last modified：2024/03/12
Associate Professor Yuji Kikukawa
Faculty, Affiliation
Faculty of Chemistry, Institute of Science and Engineering
associate professor
College and School Educational Field
Division of Material Chemistry, Graduate School of Natural Science and Technology
Division of Material Chemistry, Graduate School of Natural Science and Technology
School of Chemistry, College of Science and Engineering
Laboratory
Inorganic Lab
Academic Background
【Academic background(Doctoral/Master's Degree)】
The University of Tokyo Doctor School of Engineering Applied Chemistry 201103 Completed
The University of Tokyo Master School of Engineering Applied Chemistry 200803 Completed
【Academic background(Bachelor's Degree)】
The University of Tokyo Applied Chemistry 200603
Career
Japan Science and Technology Agency(2016/10/01-2020/03/31)
Year & Month of Birth
1982/05
Academic Society
Catalysis Society of Japan
The Chemical Society of Japan
Award
○CSJ Presentation Award(2012/03)
○Inoue Research Award for Young Scientists(2013/12)
Specialities
Inorganic chemistry、Catalyst/Resource chemical process
Speciality Keywords
metal-oxide molecules, catalyst, functional materials
Research Themes
Books
Papers
- Synthesis and oxidation catalysis of a difluoride-incorporated polyoxovanadate and isolation of active vanadium alkylperoxo species Yuji Kikukawa, Yui Sakamoto, Hikari Hirasawa, Yushi Kurimoto, Hiroya Iwai, Yoshihito Hayashi Catalysis Science & Technology 2022/01/05
- Ultra-High Proton Conduction via Extended Hydrogen-Bonding Network in a Preyssler-type Polyoxometalate-Based Framework Functionalized with Lanthanide Ion Tsukasa Iwano, Kota Shitamatsu, Naoki Ogiwara, Masanari Okuno, Yuji Kikukawa, Satory Ikemoto, Sora Shirai, Satoshi Muratsugu, Paul Waddell, John, R. Errington, Masahiro Sadakane, Sayaka Uchida ACS Applied Materials & Interfaces 13 19138 2021/04/19
- Synthesis of Cyanooxovanadate and Cyanosilylation of Ketones Yuji Kikukawa, Hiroko Kawabata, Yoshihito Hayashi RSC Advances 11 31688 2021/09/27
- Incorporating highly-basic polyoxometalate anions comprising Nb or Ta into nanoscale reaction fields of porous ionic crystals Zhewei Weng, Naoki Ogiwara, Takashi Kitao, Takashi, Yuji Kikukawa, Yu Gao, Li-Kai Yan, Sayaka Uchida, Nanoscale 13 18451 2021/10/01
- Isostructural Mesoporous Ionic Crystals as a Tunable Platform for Acid Catalysis Yuto Shimoyama, Zhewei Weng, Naoki Ogiwara, Takashi Kitao, Yuji Kikukawa, Sayaka Uchida Dalton Transactions 49 10328 2020/06/05
- Induced-Fitting and Polarization of Bromine Molecule in an Electrophilic Inorganic Molecular Cavity and Its Bromination Reactivity Yuji Kikukawa, Kensuke Seto, Daiki Watanabe, Hiromasa Kitajima, Misaki Katayama, Shohei Yamashita, Yasuhiro Inada, Yoshihito Hayashi Angewandte Chemie, International Edition 59 14399 2020/06/08
- Isolation of a Nitromethane Anion in the Calix-Shaped Inorganic Cage Yuji Kikukawa, Hiromasa Kitajima, Sho Kuwajima, Yoshihito Hayashi Molecules 25 5670 2020/12/01
- Redox active mixed-valence hexamanganese double-cubane complexes supported by tetravanadates Tatsuya Maruyama, Akimi Namekata, Hiroshi Sakiyama, Yuji Kikukawa, Yoshihito Hayashi New Journal of Chemistry 43 17703 2019/07/23
- Evaluation of Chemo- and Shape-Selective Association of a Bowl-Type Dodecavanadate Cage with an Electron-Rich Group Yuji Kikukawa, Hiromasa Kitajima, Yoshihito Hayashi Dalton Transactions 48 7138 2019/04/04
