Associate Professor FURUYAMA, Taniyuki
Faculty, Affiliation
Nanomaterials Research Institute
College and School Educational Field
Division of Material Chemistry, Graduate School of Natural Science and Technology
Division of Material Chemistry, Graduate School of Natural Science and Technology
School of Chemistry, College of Science and Engineering
Laboratory
Photofunctional Materials Synthesis Group TEL:076-234-4786
Academic Background
【Academic background(Doctoral/Master's Degree)】
The University of Tokyo Doctor Graduate School of Pharmaceutical Sciences 201003 Completed
【Academic background(Bachelor's Degree)】
The University of Tokyo 200503
【Degree】
Ph. D. (Pharmaceutical Sciences)
Career
JST PRESTO Researcher(2018/10/01-2022/03/31)
Tohoku University Graduate School of Science Assistant Professor(2010/07-2015/10)
RIKEN Advanced Elements Chemistry Lab. Research Scientist(2010/04-2010/06)
Year & Month of Birth
1982/06
Academic Society
Chemical Society of Japan
Pharmaceutical Society of Japan
Society of Synthetic Organic Chemistry of Japan
The Society of Physical Organic Chemistry of Japan
Society of Porphyrins & Phthalocyanines
The Japanese Photochemistry Association
Award
○SPP/JPP Young Investigator Awards (2022/07/13)
○The Young Scientists’ Award, The Commendation for Science and Technology(2022/04/20)
○The Young Scientists’ Award, The Commendation for Science and Technology(2022/04/20)
○International Conference on Porphyrins and Phthalocyanines 2018 The Best Oral Presentation(2018/07/06)
○Takasago International Corporation Award in The Society of Synthetic Organic Chemistry(2017/12/11)
○The Pharmaceutical Society of Japan Award for Young Scientists '17(2017/03/24)
○PCCP Prize 2015(2015/03)
○CSJ Presentation Award 2013(2013/04)
○Young Scholar Lectures of CSJ-95(2015/03)
Specialities
Physical Organic Chemistry、Functional solid state chemistry、Chemical pharmacy
Speciality Keywords
Synthetic organic chemistry, Main group element chemistry, Phthalocyanine
Research Themes
Books
Papers
- Direct Near Infrared Light–Activatable Phthalocyanine Catalysts Yoshino Katsurayama,Yasuhiro Ikabata,Hajime Maeda,Masahito Segi,Hiromi Nakai,Taniyuki Furuyama Chemistry – A European Journal 28 2 e202103223 2022/01/10
- Red-light-activatable ruthenium phthalocyanine catalysts Yuta Ishikawa,Tatsuya Kameyama,Tsukasa Torimoto,Hajime Maeda,Masahito Segi,Taniyuki Furuyama Chemical Communications 57 99 13594 2021/11
- Direct Excitation of Triplet State of Molecule by Enhanced Magnetic Field of Dielectric Metasurfaces Hiroshi Sugimoto,Hiroaki Hasebe,Taniyuki Furuyama,Minoru Fujii Small 17 47 2104458 2021/11
- Synthesis of homo- and heterofunctionalized bay-annulated indigo derivatives and their properties Taniyuki Furuyama,Daichi Tamura,Hajime Maeda,Masahito Segi,Masanobu Uchiyama Dyes and Pigments 193 109535 2021/09
- Fluorescent-Oxaboroles: Synthesis and Optical Property by Sugar Recognition Misaki Nakano,Rikako Nakamura,Yuto Sumida,Kazunori Nagao,Taniyuki Furuyama,Fuyuhiko Inagaki,Hirohisa Ohmiya Chemical and Pharmaceutical Bulletin 69 6 526 2021/06/01
