphyrin-Viologene Complex Y. Tuda, K. Takahashi, T. Yamaguchi, S. Matsui, T. Komura JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 130 285-295 1998

show all

  •  Charge transport properties of polythionine films dependent on electrode potential and solution pH W. Wang, T. Komura, T. Yamaguchi, K. Takahashi ELECTROCHEMISTRY 68 1 17-23 2000/01
  •  Charge-transport processes at poly-o-aminophenol film electrodes: electron hopping accompanied by proton exchange T.Komura, Y.Ito, T.Yamaguchi, K.Takahashi ELECTROCHIMICA ACTA 43 7 723-731 1998
  •  Charge-transporting properties of electropolymerized phenosafranin in aqueous media T.Komura, M.Ishihara, T.Yamaguchi, K.Takahashi JOURNAL OF ELECTROANALYTICAL CHEMISTRY 493 1 84-92 2000/11
  •  Contribution of electric-field-induced metal-free porphyrin dication to photocurrent in mixed solid of metal-free porphyrin and o-chloranil/Al Schottky-barrier cell K. Takahashi, T. Terada, T. Yamaguchi, T. Komura, K. Murata JOURNAL OF THE ELECTROCHEMICAL SOCIETY 146 5 1717-1723 1999
  •  Current enhancing effect of poly[1-methyl (pyrrol-1- ylmethyl)pyridinium] films on the electrode reaction of anthraquinonedisulfonate T.Komura, Y. Yokono, T.Yamaguchi, K.Takahashi JOURNAL OF ELECTROANALYTICAL CHEMISTRY 478 9-16 1999
  •  Dependence of redox-kinetic parameters at poly(o-phenylenediamine) modified electrodes upon the oxidation and protonation levels of the polymer T.Komura, Y. Funahashi, T.Yamaguchi, K.Takahashi JOURNAL OF ELECTROANALYTICAL CHEMISTRY 446 113-123 1998
  •  Dioxygen-Activated Reductive Epoxidation of Cyclohexene Using Mn(III) Porphyrin as Catalyst and Hexylviologen as Electron Mediator Y. Tsuda, K. Takahashi, T.Yamaguchi, S.Matsui, T.Komura, I. Nishiguchi JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 138 145-153 1999
  •  Direct electrochemistry of cytochrome c at a glassy carbon electrode covered with a microporous alumina memmbrane O.Ikeda, M.Ohtani, T. Yamaguchi, T.Komura ELECTROCHIMICA ACTA 43 8 833-839 1998
  •  Electrocatalytic oxidation of NADH at polythionine-modified electrodes as studied by rotating disk voltammetry W.Wang, T.Komura, T.Yamaguchi, K.Takahashi ELECTROCHEMISTRY 69 3 165-170 2001/03
  •  Electrochemical Characteristics of Viologen Carboxylic Acid Derivatives Assembled onto Au Electrode as a Synthetic Receptor for Electron-Rich Compounds T. Yamaguchi, K. Takahashi, T. Komura ELECTROCHIMICA ACTA 46 16 2527-2535 2001/05
  •  Electrochemical growth and charge-transport properties of polyaniline/polystyrenesulfonate composite films T. Komura, T. Mori, T. Yamaguchi, K. Takahashi Bull. Chem. Soc. Jpn 73 19-27 2000
  •  Electron and ion transport in polypyrrole/ polystyrenesulfonate composite films T.Komura, S. Goishihara, T.Yamaguchi, K.Takahashi JOURNAL OF ELECTROANALYTICAL CHEMISTRY 456 121-129 1998
  •  Electrostatic binding and release: incorporation of IrCl63- into polypyrrole containing viologen groups T.Komura K.Kijima, T.Yamaguchi, K.Takahashi JOURNAL OF ELECTROANALYTICAL CHEMISTRY 486 2 166-174 2000/05
  •  Electrostatic Incorporation of Alizarin Red S into Poly(1-methyl-3- (pyrrol-1-ylmethyl) pyridinium) film T. Yamaguchi, Y.Yokono, K. Takahashi, T. Komura ELECTROCHIMICA ACTA 47 11 1713-1719 2002/03
