last modified：2024/10/24
Assistant Professor SUGA, Takuya
Faculty, Affiliation
Faculty of Chemistry, Institute of Science and Engineering
College and School Educational Field
Division of Material Chemistry, Graduate School of Natural Science and Technology
Division of Material Chemistry, Graduate School of Natural Science and Technology
Course in Chemistry, School of Chemistry, College of Science and Engineering
Laboratory
Academic Background
Career
Kanazawa University Division of Material Chemistry, Graduate School of Natural Science and Technology Assistant professor(2016/03/01-)
Gakushuin University Department of Chemistry PD(2015/04/01-2016/02/28)
Year & Month of Birth
Academic Society
Award
○Ube Industries Foundation Award(2018/06/14)
○Mitsui Chemicals Award in Synthetic Organic Chemistry, Japan(2018/02/15)
○Mitsui Chemicals Award in Synthetic Organic Chemistry, Japan(2018/02/15)
○Mitsui Chemicals Award in Synthetic Organic Chemistry, Japan(2018/02/15)
Specialities
Synthetic chemistry、Organic chemistry
Speciality Keywords
Synthetic organic chemistry, Organometallic chemistry
Research Themes
Development of New Radical Reactions Utilizing Alcohols
Books
- Takuya Suga Chemistry & Chemical Industry Chemical Society, Japan 2024/09/04
Papers
- Nickel-Catalyzed Cross-Coupling Between Benzyl Alcohols and Alkenyl Triflates Assisted by Titanium-Mediated Radical C–O Bond Cleavage Takuya Suga, Miki Kondo, Yuuki Takahashi, Yutaka Ukaji Bulletin of the Chemical Society of Japan 97 2 uoad003 2023/12/01
- Molecular Transformations Based on Homolytic Cleavage of Alcohol and Ether C-O Bonds Takuya Suga, Yutaka Ukaji Journal of Synthetic Organic Chemistry, Japan 82 7 697 2024/07/01
- Directing-Group-Assisted Non-Strained Ether C–O Bond Homolysis Mediated by Low-Valent Titanium Takuya Suga, Ryusei Takada, Masaya Sakamoto, Yutaka Ukaji Organic Letters 26 11 2315 2024/03/08
- Asymmetric Hetero Diels-Alder Reaction of 4-Phenyl-1,2,3-triazole-3,5-dione with 2,4-Dienyl Carboxylic Acids Yu Sato, Takahiro Ukei, Hiromasa Tsugeno, Takuya Suga, Takahiro Soeta, Yutaka Ukaji Synthesis 55 3342 2023/07/18
- Divergent Transformation of C,N-Cyclic-N’-acyl Azomethine Imines by Diazo Compounds Haruki Ohno, Ryosuke Takahashi, Takuya Suga, Takahiro Soeta, Yutaka Ukaji Organic & Biomolecular Chemistry 21 7891 2023/08/25
- From-Neutral-to-Neutral Reductive Radical Coupling of Non-Activated Alcohols and Styrenes Takuya Suga, Chinatsu Miki, Yutaka Ukaji ChemistryEurope 2023 e202300033 2023/06/15
- Highly (E)-Selective Trisubstituted Alkene Synthesis by Low-Valent Titanium-Mediated Homolytic Cleavage of Alcohol C–O Bond Takuya Suga, Ryusei Takada, Shoma Shimazu, Mizuki Sakata, Yutaka Ukaji The Journal of Organic Chemistry 87 7487 2022/05/24
- Hydroxy Group-Directed Diastereoselective Paternò-Büchi Reaction between Arylglyoxylates and Furfuryl Alcohols Hiromi Ii, Takuya Suga, Takahiro Soeta, Hajime Maeda, Yutaka Ukaji Chemistry Letters 51 1143 2022/10/30
- Direct and Unified Access to Carbon Radicals from Aliphatic Alcohols by Cost-Efficient Titanium-Mediated Homolytic C–OH Bond Cleavage Takuya Suga, Yuuki Takahashi, Chinatsu Miki, Yutaka Ukaji Angewandte Chemie International Edition 2022 61 e202112533 2022/01/11
- Formal Methylene Insertion into the C–H Bond of α-Carbonyl Aldonitrones with Dimethylsulfoxonium Methylide Takanobu Sakurai, Tohru Yano, Takuya Suga, Takahiro Soeta, Yutaka Ukaji Bulletin of the Chemical Society of Japan 95 1518 2022/09/27