- Synthesis and characterization of heteroleptic rare earth double-decker complexes involving tetradiazepinoporphyrazine and phthalocyanine macrocycles Ekaterina N. Tarakanova,Pavel A. Tarakanov,Anton O. Simakov,Taniyuki Furuyama,Nagao Kobayashi,Dmitry V. Konev,Olga A. Goncharova,Stanislav A. Trashin,Karolien De Wael,Ilya V. Sulimenkov,Vasily V. Filatov,Viatcheslav I. Kozlovskiy,Larisa G. Tomilova,Pavel A. Stuzhin,Victor E. Pushkarev Dalton Transactions 50 18 6245 2021
- Efficiency Enhancement of a Photocatalytic Decarbonylation of an Aminocyclopropenone by Benzothiophene Substitution Kenji Mishiro,Mitsuki Nomura,Taniyuki Furuyama,Munetaka Kunishima The Journal of Organic Chemistry 86 4 3625 2021/02/19
- Synthesis of Low-symmetry Ball-shaped Ruthenium Complexes and Fine-tuning of Their Optical Properties in the Visible and NIR Region Sari Ishikawa,Fumika Shimasaki,Hajime Maeda,Masahito Segi,Taniyuki Furuyama Chemistry Letters 49 11 1394 2020/11/05
- Temperature-dependent changes in the molecular orientation and visible color of phthalocyanine films T. Furuyama, S. Uchiyama, T. Chikamatsu, T. Horikawa, H. Maeda, M. Segi, H. Takahashi, T. Taima RSC Adv. 10 52 31348 2020/08
- Photophysical properties of silyl‐substituted stilbene derivatives H. Maeda, R. Horikoshi, M. Yamaji, T. Furuyama, M. Segi Eur. J. Org. Chem. 23 3410 2020/05
- Effects of substituents on absorption and fluorescence properties of trimethylsilylethynyl- and tert-butylethynyl-pyrenes H. Maeda, R. Ueno, T. Furuyama, M. Segi J. Photochem. Photobiol. A 392 112428 2020/04
- One-step synthesis of ball-shaped metal complexes with a main absorption band in the near-IR region T. Furuyama, F. Shimasaki, N. Saikawa, H. Maeda, M. Segi Sci. Rep. 9 16528 2019/11
- Cationic axial ligands on sulfur substituted silicon(IV) phthalocyanines: Improved hydrophilicity and exceptionally red-shifted absorption into the NIR region T. Furuyama, T. Ishii, N. Ieda, H. Maeda, M. Segi, M. Uchiyama, H. Nakagawa Chem. Commun. 55 51 7311 2019/05
- Phototriggered active alkyne generation from cyclopropenones with visible light-responsive photocatalysts K. Mishiro, T. Kimura, T. Furuyama, M. Kunishima Org. Lett. 21 11 4101 2019/05
- Chemoselective synthesis of aryloxy-substituted phthalocyanines T. Furuyama, K. Maeda, H. Maeda, M. Segi J. Org. Chem. 84 21 14306 2019/10
- Synthesis, structural and optical properties of tetrabenzoporphyrin complexes bearing four or eight peripheral phenyl groups T. Furuyama, T. Okujima, K. Muramatsu, Y. Takahashi, A. Mikami, T. Fukumura, S. Mori, T. Nakae, M. Takase, H. Uno, N. Kobayashi Eur. J. Org. Chem. 20 3224 2019/05
- Extremely photostable electron-deficient phthalocyanines that generate high levels of singlet oxygen T. Furuyama, Y. Miyaji, K. Maeda, H. Maeda, M. Segi Chem. Eur. J. 25 7 1678 2019/02
- Synthesis and peripheral substituent effects of bay-annulated indigo derivatives T. Furuyama, D. Tamura, H. Maeda, M. Segi Tetrahedron Lett. 59 30 2913 2018/07
- Synthesis, fluorescence properties, and conformational analysis of ether-linked (1,8)pyrenophanes H. Maeda, M. Geshi, K. Hirose, T. Furuyama, M. Segi Tetrahedron 75 37 130512 2019/09
- Electron photoejection from dianion of an expanded phthalocyanine Y. H. Koo, R. Yanagisawa, W.-Y. Cha, T. Furuyama, N. Kobayashi, D. Kim J. Porphyrins Phthalocyanines 22 5 437 2018/05