  •  Electrostatic incorporation of anthraquinonesulfonate ions into a polypyrrole film containing pyridinium groups T.Komura, Y. Mori, T.Yamaguchi, K.Takahashi ELECTROCHIMICA ACTA 42 6 985-991 1997
  •  Enhanced photocurrent in Al/porphyrin Schottky barrier cell with heterodimer consisting of metal-free porphyrin and zinc porphyrin K. Takahashi, T. Goda, T. Yamaguchi, T. Komura, K. Murata JOURNAL OF PHYSICAL CHEMISTRY B 103 23 4868-4875 1999
  •  Enhanced photocurrent quantum yield by electronic interaction between zinc porphyrin and rhodamine B molecules in Al/dye/Au sandwich-type solar cell K. Takahashi, J. Nakamura, T. Yamaguchi, T. Komura, S. Ito, K. Murata JOURNAL OF PHYSICAL CHEMISTRY B 101 6 991-997 1997
  •  Enhanced quantum yield in porphyrin/electron-donor double-layer solar cells K. Takahashi, S. Nakatani, T. Yamaguchi, T. Komura, S. Ito, K. Murata SOLAR ENERGY MATERIALS AND SOLAR CELLS 45 1 127-139 1997
  •  Enhanced rate of the redox reaction of indigodisulfonate at electrodes coated with Poly[1-Methyl-3-(pyrrol-1-ylmethyl)pyridinium] chloride films T.Komura, T. Kobayashi, T.Yamaguchi, K.Takahashi JOURNAL OF ELECTROANALYTICAL CHEMISTRY 454 145-153 1998
  •  Incorporation of 1,1'-dibenzyl-4,4'-bipyridinium cation into Nafion films and charge transport in loaded film electrodes T.Komura, T.Yamaguchi, H.Sato, H.Shimatani, K.Takahashi ELECTROCHIMICA ACTA 46 23 3579-3588 2001/08
  •  Increased redox-reaction rate of quinhydrone at N-substituted polypyrrole film electrodes T.Komura, T. Kobayashi, T. Yamaguchi, K.Takahashi BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 70 5 1061-1067 1997/05
  •  pH-dependent binding interaction between functionalized thiol monolayers and electroactive ions T.Komura, T.Yamaguchi, K.Takahashi, H.Terasawa JOURNAL OF ELECTROANALYTICAL CHEMISTRY 481 2 183-191 2000/02
  •  Photocurrent increment in organic solar cell with mixed solid of merocyanine and zinc porphyrin K. Takahashi, M. Higashi, Y. Tsuda, T. Yamaguchi, T. Komura, S. Ito, K. Murata THIN SOLID FILMS 333 256-263 1998
  •  Photoinduced electron transfer from porphyrin to C60 in a C60|porphyrin double-layer photoelectrochemical cell K. Takahashi, K. Etoh, Y. Tsuda, T. Yamaguchi, T. Komura, S. Ito, K. Murata JOURNAL OF ELECTROANALYTICAL CHEMISTRY 426 1 85-90 1997
  •  Three-layer organic solar cell with high-power conversion efficiency of 3.5% K. Takahashi, N. Kuraya, T. Yamaguchi, T. Komura, K. Murata SOLAR ENERGY MATERIALS AND SOLAR CELLS 61 403-416 2000
  •  Voltammetric behavior of 1,2-dihydroxy-anthraquinones attached to glassy carbon electrodes and their surface complexation with copper T.Komura, S.Isogai, T.Yamaguchi, K.Takahashi JOURNAL OF ELECTROANALYTICAL CHEMISTRY 490 1 70-78 2000/08
  •  Dioxygen-activated Reductive Epoxidation of Cyclohexene Using Mn(III) Porphyrin-viologen Catalytic Systems Y. Tuda, K. Takahashi, T. Yamaguchi, S. Matsui, T. Komura,Nishiguchi Journal of the Chemical Society of Japan, Chemistry and Industrial Chemistry 9 581-590 1998/09