- Conjugate Addition of Acetal-Derived Benzyl Radicals Generated from Low-Valent Titanium-Mediated C–O Bond Cleavage Takuya Suga, Masaharu Nakamura, Ryusei Takada, Yutaka Ukaji Bulletin of the Chemical Society of Japan 94 1258 2021/01/20
- Synthesis of 3,6-Dihydro-2H-1,2-oxazines via Dimethylsulfoxonium Methylide Addition to α,β-Unsaturated Nitrones Megumi Hasegawa, Takuya Suga, Takahiro Soeta, and Yutaka Ukaji The Journal of Organic Chemistry 85 11258 2020/08/03
- Enantioselective Dehydroxyhydrogenation of 3-Indolylmethanols by the Combined Use of Benzothiazoline and Chiral Phosphoric Acid: Construction of a Tertiary Carbon Center Hiroto Osakabe, Shota Saito, Masamichi Miyagawa, Takuya Suga, Tatsuhiro Uchikura, Takahiko Akiyama Organic Letters 22 6 2225 2020/02/27
- One-Shot Radical Cross Coupling Between Benzyl Alcohols and Alkenyl Halides Using Ni/Ti/Mn System Takuya Suga, Yuuki Takahashi, Yutaka Ukaji Advanced Synthesis and Catalysis 362 24 5622 2020/10/02
- Rh‐Catalyzed Direct Carboxylation of Alkenyl C−H Bonds of Alkenylpyrazoles Takanobu Saitou, Yushu Jin, Kotaro Isobe, Takuya Suga, Jun Takaya, Nobuharu Iwasawa Chemistry An Asian Journal 15 13 1941 2020/05/16
- Synthesis of Optically Acitve γ-Lactams by Palladium Catalyzed Asymmetric Dicarbonylation Reaction of N-Arylsufonyl Homoallylic Amines Ryosuke Takahashi, Nga Hang Thi Phan, Takuya Suga, Takahiro Soeta, and Yutaka Ukaji Heterocycles 98 8 1044 2019/07/17
- Organic Transformations Utilizing Photo─Induced Electron Transfer of
Electron─Donor─Acceptor Complexes Takuya Suga Yuuki gousei kagaku kyoukaishi 77 4 367 2019/04/11
- Nickel-Catalyzed Cross-Electrophile Coupling between Benzyl Alcohols and Aryl Halides Assisted by Titanium Co-reductant Takuya Suga, Yutaka Ukaji Organic Letters 20 7846 2018
- Low-Valent Titanium-Mediated Radical Conjugate Addition Using Benzyl Alcohols as Benzyl Radical Sources Takuya Suga, Shoma Shimazu, Yutaka Ukaji Organic Letters 20 5389 2018
- Synthesis of Sterically Fixed Phytochrome Chromophore Derivatives Bearing a 15E-Fixed or 15E-Anti-Fixed CD-Ring Component Takahiro Soeta, Nobuhiko Ohashi, Toshiharu Kobayashi, Yoko Sakata, Takuya Suga, Yutaka Ukaji The Journal of Organic Chemistry 2018
- Niobium( v )-catalyzed defluorinative triallylation of α,α,α-trifluorotoluene derivatives by triple C–F bond activation Kodai Saito, Taishi Umi, Takayuki Yamada, Takuya Suga, Takahiko Akiyama Organic & Biomolecular Chemistry 15 1767 2017
- Palladium-catalyzed C–H Alkenylation of C-Aryl Nitrones Megumi Hasegawa, Arisa Nomoto, Takuya Suga, Takahiro Soeta, Yutaka Ukaji Chemistry Letters 46 45 2017
- Formal Total Synthesis of Manzacidin C Based on Assymmetric 1,3-Dipolar Cycloaddition of Azomethine Imines Thu Tong, Takahiro Soeta, Takuya Suga, Keisuke Kawamoto, Yoshihito Hayashi, Yutaka Ukaji The Journal of Organic Chemistry 82 1969 2017
- Mechanistic study of rhodium-catalyzed carboxylation of simple aromatic compounds with carbon dioxide Takuya Suga, Takanobu Saitou, Jun Takaya, Nobuharu Iwasawa Chemical Science 8 2 1454 2016
- Versatile and highly efficient oxidative C(sp3)–H bond functionalization of tetrahydroisoquinoline promoted by bifunctional diethyl azodicarboxylate (DEAD): scope and mechanistic insights Takuya Suga, Sunao Iizuka, Takahiko Akiyama Organic Chemistry Frontiers 3 1259 2016
- Direct Carboxylation of Simple Arenes with CO2 through a rhodium-catalyzed C-H bond activation Takuya Suga, Hajime Mizuno, Jun Takaya, Nobuharu Iwasawa Chemical Communications 50 14360 2014