- (1,3)Pyrenophanes containing crown ether moieties as fluorescence sensors for metal and ammonium ions H. Maeda, K. Nakamura, T. Furuyama, M. Segi Photochem. Photobiol. Sci. 18 10 2397 2019/07
- Changes of phthalocyanine visible color caused by near-IR solvatochromism T. Furuyama, S. Uchiyama, T. Iwamoto, H. Maeda, M. Segi J. Porphyrins Phthalocyanines 22 1-3 88 2018/01
- D-A-D type dinitriles with vapor-dependent luminescence in the solid state T. Furuyama, J. Shinozaki, T. T. Tasso, H. Maeda, M. Segi, N. Kobayashi Tetrahedron Lett. 58 45 4243 2017/11
- Synthesis and electronic properties of meso-tetra(3,4,5-trimethoxy)phenyl-porphyrin and -tetrabenzoporphyrin and their phosphorus complexes T. Furuyama, Y. Takahashi, T. Fukumura, A. C. C. Bacilla, N. Kobayashi J. Porphyrins Phthalocyanines 24 1-3 105 2019/06
- Azaporphyrin Phosphorus(V) Complexes: Synthesis, Structure, and Modification of Optical Properties T. Furuyama, N. Kobayashi Phys. Chem. Chem. Phys. 19 24 15596 2017/05
- Structural, photophysical, and magnetic circular dichroism studies of three rigidified meso-pentafluorophenyl-substituted hexaphyrin analogues M. Ishida, T. Furuyama, J. M. Lim, S. Lee, Z. Zhang, S. K. Ghosh, V. M. Lynch, C.-H. Lee, N. Kobayashi, D. Kim, J. L. Sessler Chem. Eur. J. 23 27 6682 2017/05
- Simple primary β-amino alcohol catalyzed enantioselective Diels-Alder reaction of 3-hydroxy-2-pyridones T. Takahashi, U. V. S. Reddy, Y. Kohari, C. Seki, T. Furuyama, N. Kobayashi, Y. Okuyama, E. Kwon, K. Uwai, M. Tokiwa, M. Takeshita, H. Nakano Tetrahedron Lett. 57 51 5771 2016/12
- Formation of a trithia[5]helicene in an unexpected photoreaction of a methyl-substituted bis(dithienylethenyl)thiophene through a double sequence of 6-electrocyclization/aromatization (dehydrogenation/demethylation) A. Yamamoto, Y. Matsui, E. Ohta, T. Ogaki, H. Sato, T. Furuyama, N. Kobayashi, K. Mizuno, H. Ikeda J. Photochem. Photobiol. A 331 1 48 2016/12
- Synthesis of meta-methoxyphenyl substituted tetraazaporphyrin and corrolazine phosphorus(V) complexes T. Furuyama, Y. Sugiya, T. Yoshida, N. Kobayashi J. Porphyrins Phthalocyanines 20 8-11 1075 2016/12
- Double-decker Bis(tetradiazepinoporphyrazinato) Rare Earth Complexes: Crucial Role of Intramolecular Hydrogen Bonding E. N. Tarakanova, S. Trashin, A. O. Simakov, T. Furuyama, A. V. Dzuban, L. N. Inasaridze, P. A. Tarakanov, P. Troshin, V. Pushkarev, N. Kobayashi, L. B. Tomilova Dalton Trans. 45 30 12041 2016/06
- Synthesis, Optical Properties, and Electronic Structures of Tetrakis(pentafluorophenyl)tetrathiaisophlorin Dioxide V. L. Mishra, T. Furuyama, N. Kobayashi, K. Goto, T. Miyazaki, J.-S. Yang, T. Shinmyozu Chem. Eur. J. 22 27 9190 2016/06
- Preparation, optical and electrochemical properties, and molecular orbital calculations of tetraazaporphyrinato ruthenium (II) bis(4-methylpyridine) fused with one to four diphenylthiophene units T. Kimura, N. Murakami, E. Suzuki, T. Furuyama, T. Nakahodo, H. Fujihara, N. Kobayashi J. Inorg. Biochem. 158 1 35 2016/01
- Synthesis and Photophysical Investigation of Tetraazaporphyrin Substituted with Aggregation-Induced Emission (AIE) Active Moieties T. T. Tasso, T. Furuyama, J. Mack, T. Nyokong, N. Kobayashi Eur. J. Inorg. Chem. 33 5516 2015/11
