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Researcher Information

last modified：2024/11/25

Associate Professor　HIROSE, Daisuke

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Faculty, Affiliation

Faculty of Chemistry, Institute of Science and Engineering
Associate Professor

College and School Educational Field

Division of Material Chemistry, Graduate School of Natural Science and Technology
Course in Applied Chemistry, School of Chemistry, College of Science and Engineering

Laboratory

Academic Background

【Degree】
Ph.D

Career

Kanazawa University　Institute of Science and Engineering, Faculty of Chemistry(2019/11-2024/10)
Kanazawa University　Institute for Frontier Science Initiative(2019/01-2019/10)
金沢大学(2017/08-2018/12)
金沢大学(2017/04-2017/07)
(2016/04-2017/03)
(2014/04-2016/03)

Year & Month of Birth

1988/10

Academic Society

THE SOCIETY OF POLYMER SCIENCE, JAPAN
THE CHEMICAL SOCIETY OF JAPAN

Award




Specialities

Polymer chemistry

Speciality Keywords

biomass,organocatalyst,helix,polymer chemistry,organic synthesis

Research Themes

Books

  • 　Daisuke Hirose,Naoki Wada,Kenji Takahashi　Biomass Conversion Process Innovated by Ionic Liquid　2020/06

Papers

  • 　Three-State Switchable Chiral Stationary Phase Based on Helicity Control of an Optically Active Poly(phenylacetylene) Derivative by Using Metal Cations in the Solid State　Hirose Daisuke,Isobe Asahi,Quinoa Emilio,Freire Felix,Maeda Katsuhiro　JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　141　21　8592　2019/05/29　
  • 　Helix-Sense-Selective Synthesis of Right- and Left-Handed Helical Luminescent Poly(diphenylacetylene)s with Memory of the Macromolecular Helicity and Their Helical Structures.　Katsuhiro Maeda,Mai Nozaki,Kengo Hashimoto,Kouhei Shimomura,Daisuke Hirose,Tatsuya Nishimura,Go Watanabe,Eiji Yashima　Journal of the American Chemical Society　142　16　7668　2020/04/22
  • 　Helical springs as a color indicator for determining chirality and enantiomeric excess　Katsuhiro Maeda,Daisuke Hirose,Mai Nozaki,Yoichi Shimizu,Taro Mori,Kentaro Yamanaka,Koji Ogino,Tatsuya Nishimura,Tsuyoshi Taniguchi,Munetsugu Moro,Eiji Yashima　SCIENCE ADVANCES　7　27　2021/06
  • 　Direct Detection of Hardly Detectable Hidden Chirality of Hydrocarbons and Deuterated Isotopomers by a Helical Polyacetylene through Chiral Amplification and Memory　Katsuhiro Maeda,Daisuke Hirose,Natsuki Okoshi,Kouhei Shimomura,Yuya Wada,Tomoyuki Ikai,Shigeyoshi Kanoh,Eiji Yashima　Journal of the American Chemical Society　140　9　3270　2018/03/07
  • 　Direct one-step synthesis of a formally fully bio-based polymer from cellulose and cinnamon flavor　Hirose Daisuke,Kusuma Samuel,Budi Wardhana,Ina Daiki,Wada Naoki,Takahashi Kenji　GREEN CHEMISTRY　21　18　4927　2019/09/21　