- Construction of Cycohepta[b]indoles via Platinum-Catalyzed Intermolecular Formal [4+3]-Cycloaddition Reaction of a,b-Unsaturated Carbene Complex Intermediates with Siloxydienes Hiroyuki Kusama, Hideyuki Sogo, Kodai Saito, Takuya Suga, Nobuharu Iwasawa Synlett 24 1364 2013
- Platinum(II)-Catalyzed Generation and [3+2] Cycloaddition Reaction of a,b-Unsaturated Carbene Complex Intermediates for the Preparation of Polycyclic Compounds Kodai Saito, Hideyuki Sogou, Takuya Suga, Hiroyuki Kusama, Nobuharu Iwasawa Journal of The American Chemical Society 133 689 2011
Conference Presentations
- Hydroxy Group-Directed Stereoselective Paternò-Büchi Reaction of Allylic Alcohols(2023/11/17)
- Hydroxy Group-Directed Diastereoselective Paternò-Büchi Reaction of Allylic Alcohols(2023/10/20)
- Low-Valent Titanium-Mediated Alcohol C–O Bond Homolysis(conference：10th Pacific Symposium on Radical Chemistry)(2023/06/04)
- Low-Valent Titanium-Mediated Homolytic Cleavage of Alcohol C-O Bonds (conference：Dalian-Kanazawa Joint Symposium on Material Chemistry)(2022/12/16)
- Radical and Ionic Transformation Sequence Utilizing Low-valent Titanium-Mediated Homolytic C-OH Bond Cleavage(conference：The 2nd Irkutsk and Kanazawa University Chemistry Symposium)(2021/10/01)
- Hydroxy Group Directed Paternò-Büchi Reaction of Arylglyoxylates(2021/09/29)
- Low-Valent Titanium-Mediated Homolytic Cleavage of Alcohol C-O Bonds(2021/09/07)
- Low-Valent Titanium Reagent for Direct Conversion of Benzyl Alcohols to Benzyl Radicals(conference：International Congress on Pure & Applied Chemistry (ICPAC) Yangon 2019)(2019/08/06)
- Low-Valent Titanium-Mediated Radical Conjugate Addition Utilizing Acetals as Carbon Radical Sources(2019/09/27)
- Cross-Coupling Reaction between Alcohols and Alkenyl Halides via C-OH Bond Homolysis(2019/09/14)
- Low-Valent Titanium-Mediated Radical Conjugate Addition Utilizing Acetals as Carbon Radical Sources (2019/09/14)
- Low-Valent Titanium-Mediated Direct C–OH Bond Cleavage of Benzyl Alcohol Derivatives and Its Application to C–C Bond Formation Reactions(2019/03/16)
- Low-Valent Titanium-Mediated Radical Conjugate Addition Using Benzyl Alcohols as Benzyl Radical Sources(conference：The 14th International Kyoto Conference on New Aspects of Organic Chemistry)(2018/11/12)
- Nickel-Catalyzed Reductive Cross Coupling between Benzyl Alcohols and Aryl Halides Assisted by Titanium Co-Reductant(conference：The 14th International Kyoto Conference on New Aspects of Organic Chemistry)(2018/11/12)
- Low-Valent Titanium Mediated Radical Conjugate Addition Using Benzyl Alcohol as Benzyl Radical Sources(conference：4th International Symposium on Center of Excellence for Innovative Material Sciences Based on Supramolecules)(2018/10/18)
Others
Arts and Fieldwork
Patent
Theme to the desired joint research
Grant-in-Aid for Scientific Research
○「汎用的フルベン－ベンゼン転位の実現」(2021-2023)
○「汎用的フルベン-ベンゼン転位の実現」(2021-2023)
Competitive research funding,Contribution
Collaborative research,Consignment study
Classes (Bachelors)
○Experiments in Basic Chemistry A(2018)
○Experiments in Basic Chemistry A(2017)
○Experiments in Basic Chemistry A(2017)
○Experiments in Basic Chemistry B(2017)
○Experiments in Basic Chemistry B(2016)
Classes (Graduate Schools)
○Seminar in Material Creation(2017)
○Seminar in Material Creation(2017)
○Seminar in Material Creation(2016)
○Seminar in Material Creation(2016)