- A Bottom-up Synthesis of Antiaromatic Expanded Phthalocyanines: Pentabenzotriazasmaragdyrins, i.e. Norcorroles of Superphthalocyanines T. Furuyama, T. Sato, N. Kobayashi J. Am. Chem. Soc. 137 43 13788 2015/10
- Solution-Cast Monolayers of Cobalt Crown Ether Phthalocyanine on Highly Ordered Pyrolytic Graphite H. Lu, I. Kwak, J. H. Park, K. O'Neill, T. Furuyama, N. Kobayashi, A. Seabaugh, A. Kummel, S. K. Fullerton-Shirey J. Phys. Chem. C 119 38 21922 2015/08
- Fluorescence Enhancement of Tetraazaporphyrins by Use of Bulky Substituent Effects T. Yoshida, T. Furuyama, M. Asai, N. Kobayashi Chem. Lett. 44 8 1056 2015/08
- An Extremely Air-Stable 19π Porphyrinoid T. Yoshida, W. Zhou, T. Furuyama, D. B. Leznoff, N. Kobayashi J. Am. Chem. Soc. 137 29 9258 2015/07
- Reducing Zirconium(IV) Phthalocyanines and the Structure of a Pc4–Zr Complex W. Zhou, R. H. Platel, T. T. Tasso, T. Furuyama, N. Kobayashi, D. B. Leznoff Dalton. Trans. 44 31 13955 2015/06
- A Stable iso-Bacteriochlorin Mimics from Porpholactone: Effect of β-oxazolone Moiety on the Frontier π-Molecular Orbitals Y. Yu, T. Furuyama, J. Tang, Z.-Y. Wu, J.-Z. Chen, N. Kobayashi, J.-L. Zhang Inorg. Chem. Front. 2 7 671 2015/06
- Metallophthalocyanin-ocenes: Scandium Phthalocyanines with an η5-bound Cp Ring R. H. Platel, T. T. Tasso, W. Zhou, T. Furuyama, N. Kobayashi, D. B. Leznoff Chem. Commun. 51 27 5986 2015/03
- Dinitriles Having AIE-Active Moieties: Synthesis, E/Z Isomerization and Fluorescence Properties T. T. Tasso, T. Furuyama, N. Kobayashi Chem. Eur. J. 21 12 4817 2015/02
- Synthesis and Optical Properties of Tetraazaporphyrin Phosphorus(V) Complexes with Electron-Rich Heteroatoms T. Yoshida, T. Furuyama, N. Kobayashi Tetrahedron Lett. 56 13 1671 2015/02
- Synthesis and Spectral Properties of Nonclassical Binuclear Thienoporphyrazines T. V. Dubinina, N. E. Borisova, M. V. Sedova, L. B. Tomilova, T. Furuyama, N. Kobayashi Dyes Pigments 117 1 1 2015/02
- Structural Changes in Non-Planar Octaaryl Substituted Phthalocyanine Phosphorus Complexes T. Furuyama, R. Harako, N. Kobayashi J. Porphyrin Phthalocyanines 19 1-3 500 2015/01
- Optical, Electrochemical, and Magnetic Properties of Pyrrole- and Thiophene-Bridged 5,15-Diazaporphyrin Dimers S. Omomo, Y. Maruyama, K. Furukawa, T. Furuyama, H. Nakano, N. Kobayashi, Y. Matano Chem. Eur. J. 21 5 2003 2014/11
- Control of Absorption Properties of Tetraazaporphyrin Group 15 Complexes by Modification of their Axial Ligands T. Furuyama, M. Asai, N. Kobayashi Chem. Commun. 50 95 15101 2014/10
- Enantioselective Diels-Alder Reaction of 1,2-Dihydropyridines with Aldehydes using β-Amino Alcohol Organocatalyst Y. Kohari, Y. Okuyama, E. Kwon, T. Furuyama, N. Kobayashi, T. Otuki, J. Kumagai, C. Seki, K. Uwai, G. Dai, T. Iwasa, H. Nakano J. Org. Chem. 79 20 9500 2014/10
- Synthesis of New Chlorin e6 Trimethyl and Protoporphyrin IX Dimethyl Ester Derivatives and Their Photophysical and Electrochemical Characterizations J. C. J. M. D. S. Menezes, M. A. F. Faustino, K. T. de Oliveira, M. P. Uliana, V. F. Ferreira, S. Hackbarth, B. Röder, T. T. Tasso, T. Furuyama, N. Kobayashi, A. M. S. Silva, M. G. P. M. S. Neves, J. A. S. Cavaleiro Chem. Eur. J. 20 42 13644 2014/08