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  • 　Direct Synthesis of Full-Biobased Cellulose Esters from Essential Oil Component alpha,beta-Unsaturated Aldehydes　Samuel Budi Wardhana Kusuma,Daisuke Hirose,Akina Yoshizawa,Laszlo Szabo,Daiki Ina,Naoki Wada,Kenji Takahashi　ACS SUSTAINABLE CHEMISTRY & ENGINEERING　9　25　8450　2021/06
  • 　Direct Synthesis of 1,4-Diols from Alkenes by Iron-Catalyzed Aerobic Hydration and C-H Hydroxylation　Takuma Hashimoto,Daisuke Hirose,Tsuyoshi Taniguchi　ANGEWANDTE CHEMIE-INTERNATIONAL EDITION　53　10　2730　2014/03
  • 　Recyclable Mitsunobu Reagents: Catalytic Mitsunobu Reactions with an Iron Catalyst and Atmospheric Oxygen　Daisuke Hirose,Tsuyoshi Taniguchi,Hiroyuki Ishibashi　ANGEWANDTE CHEMIE-INTERNATIONAL EDITION　52　17　4613　2013
  • 　Advances and mechanistic insight on the catalytic Mitsunobu reaction using recyclable azo reagents　Daisuke Hirose,Martin Gazvoda,Janez Kosmrlj,Tsuyoshi Taniguchi　CHEMICAL SCIENCE　7　8　5148　2016
  • 　Esterification via Iron-Catalyzed Activation of Triphenylphosphine with Air　Tsuyoshi Taniguchi,Daisuke Hirose,Hiroyuki Ishibashi　ACS CATALYSIS　1　11　1469　2011/11
  • 　Continuous process of cellulose dissolution and transesterification reaction catalysed by ionic liquid in twin screw extruder　Romain Milotskyi,Gyanendra Sharma,Tetsuo Fujie,Daisuke Hirose,Naoki Wada,Kenji Takahashi　Reaction Chemistry and Engineering　8　6　1395　2023/03/23
  • 　Visualisation of helical structures of poly(diphenylacetylene)s bearing chiral amide pendants by atomic force microscopy　Ayhan Yurtsever,Sandip Das,Tatsuya Nishimura,Rafael Rodríguez,Daisuke Hirose,Kazuki Miyata,Ayumi Sumino,Takeshi Fukuma,Katsuhiro Maeda　Chemical Communications　57　92　12266　2021/11/28
  • 　Macromolecular helicity control of poly(phenyl isocyanate)s with a single stimuli-responsive chiral switch　Fukuda Mayu,Rodriguez Rafael,Fernandez Zulema,Nishimura Tatsuya,Hirose Daisuke,Watanabe Go,Quinoa Emilio,Freire Felix,Maeda Katsuhiro　CHEMICAL COMMUNICATIONS　55　55　7906　2019/07/14　
  • 　Electron beam induced strengthening of a short carbon fiber reinforced green thermoplastic composite: Key factors determining materials performance　László Szabó,Sari Imanishi,Fujie Tetsuo,Masaki Nishio,Daisuke Hirose,Takayuki Tsukegi,Kentaro Taki,Kazuaki Ninomiya,Kenji Takahashi　Composites Part A: Applied Science and Manufacturing　121　386　2019/06
  • 　Thermally stable and rewritable circularly polarized luminescent helical poly(diphenylacetylene)s: stabilization of macromolecular helicity memory via reversible ion-pair formation　Shota Sona,Daisuke Hirose,Yuki Kurihara,Katsuhiro Maeda　Journal of Materials Chemistry C　11　4　1271　2022/12/21
  • 　Ultra-fast One-Handed Helix Induction and Its Static Helicity Memory in a Poly(biphenylylacetylene) with a Catalytic Amount of Chiral Ammonium Salts　Mayu Fukuda,Mai Morikawa,Daisuke Hirose,Tsuyoshi Taniguchi,Tatsuya Nishimura,Eiji Yashima,Katsuhiro Maeda　Angewandte Chemie - International Edition　62　15　e202217020　2023/04
  • 　Helicity induction and memory of a lipophilic Brønsted acid-type poly(phenylacetylene) in non-polar solvents　Yuki Nishikawa,Daisuke Hirose,Shota Sona,Katsuhiro Maeda　Chemical Communications　59　53　8226　2023/05/19　
  • 　Dehydrogenative silylation of cellulose in ionic liquid　Daisuke Hirose,Samuel Budi Wardhana Kusuma,Akina Yoshizawa,Naoki Wada,Kenji Takahashi　Green Chemistry　25　18　7062　2023/08/18　

Conference Presentations

  • Synthesis of Rh Complexes Bearing Poly(diphenylacetylene)s with Macromolecular Helicity Memory as Chiral Ligands and Their Use as Asymmetric Catalysts(conference：Molecular Chirality 2017; ISCD-29)(2017/07)
  • Helicity Induction and Memory in a Poly(biphenylylacetylene) with Chiral Ammonium Salts and Its Chiral Amplification Behavior(conference：Molecular Chirality Asia 2018)(2018/07)
  • Esterification of Cellulose with Methyl Ester in Imidazolium-based Ionic Liquid(conference：255th ACS National Meeting & Exposition)(2018/03)
  • Direct One-step Synthesis of Fully Bio-based Polymer from Polysaccharide and Natural Aldehyde in Ionic Liquid(conference：SEMINAR NASIONAL KIMIA DAN PENDIDIKAN KIMIA 2021)(2021/10/09)
  • Development of Helical Polymer-based Chiral Materials Focused on Non-privileged Host Structure(2024/03/18)

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  • Ionic Liquid Catalyst for Polysaccharide Modification(conference：7th International Conference on CATALYSIS AND CHEMICAL ENGINEERING (CCE-2023))(2023/02/24)
  • Direct Synthesis of Fully Bio-based Polymer from Cellulose and Natural Aldehyde(conference：ICMSE 2022)(2022/10/05)

Others

Arts and Fieldwork

Patent

Theme to the desired joint research

Grant-in-Aid for Scientific Research

○「らせん高分子を用いた万能キラル可視化技術の開発と未可視キラリティへの挑戦」(2023-2025)　
○「工業的利用を見据えた触媒的光延反応の開発研究」(2014-2017)　
○「環境影響をポジティブに変える循環型オールバイオマス樹脂の高速製造技術の開発」(2022-2025)　
○「ラセン高分子鎖の伸縮に由来する運動性を示す機能性マテリアルの創製」(2021-2023)　
○「ヘリカルナノカーボン「ポリジフェニルアセチレン」の精密合成法の開発と機能の開拓」(2021-2024)　
○「ラセン高分子の記憶操作技術に基づく高感度キラルセンシング」(2019-2020)　
○「イオン液体を用いた連続的バイオマス直接変換プロセス」(2018-2021)　

Competitive research funding,Contribution

Collaborative research,Consignment study

Classes (Bachelors)

○Organic Chemistry Laboratory C(2023)
○Organic Chemistry Laboratory C(2023)
○Laboratory Course V(2022)
○Laboratory Course V(2022)
○Laboratory Course V(2022)
○Laboratory Course V(2022)
○Laboratory Course V(2021)
○Laboratory Course V(2021)
○Laboratory Course V(2020)
○[Laboratory Course V](2020)

Classes (Graduate Schools)

○Fine Synthetic Polymer Chemistry(2023)
○Fine Synthetic Polymer Chemistry(2023)
○Laboratory Rotation I(2023)
○Fine Synthetic Polymer Chemistry(2022)
○Fine Synthetic Polymer Chemistry(2022)
○Fine Synthetic Polymer Chemistry(2021)
○Fine Synthetic Polymer Chemistry(2020)

International Project

International Students

Lecture themes

Others (Social Activities)

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