- Solid State Umbrella-type Inversion of a VO5 Square Pyramidal Unit in a Bowl-type Dodecavanadate Induced by Insertion and Elimination of a Guest Molecule Yuji Kikukawa, Kensuke Seto, Sayaka Uchida, Sho Kuwajima, Yoshihito Hayashi Angewandte Chemie, International Edition 57 16051-16055 2018/10/15
- Synthesis and structural characterization of tube type tetradecavanadates Sho Kuwajima, Yuta Arai, Hiromasa Kitajima, Yuji Kikukawa, Yoshihito Hayashi Acta Crystallographica Section C 74 1295-1299 2018/11/01
- Synthesis and Characterization of Yttrium-containing Sandwich-, Ring-, and Cage-type Polyoxovanadates Tatsuya Maruyama, Hiroko Kawabata, Yuji Kikukawa, Yoshihito Hayashi European Journal of Inorganic Chemistry 2019 3-4 529-533 2018/08/09
- Synthesis and Characterization of a Palladium-Supported Fluoride-Incorporated Dodecavanadate Miftahul Khair, Yuji Kikukawa, Yoshihito Hayashi Chemistry Letters 46 1406-1408 2017/07/12
- A Highly-flexible Cyclic-decavanadate Ligand for Interconversion of Dinuclear- and Trinuclear-cobalt(II) and Manganese(II) Cores Tatsuya Maruyama, Yuji Kikukawa, Hiroshi Sakiyama, Misaki Katayama, Yasuhiro Inada, Yoshihito Hayashi RSC Advances 7 37666-37674 2017/08/01
- Water- and Temperature-Triggered Reversible Structural Transformation of Tetranuclear Cobalt(II) Cores Sandwiched by Polyoxometalates Yosuke Kuriyama, Yuji Kikukawa, Kosuke Suzuki, Kazuya Yamaguchi, Noritaka Mizuno Chemistry A European Journal 22 3962-3966 2016/02/05
- A Bowl-Type Dodecavanadate as a Halide Receptor Sho Kuwajima, Yuka Ikinobu, Daiki Watanabe, Yuji Kikukawa, Yoshihito Hayashi, Atsushi Yagasaki ACS Omega 2 268-275 2017/01/26
- Synthesis and Structural Characterization of Trimanganese-Containing Polyoxovanadates with Carboxylate Ligands Tatsuya Maruyama, Yuji Kikukawa, Keisuke Kawamoto, Yoshihito Hayashi European Journal of Inorganic Chemistry 2017 596-599 2017/01/18
- Small Molecular Anion Recognition by a Shape-responsive Bowl-Type Dodecavanadate Sho Kuwajima, Yuji Kikukawa, Yoshihito Hayashi Chemistry-An Asian Journal 2017/04/22
- Chloride capturing system via proton-induced structure transformation between opened- and closed-forms of dodecavanadates Yoshitaka Inoue, Yuji Kikukawa, Sho Kuwajima, Yoshihito Hayashi Dalton Transaction 45 7563-7569 2016
- Synthesis and oxidation catalysis of a Ti-substituted phosphotungstate, and identification of the active oxygen species Eri Takahashi, Keigo Kamata, Yuji Kikukawa, Sota Sato, Kosuke Suzuki, Kazuya Yamaguchi, Noritaka Mizuno Catalysis Science & Technology 5 4778-4789 2015
- Structure Transformation among Deca-, Dodeca- and Tridecavanadates and Their Properties for Thioanisole Oxidation Yuji Kikukawa, Kazuhiro Ogihara, Yoshihito Hayashi Inorganics 3 295-308 2015
- Layered Assemblies of Dialuminum-Substituted Silicotungstate Trimer and the Reversible Interlayer Cation-Exchange Properties Yuji Kikukawa, Kazuya Yamaguchi, Mitsuhiro Hibino, Noritaka Mizuno Inorganic Chemistry 50 12411-12413 2011
- Synthesis and characterization of fluoride-incorporated polyoxovanadates Yuji Kikukawa, Taiga Yokoyama, Sanae Kashio, Yoshihito Hayashi Journal of Inorganic Biochemistry 147 221-226 2015
- Hydrogen Evolution Using the Visible-Light-Induced Metal-to-Polyoxometalate Multiple Electron Transfer Kosuke Suzuki, Fei Tang, Yuji Kikukawa, Kazuya Yamaguchi, Noritaka Mizuno Chemistry Letters 43 1429-1431 2014
- Visible Light-Induced Photoredox Catalysis of a Tetracerium-Containing Silicotungstate Kosuke Suzuki, Fei Tang, Yuji Kikukawa, Kazuya Yamaguchi, Noritaka Mizuno Angewandte Chemie, International Edition 53 5356-5360 2014