- Synthesis and Spectroscopic Properties of Chiral Binaphthyl-Linked Subphthalocyanines L. Zhao, K. Wang, T. Furuyama, J. Jiang, N. Kobayashi Chem. Commun. 50 57 7663 2014/06
- High Diastereoselection of Dissymmetric Capsule by Chiral Guest Complexation Y. Tsunoda, K. Fukuta, T. Imamura, R. Sekiya, T. Furuyama, N. Kobayashi, T. Haino Angew. Chem. Int. Ed. 53 28 7243 2014/06
- Synthesis of Tetrabenzotriazacorrole-Subphthalocyanine µ-Oxo Triad T. Furuyama, Y. Sugiya, N. Kobayashi Macroheterocycles 50 57 7663 2014/06
- Synthesis and Characterization of Aza-Bridged Thiophene-Pyrrole Dyads and Their Isomers T. Furuyama, D. Noguchi, Y. Suzuki, N. Kobayashi Can. J. Chem. 92 8 765 2014/03
- Phosphorus(V) Tetraazaporphyrins: Porphyrinoids Showing an Exceptionally Strong CT Band between the Soret and Q Bands T. Furuyama, T. Yoshida, D. Hashizume, N. Kobayashi Chem. Sci. 5 6 2466 2014/02
- Synthesis of Tetrabenzotriazacorrole µ-Oxo Dimer and Investigation of Its Stacking Effect T. Furuyama, Y. Sugiya, N. Kobayashi Chem. Commun. 50 33 4312 2014/02
- Design, Synthesis and Properties of Phthalocyanine Complexes with Main-Group Elements Showing Main Absorption and Fluorescence beyond 1000 nm T. Furuyama, K. Satoh, T. Kushiya, N. Kobayashi J. Am. Chem. Soc. 136 2 765 2014/01
- An Exemplary Relationship between the Extent of Cofacial Aggregation and Fluorescence Quantum Yield as Exhibited by Quaternized Amphiphilic Phthalocyanines T. T. Tasso, Y. Yamasaki, T. Furuyama, N. Kobayashi Dalton Trans. 43 15 5886 2014/01
- Absorption and Electrochemical Properties of Cobalt and Iron Phthalocyanines and Their Quaternized Derivatives: Aggregation Equilibrium and Oxygen Reduction Electrocatalysis T. T. Tasso, T. Furuyama, N. Kobayashi Inorg. Chem. 52 16 9206 2013/08
- Superazaporphyrins: Meso-Pentaazapentaphyrins and One of Their Low-Symmetry Derivatives T. Furuyama, Y. Ogura, K. Yoza, N. Kobayashi Angew. Chem. Int. Ed. 51 44 11110 2012/10
- Calix[3]amide-based Anion Receptors: High Affinity for Fluoride Ion and Twisted Binding Model K. Katagiri, T. Furuyama, H. Masu, T. Kato, M. Matsumura, M. Uchiyama, A. Tanatani, M. Tominaga, H. Kagechika, K. Yamaguchi, I. Azumaya Supramolecular Chemistry 23 1-2 125 2011/02
- A Zinc Gable Phthalocyanine and a Derived Planar Bis-phthalocyanine Containing a Shared Anthracene Unit Y. Asano, J. Sato, T. Furuyama, N. Kobayashi Chem. Commun. 48 36 4365 2012/03
- Aluminepin: Aluminum Analogues of Borepin and Gallepin K. Yoshida, T. Furuyama, C. Wang, A. Muranaka, D. Hashizume, S. Yasuike, M. Uchiyama J. Org. Chem. 77 1 729 2012/01
- Development of Mono- and Di-AcO Substituted BODIPYs on the Boron Center X.-D. Jiang, J. Zhang, T. Furuyama, W. Zhao Org. Lett. 14 1 248 2012/01
- Rationally Designed Phthalocyanines Having Their Main Absorption Band beyond 1000 nm N. Kobayashi, T. Furuyama, K. Satoh J. Am. Chem. Soc. 133 49 19642 2011/11
- Helical Chirality of Azobenzenes Induced by an Intramolecular Chiral Axis and Potential as Chiroptical Switches K. Takaishi, M. Kawamoto, K. Tsubaki, T. Furuyama, A. Muranaka, M. Uchiyama Chem. Eur. J. 17 6 1778 2011/01