  •  Electron transfer rate of redox ion controlled by electrostatic interaction with bilayer films assembled using thiolate-copper ion-carboxylate bridges T. Yamaguchi, R.Sakai, K. Takahashi, T. Komura ELECTROCHIMICA ACTA 48 5 589-597 2003/01
  •  pH-dependent binding interaction between thiol monolayers having terminal amino group and indigo ion T.Yamaguchi, T.Komura, K.Takahashi, Y. Endo Electrode Processes VII PV 2004-18 294-302 2005/09
  •  Interfacial charge-transfer resistance at ionizable thiol monolayer-modified gold electrodes as studied by impedance spectroscopy T. Komura, T. Yamaguchi, H. Shimatani, R. Okushio ELECTROCHIMICA ACTA 49 4 597-606 2004/02
  •  Efficiency Increase by Insertion of Electrodeposited CuSCN Layer into ITO/Organic Solid Interface in Bulk Hetero-junction Solar Cells Consisting of Polythiophene and Fullerene K. Takahashi, S.Suzaka, Y.Sigeyama, T.Yamaguchi, J.Nakamura, K.Murata CHEMISTRY LETTERS 36 6 762-763 2007
  •  Electrocatalytic Activity of Electropolymerized Meldola's blue toward Oxidation of Dopamine T.Yamaguchi, T.Komura, S.Hayashi, M.Asano, G.Y. Niu, K.Takahashi ELECTROCHEMISTRY 74 1 32-44 2006
  •  Voltammetric and Impedance Study of Interaction of Indigo Ion with Thiol Monolayers having Terminal Amino Groups Modified Gold Electrode T.Yamaguchi, Y.Endo, T.Komura, K.Takahashi ELECTROCHEMISTRY 74 1 59-64 2006
  •  Perfomance improvement by inserting an electrodeposited ZnO into ITO/organic solid interface in organic solid-state solar cells K. Takahashi, T.Nishi, S.Suzaka, Y.Sigeyama, T.Yamaguchi, J.Nakamura, K.Murata CHEMISTRY LETTERS 34 6 768-769 2005/06
  •  Perfomance enhancement by blending merocyanine photosensitizer in TiO2/polythiophen solid-state solar cells K. Takahashi, T.Nakanishi, T.Yamaguchi, J.Nakamura, K.Murata CHEMISTRY LETTERS 34 5 714-715 2005/05
  •  Coupled electron-proton transport in electropolymerized methylene blue and the influences of its protonation level on the rate of electron exchange with Β-nicotinamide adenine dinucleotide T. Komura, G.Y. Niu, T. Yamaguchi, M. Asano, A. Matsuda ELECTROANALYSIS 16 21 1834-1843 2004/07
  •  Performance enhancement by blending an electron acceptor in TiO2/polyphenylenevinylene/Au solid-state solarcells K.Takahashi, K. Seto, T.Yamaguchi, J. Nakamura, C. Yokoe, K. Murata CHEMISTRY LETTERS 33 8 1042-1043 2004/08
  •  Redox properties of anion-exchangeable polypyrrole substituted by (ferrocenylmethyl) ammonium groups and their binding T.Komura,T.Yamaguchi,E.Kunitani,Y.Endo JOURNAL OF ELECTROANALYTICAL CHEMISTRY 557 49-58 2003/10
  •  Redox and ionic-binding switched fluorescence of phenosafranine and thionine included in Nafion films T.Komura,G.Y.Niu,T.Yamaguchi,M.Asano ELECTROCHIMICA ACTA 48 6 631-639 2003/02
  •  Sensitization effect by porphyrin in polythiophene/perylene dye two-layer solar cells K.Takahashi, I. Nakajima, K. Imoto, T.Yamaguchi, T.Komura, K. Murata SOLAR ENERGY MATERIALS AND SOLAR CELLS 76 115-124 2003
  •  Sensitization effect of porphyrin dye on the photocurrent of Al/polythiophene schottky-barrier cells K.Takahashi, M. Asano, K. Imoto, T.Yamaguchi, T.Komura, J. Nakamura, K. Murata JOURNAL OF PHYSICAL CHEMISTRY B 107 1646-1652 2003