- Synthesis, Structure Characterization, and Reversible Transformation of a Cobalt Salt of a Dilacunary γ-Keggin Silicotungstate and Sandwich-Type Di- and Tetra-Cobalt-Containing Silicotungstate Dimers Yuji Kikukawa, Kosuke Suzuki, Kazuya Yamaguchi, Noritaka Mizuno Inorganic Chemistry 52 8644-8652 2013
- A Discrete Octahedrally Shaped [Ag6]4+ Cluster Encapsulated within Silicotungstate Ligands Yuji Kikukawa, Yoshiyuki Kuroda, Kosuke Suzuki, Mitsuhiro Hibino, Kazuya Yamaguchi, Noritaka Mizuno Chemical Communications 49 376-378 2013
- Strategic Design and Refinement of Lewis Acid-Base Catalysis by Rare-Earth-Metal-Containing Polyoxometalates Kosuke Suzuki, Midori Sugawa, Yuji Kikukawa, Keigo Kamata, Kazuya Yamaguchi, Noritaka Mizuno Inorganic Chemistry 51 6953-6961 2012
- Cyanosilylation of Carbonyl Compounds with Trimethylsilyl Cyanide by an Yttrium-Pillared Silicotungstate Dimer” Yuji Kikukawa, Kosuke Suzuki, Midori Sugawa, Tomohisa Hirano, Keigo Kamata, Kazuya Yamaguchi, Noritaka Mizuno Angewandte Chemie International Edition 51 3686-3690 2012
- Three-Dimensional Ordered Arrays of 58 x 58 x 58 A3 Hollow Frameworks in Ionic Crystals of M2Zn2-Substituted Polyoxometallates Kosuke Suzuki, Yuji Kikukawa, Sayaka Uchida, Hiroko Tokoro, Kenta Imoto, Shin-ichi Ohkoshi, Noritaka Mizuno Angewandte Chemie International Edition 51 1597-1601 2012
- Diamond-Shaped [Ag4]4+ Cluster Encapsulated with Silicotungstate Ligands: Synthesis and the Catalysis for Hydrolytic Oxidation of Silanes Yuji Kikukawa, Yoshiyuki Kuroda, Kazuya Yamaguchi, Noritaka Mizuno Angewandte Chemie International Edition 51 2434-2437 2012
- Sandwich-Type Zinc-Containing Polyoxometalates with a Hexaprismane core [{Zn2W(O)O3}2]4+: Synthesized by Thermally-Induced Isomerization of a Metastable Polyoxometalate Yuji Kikukawa, Kazuya Yamaguchi, Noritaka Mizuno Inorganic Chemistry 49 8194-8196 2010
- Zinc(II) Containing γ-Keggin Sandwich-Type Silicotungstate: Synthesis in Organic Media and Oxidation Catalysis Yuji Kikukawa, Kazuya Yamaguchi, Noritaka Mizuno Angewandte Chemie International Edition 49 6096-6100 2010
- Synthesis of a Dialuminum-Substituted Silicotungstate and the Diastereoselective Cyclization of Citronellal Derivatives Yuji Kikukawa, Syuhei Yamaguchi, Yoshinao Nakagawa, Kazuhiro Uehara, Sayaka Uchida, Kazuya Yamaguchi, Noritaka Mizuno Journal of the American Chemical Society 130 15872-15878 2008
- Synthesis and Catalysis of Di- and Tetra-nuclear Metal Sandwich-type Silicotungstate [(γ-SiW10O36)2M2(μ-OH)2]10- and [(γ-SiW10O36)2M4(μ4-O)(μ-OH)6]8- (M = Zr or Hf) Yuji Kikukawa, Syuhei Yamaguchi, Kazutaka Tsuchida, Yoshinao Nakagawa, Kauhiro Uehara, Kazuya Yamaguchi, Noritaka Mizuno Journal of the American Chemical Society 130 5472-5478 2008
- Synthesis and Structural Characterization of a γ-Keggin-Type Dimeric Silicotungstate with a Bis(μ-hydroxo) Dizirconium Core [(γ-SiW10O36)2Zr2(μ-OH)2]10- Syuhei Yamaguchi, Yuji Kikukawa, Kazutaka Tsuchida, Yoshinao Nakagawa, Kazuhiro Uehara, Kazuya Yamaguchi, Noritaka Mizuno Inorganic Chemistry 46 8502-8504 2007
- Culture and Leukocyte Adhesion Assay of Human Arterial Endothelial Cells in a Glass Microchip Yo Tanaka, Yuji Kikukawa, Kae Sato, Yasiko Sugii, Takehiko Kitamori Analytical Sciences 23 261-266 2007
- Synthesis of Copper-Substituted Polyoxovanadate and Oxidation of 1-Phenyl Ethanol Isshin Yoshida, Ryoji Mitsuhashi, Yuji Kikukawa, Yoshihito Hayashi Inorganics 12 61 2024/02/19