Conference Presentations
Others
- Synthetic Organic Chemistry of Functional NIR Materials Taniyuki Furuyama 50 9 12 2021/09
- Development of NIR-Absorbing Organometallic Dyes Taniyuki Furuyama Photochemistry 52 1 25 2021/04
- Synthesis of Hydrophilic Silicon(IV) Phthalocyanines as a Near-infrared PDT Photosensitizer Takashi Ishii,Taniyuki Furuyama MATERIAL STAGE 1 80 2021/01
- Synthesis of Ball-shaped Metal Complexes Absorbing NIR light Taniyuki Furuyama 458 134 2020/02
Arts and Fieldwork
Patent
Theme to the desired joint research
Grant-in-Aid for Scientific Research
○「透明な近赤外色素の論理的設計」(2021-2022)
○「液中原子分解能AFM探針の革新：分子精密設計および単分子評価によるアプローチ」(2021-2022)
○「材料合成に革新をもたらす「近赤外フォトレドックス反応」の開発」(2018-2020)
○Scientific Research (C)「Developments of azaporphyrin complexes with main-group elements」(2015-2017)
○Young Scientists (B)「Development of functional oligoheteroles bearing main-group elements」(2012-2014)
Competitive research funding,Contribution
Collaborative research,Consignment study
Classes (Bachelors)
○Laboratory Course IV(2021)
○Organic Chemistry I(2021)
○Exercise I in Applied Chemistry(2021)
○Laboratory Course IV(2021)
○Problem-Based Learning I(2021)
○Problem-Based Learning I(2020)
○Laboratory Course IV(2020)
○Laboratory Course IV(2020)
○Laboratory Course IV(2019)
○Chemistry for Education(2019)
○Chemistry for Education(2019)
○Problem-Based Learning I(2019)
○Laboratory Course IV(2019)
○Problem-Based Learning I(2018)
○Laboratory Course IV(2018)
○Laboratory Course IV(2017)
○Laboratory Course IV(2017)
○Laboratory Course IV(2016)
○Laboratory Course IV(2016)
Classes (Graduate Schools)
○Introduction of Material Program(2021)
○Synthetic Chemistry of Organic Materials(2021)
○Introduction of Material Program(2021)
○Organic Functional Chemistry(2021)
○Introduction of Material Program(2020)
○Chemistry of Functional Organic Materials(2020)
○Chemistry of Functional Organic Materials(2020)
○Chemistry of Functional Organic Materials(2020)
○Chemistry of Functional Organic Materials(2020)
○Organic Functional Chemistry(2020)
○Synthetic Chemistry of Organic Materials(2020)
○Introduction of Material Program(2020)
○Synthetic Chemistry of Organic Materials(2019)
○Introduction of Material Program(2019)
○Chemistry of Functional Organic Materials(2019)
○Introduction of Material Program(2019)
○Chemistry of Functional Organic Materials(2019)
○Chemistry of Functional Organic Materials(2019)
○Chemistry of Functional Organic Materials(2019)
○Organic Functional Chemistry(2019)
○Introduction of Material Program(2018)
○Organic Functional Chemistry(2018)
○Chemistry of Functional Organic Materials(2018)
○Introduction of Material Program(2018)
○Synthetic Chemistry of Organic Materials(2018)
○Chemistry of Functional Organic Materials(2017)
○Chemistry of Functional Organic Materials(2017)
○Introduction of Material Program(2017)
○Synthetic Chemistry of Organic Materials(2017)
○Organic Functional Chemistry(2017)
○Chemistry of Functional Organic Materials(2017)
○Chemistry of Functional Organic Materials(2017)
○Synthetic Chemistry of Organic Materials(2016)
○Organic Functional Chemistry(2016)
○Chemistry of Functional Organic Materials(2016)
○Introduction of Material Program(2016)