  •  Merocyanine dye-sensitization of polythiophene in a conjugated polymer/TiO2 p-n hetero-junction solar cell K. Imoto, K. Takahashi, T. Yamaguchi, T. Komura, J. Nakamura, K. Murata BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 76 12 2277-2283 2003/12
  •  Activated carbon counter electrode for dye-sensitized solar cell K. Imoto, M. Suzuki, K. Takahashi, T. Yamaguchi,T. Komura, J. Nakamura, K. Murata ELECTROCHEMISTRY 71 11 944-946 2003/11
  •  Irreversible transformation of polypyrrole-bound viologen with two-electron reduction in acidic aqueous solutions T.Komura, T.Yamaguchi, K.Furuta, K.Shirono JOURNAL OF ELECTROANALYTICAL CHEMISTRY 534 2 123-130 2002/10
  •  Inclusion complexation of (11-ferrocenylundecyl)trimethylammonium bromide by β-cyclodextrin and its effects on electrochemical behavior of the surfactant T.Komura, T.Yamaguchi, K.Noda, S.Hayashi ELECTROCHIMICA ACTA 47 20 3315-3325 2002/08
  •  Electrochemical study of the binding interaction between dihydroxybenzenesulfonates and viologen-linked polypyrrole T.Komura, T.Yamaguchi, K.Shirono, K.Kura ELECTROANALYSIS 14 12 823-832 2002/06
  •  Voltammetric and impedance study of the binding of ferrocene derivatives to a sulfonated calix[6]arene host in aqueous solution T.Komura, T.Yamaguchi, K.Kura, J.Tanabe JOURNAL OF ELECTROANALYTICAL CHEMISTRY 523 126-135 2002/04
  •  Characterization of water-soluble externally HCl-doped conducting polyaniline K.Takahashi, K. Nakamura, T.Yamaguchi, T.Komura, S. Ito, R. Aizawa, K. Murata SYNTHETIC METALS 128 27-33 2002
  •  Enhanced photocurrent by schottky-barrier solar cell composed of regioregular polythiophene with merocyanine dye K.Takahashi, K. Tsuji, K. Imoto, T.Yamaguchi, T.Komura, K. Murata SYNTHETIC METALS 130 177-183 2002
  •  Incorporation of 1,1'-ferrocene dimethanol into poly phenosafranin and a binding interaction between them T.Komura, T.Yamaguchi, M.Ishihara, G.Y.Niu JOURNAL OF ELECTROANALYTICAL CHEMISTRY 513 1 59-66 2001/10
  •  Organic solid-state solar cells with mixture of monomeric porphyrins for light-harvesting and regioregular polythiophene for charge transport K.Takahashi, T. Iwanaga, T.Yamaguchi, T.Komura, K. Murata SYNTHETIC METALS 123 91-94 2001
  •  Impedance study of charge transport at poly-o-phenylenediamine film electrode T.Komura, T.Yamaguchi, K.Takahashi ELECTROCHIMICA ACTA 41 18 2865-2870 1996
  •  Role of Hydrogen Ions in Charge Transport at Poly(o-phenylenediamine) Film Electrode T.Yamaguchi, K.Takahashi, T.Komura ELECTROCHEMISTRY 64 7 836-841 1996/07
  •  Electrochemical Characterization of Galactose Oxidase Coupled with Ferrocane Derivatives T.Yamaguchi, Y.Murakami, K.Yokoyama, T.Komura,E.Tamiya DENKI KAGAKU 63 12 1179-1182 1995/12
  •  Electrochemical Study on Mediators Coupled with Galactose Oxidase T.Yamaguchi, E.Tamiya DENKI KAGAKU 62 12 1258-1259 1994/12
  •  Problem-Based Learning in the Laboratory Course in Physical, Inorganic, and Analytical Chemistry H.Hasegawa,T.Yamaguchi,A.Ohta,T.Maki Journal of JSEE 53 1 105-108 2005
  •  Mechanistic Insights into UV-Induced Electron Transfer from PCBM to Titanium Oxide in Inverted-Type Organic Thin Film Solar Cells Using AC Impedance Spectroscopy T. Kuwabara, C. Iwata, T. Yamaguchi, K. Takahashi  ACS Applied Materials & Interfaces 2 8 2254 2010/08