- Mechanistic insights into template-driven polyoxovanadate selfassembly: the role of internal and external templates Stefan Repp, Kim Lara Junginger, Dieter Sorsche, Theresa Zorn,b Ann-Christin Pöppler, Yuji Kikukawa, Yoshihito Hayashi, Carsten Streb Dalton Transactions 2023/02/16
- Vanadium-substituted polycationic Al-oxo cluster in a porous ionic crystal exhibiting Lewis acidity Wei Zhou, Naoki Ogiwara, Zhewei Weng, Congcong Zhao, Likai Yan, Yuji Kikukawa, Sayaka Uchida Chemical Communications 58 12548-12551 2022/10/11
- Hydrophobic interaction of V12 bowl-type dodecavanadates with alkyl ammonium cations Hiroya Iwai, Tsuyoshi Kasamatsu, Sho Kuwajima, Yuji Kikukawa, Yoshihito Hayashi Polyhedron 224 115985 2022/06/18
- Basicity of isostructural porous ionic crystals composed of Nb/Ta-substituted Keggin-type polyoxotungstates Zhewei Weng, Naoki Ogiwara, Daisuke Yokogawa, Takashi Kitao, Yuji Kikukawa, Sayaka Uchida Dalton Transactions 51 8186-8191 2022/04/21
Conference Presentations
- Lid effect of an organic cation on the host-guest property of the vanadate bowl(2022/09/27)
- HOST-GUEST CHEMISTRY OF A HALF SPHERICAL DODECAVANADATE AND ITS REACTIVITY(conference：International Conference on Coordination Chemistry)(2022/08/30)
- Synthesis and catalysis of a peroxo-vanadium structure on a fluoride-containing polyoxovanadate(conference：The 9th Tokyo Conference on Advanced Catalytic Science and Technology )(2022/07/29)
- Synthesis and Oxidation Catalysis of Difluoride-Containing Polyoxovanadates(conference：8th Asian Conference on Coordination Chemistry)(2022/08/08)
- Interaction of a Hydrophobic Cation and a Bowl-type Dodecavanadate Complexes(conference：8th Asian Conference on Coordination Chemistry)(2022/08/08)
- 中性分子内包ポリオキソバナデートと中空ポリオキソバナデートの合成(2022/03/25)
- Synthesis and Catalysis of Nitrate-incorporated polyoxovanadates(2022/02/25)
- Synthesis and Oxidation Catalysis of Fluoride-Containing Polyoxovanadates (2021/12/18)
- Synthesis and catalysis of Tricyanodioxidevanadate(2021/09/18)
- Imposing Trigonal Symmetry in Mononuclear HexaMonodentate Complexes with 3d-Metal Ions(2021/09/17)
- Synthesis and Oxidation Catalysis of Molecular Fluorovanadates (conference：Global Catalysis & Applied Chemical Engineering)(2021/08/12)
- Anion receptor property of a Dodecavanadate(conference： International Network on Polyoxometalate Science for Advanced Functional Energy Materials )(2021/07/19)
- Host-Guest Chemistry of Inorganic Molecular Container and Its Reactivity(conference： The 1st Irkutsk Kanazawa University joint sakigake-symposium in chemistry)(2021/01/27)
- Reactivity of a Bromine Molecule Included in a Half-Spherical Vanadium-Oxide Molecule(2021/06/26)
- SYNTHESIS AND OXIDATION CATALYSIS OF FLUORIDE-CONTAINING POLYOXOVANADATES(conference：The 8th Asia-Pacific Congress on Catalysis )(2019/08/05)
- Synthesis and Characterization of Multinuclear Cobalt Containing Polyoxovanadates(2019/10/17)
- Host-Guest Interaction Inducing a Structure Conversion of a Bowl-Type Dodecavanadate(2019/10/17)
- Structure Transformation and Host Property of a Dodecavanadate(conference：7th Asian Conference on Coordination Chemistry)(2019/10/17)
- Host-guest property of half spherical type dodecavanadates(conference：The 8th Tokyo Conference on Advanced Catalytic Science and Technology)(2018/08/05)
- Synthesis and Characterization of Fluoride-incorporated Polyoxovanadates(conference：International symposium on Metal-Oxo Cluster Sciences: Exploring Novel Possibilities)(2018/08/05)
- Host-Guest Property and Reversible Structure Transformation of Dodecavanadates(conference：43rd International Conference on Coordination Chemistry)(2018/07/31)
- Structure adaptation of yttrium containing polyoxovanadates(conference：43rd International Conference on Coordination Chemistry)(2018/07/31)
- Synthesis and Catalysis of a Titanium-Containing Polyoxovanadate (2017/03/16)
- Host Property for the Neutral Molecule Guest of the Bowl-type Dodecavanadate (2016/09/10)
- Halide Incorporation Reaction into a Bowl-Type Dodecavanadate(conference：The 10th International Vanadium Symposium)(2016/11/06)
- Synthesis of Di- and Trinuclear Manganese Cores Surrounded by Circular Decavanadates(conference：The 10th International Vanadium Symposium)(2016/11/06)
- The Movement of the Vanadium-oxygen Mitt(conference：The 10th International Vanadium Symposium)(2016/11/06)
- An Yttrium-Containing Polyoxovanadate for Cyanosilylation of Carbonyl Compounds(conference：20th The International Symposium on Homogeneous Catalysis)(2016/07/12)
Others
Arts and Fieldwork
Patent
Theme to the desired joint research
Grant-in-Aid for Scientific Research
Competitive research funding,Contribution
Collaborative research,Consignment study
Classes (Bachelors)
○Inorganic Chemistry B(2023)
○Inorganic Chemistry A(2023)
○Research Work in Chemistry(2023)
○Specialized Topics in Chemistry(2023)
○Specialized Topics in Material Chemistry(2023)
○Experiments in Basic Chemistry B(2023)
○Literature Survey in Chemistry(2023)
○Experiments in Basic Chemistry B(2023)
○GS English Language for Undergraduates II (English for Science and Engineering)(2023)
○GS English Language for Undergraduates I (English for Science and Engineering)(2023)
○Experiments in Fundamental Chemistry(2023)
○Experiments in Fundamental Chemistry(2023)
○Experiments in Basic Chemistry A(2022)
○Inorganic Chemistry B(2022)
○Experiments in Basic Chemistry B(2022)
○Experiments in Basic Chemistry B(2022)
○Experiments in Basic Chemistry A(2022)
○Inorganic Chemistry A(2022)
○Experiments in Basic Chemistry B(2021)
○Chemistry for Education(2021)
○Inorganic Chemistry II(2021)
○Chemistry for Education(2021)
○International Training B(2020)
○International Training B(2020)
○International Training B(2020)
○International Training B(2020)
○Experiments in Basic Chemistry A(2020)
○Experiments in Basic Chemistry B(2020)
○Inorganic Chemistry II(2020)
○International Training A(2020)
○International Training A(2020)
○International Training A(2020)
○International Training A(2020)
○Introduction of Chemistry B(2020)
○International Training A(2019)
○Inorganic Chemistry II(2019)
○International Training B(2019)
○International Training B(2019)
○International Training B(2019)
○Presentation and Debate (Freshman Seminar II)(2019)
○International Training A(2019)
○Experiments in Basic Chemistry B(2019)
○International Training B(2019)
○International Training A(2019)
○International Training A(2019)
○Experiments in Basic Chemistry B(2018)
○Experiments in Basic Chemistry B(2017)
○Experiments in Basic Chemistry B(2016)
Classes (Graduate Schools)
○Functional Molecule Chemistry(2023)
○Material Creation Chemistry II(2023)
○Inorganic Structural Chemistry(2023)
○Laboratory Rotation I(2023)
○Laboratory Rotation I(2023)
○Seminar in Material Creation(2017)
○Seminar in Material Creation(2017)
○Seminar in Material Creation(2016)
○Seminar in Material Creation(2016)