  •  Inverted bulk-heterojunction organic solar cell using chemical bath deposited titanium oxide as electron collection layer T. Kuwabara, H. Sugiyama, M. Kuzuba, T. Yamaguchi, K. Takahashi  Organic Electronics 11 6 1136 2010/05
  •  Characterization of Inverted Type Organic Solar Cells with ZnO Layer as Electron Collection Electrode by ac Impedance Spectroscopy T. Kuwabara, Y. Kawahara, T. Yamaguchi, K. Takahashi  ACS Applied Materials & Interfaces 1 10 2107 2009/10
  •  Inverted Type Bulk-heterojunction Organic Solar Cell Using Electrodeposited Titanium Oxide Thin Films as Electron Collector Electrode T. Kuwabara, H. Sugiyama, T. Yamaguchi, K. Takahashi  T. Kuwabara, H. Sugiyama, T. Yamaguchi, K. Takahashi 517 13 3766 2009/04
  •  Characterization of ZnS-layer-inserted Bulk-heterojunction Organic Solar Cells by ac Impedance Spectroscopy T. Kuwabara, M. Nakamoto, Y. Kawahara, T. Yamaguchi, K. Takahashi  JOURNAL OF APPLIED PHYSICS 105 12 124513-1 2009/06
  •  Highly Durable Inverted-type Organic Solar Cell Using Amorphous Titanium Oxide as Electron Collection Electrode Inserted between ITO and Organic Layer T. Kuwabara, T. Nakayama, K. Uozumi, T. Yamaguchi, K. Takahashi  SOLAR ENERGY MATERIALS AND SOLAR CELLS 92 11 1476 2008/11
  •  Efficiency Increase by Insertion of Electrodeposited CuSCN Layer into ITO/Organic Solid Interface in Bulk Hetero-junction Solar Cells Consisting of Polythiophene and Fullerene K. Takahashi, S.Suzaka, Y.Sigeyama, T.Yamaguchi, J.Nakamura, K.Murata  CHEMISTRY LETTERS 36 6 762 2007/06
  •  Mechanistic Insights into UV-Induced Electron Transfer from PCBM to Titanium Oxide in Inverted-Type Organic Thin Film Solar Cells Using AC Impedance Spectroscopy Takayuki Kuwabara, Chiaki Iwata, Takahiro Yamaguchi, Kohshin Takahashi ACS Appled Materials & Interfaces 2 8 2254
  •  Oxygen reduction at negatively charged iron porphyrins heat-treated and bridged by alkaline-earth metal ions Takahiro Yamaguchi, Kengo Tsukamoto, Osamu Ikeda, Ryotaro Tanaka, Takayuki Kuwabara, Kohshin Takahashi ELECTROCHIMICA ACTA 55 20 6042 2010/08

Conference Presentations

Arts and Fieldwork

Patent

Theme to the desired joint research

Grant-in-Aid for Scientific Research

○「白金とは異なる酸素還元経路をもつ燃料電池用金属ポルフィリンネットワーク触媒の開発」(2012-2014) 

Classes (Bachelors)

○Laboratory Course II(2017)
○Laboratory Course II(2017)
○Electrochemistry(2017)
○Fundamental Laboratory Course in Applied Chemistry(2017)
○Fundamental Laboratory Course in Applied Chemistry(2016)
○Laboratory Course II(2016)
○Laboratory Course II(2016)
○Electrochemistry(2016)
○Fundamental Chemistry 1(2016)

Classes (Graduate Schools)

○Electrochemical Kinetics(2017)
○Electrochemical Kinetics(2017)
○Electrochemical Kinetics(2017)
○Introduction of Energy and Environmental Program(2017)
○Advanced Energy Devices(2017)
○Applied Electrochemistry(2017)
○Electrochemical Kinetics(2017)
○Applied Electrochemistry(2016)
○Electrochemical Kinetics(2016)
○Introduction of Energy and Environmental Program(2016)
○Advanced Energy Devices(2016)

International Project

International Students

Lecture themes

Others (Social Activities)

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