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Researcher Information

last modified:2017/05/23

Professor MIZUNO Motohiro

Mail

Faculty, Affiliation

Institute for Frontier Science Initiative

College and School Educational Field

Division of Material Chemistry, Graduate School of Natural Science and Technology
Division of Material Sciences, Graduate School of Natural Science and Technology

Laboratory

Theoretical Chemistry TEL:076-264-5686 FAX:076-264-5742

Academic Background

【Academic background(Doctoral/Master's Degree)】
Nagoya University Doctor 1992
【Academic background(Bachelor's Degree)】
Nagoya University 1987

Career

Year & Month of Birth

1962/07

Academic Society



The Nuclear Magnetic Resonance Society of Japan
Japan Society for Molecular Science

Award

Specialities

Nanostructural chemistry、Basic chemistry、Polymer chemistry

Speciality Keywords

Magnetic Resonance. Solid State Physics

Research Themes

Magnetic Resonance Studies on Dynamics of Molecule and Electron in Solids

Magnetic Resonance Studies on Dynamics of Molecule and Electron in Solids The magnetic resonance technique is extremely effective for analyzing regional structure and dynamics of molucules and electrons in substances. In this study, we develop methods of measuring solid-state nuclear magnetic resonance (NMR) and a simulation program for the NMR spectrum, and analyze the dynamics of molecules and electrons linked with the functions of various functional materials.

Local Structure Analysis of High Electrical Conductive Materials

Local Structure Analysis of High Electrical Conductive Materials We investigate the local structure and dynamics of proton-conductive materials and ion-conductive materials with high electrical conductivity at high temperatures

Books

Papers

  •  Hybrid Soft Porous Architecture for Cooperative Functions N. Yanai, K. Kitayama, Y. Hijikata, H. Sato, R. Matsuda, Y. Kubota, M. Takata, M. Mizuno, T. Uemura, S. Kitagawa 10 787-793 2011/09
  •  One-Dimensional Imidazole Aggregate in Aluminum Porous Coordination Polymers with High Proton Conductivity 8 831-836 2009/09
  •  Deuterium NMR Study of Molecular Dynamics and Phase Transition in Acetonitrile Crystal Y. Suzuki, M. Sato, K. Takanohashi, T. Ida, M. Mizuno JOURNAL OF PHYSICAL CHEMISTRY A 112  13481-13486 2008/12
  •  Conformation and Molecular Dynamics of Single Polystyrene Chain Confined in Coordination T. Uemura, S. Horike, K. Kitagawa, M. Mizuno, K. Endo, S. Bracco, A. Comotti, M. Nagaoka, S. Kitagawa JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 2008/05
  •  Molecular Dynamics in Paramagnetic Materials as Studied by Magic-Angle Spinning M. Mizuno, Y. Suzuki, K. Endo, M. Murakami, M. Tansho, and T. Shimizu JOURNAL OF PHYSICAL CHEMISTRY A 111 2007/12

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  •  Dynamics of [Zn(D2O)6]2+ in [Zn(D2O)6][SiF6] Crystal as Studied by 1D, 2D Spectra and Spin-Lattice Relaxation Time of 2H NMR T. Araya, A. Niwa, M. Mizuno, K. Endo CHEMICAL PHYSICS 344  291-298 2008/03
  •  Photochromism of an Organorhodium Dithionite Complex in the Crystalline-State: Molecular Motion of Pentamethylcyclopentadienyl Ligands Coupled to Atom Rearrangement in a Dithionite Ligand H. Nakai, T. Nonaka, Y. Miyano, M. Mizuno, Y. Ozawa, K. Toriumi, N. Koga, T. Nishioka, M. Irie, K. Isobe JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 130  6781-6788 2008/12
  •  A Switchable Molecular Rotator: Neutron Spectroscopy Study on a Polymeric Spin-Crossover Compound  J. A. Rodríguez-Velamazán, M. A. González, J. A. Real, M. Castro, M. C. Muñoz, A. B. Gaspar, R. Ohtani, M. Ohba, K. Yoneda, Y. Hijikata, N. Yanai, M. Mizuno, H. Ando, S. Kitagawa JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 134 11 5083-5089 2012/02
  •  Effects of Strong Paramagnetic Interactions on Solid-State Deuterium NMR Spectra M. Mizuno, N. Itakura, K. Endo CHEMICAL PHYSICS LETTERS 416 358-363 2005
  •  Dynamical Structure of AgxCu1-xI (x=0.99-0.80) in Ionic and Superionic Phases Studied by Solid 63Cu and 127I NMR Spin-Lattice Relaxation Time Measurements PHYSICAL CHEMISTRY CHEMICAL PHYSICS 3 107-110 2001/01
  •  Water nanotubes clathrating solvent molecules stabilized by molecular 1-D nanoporous crystals M. Tadokoro, C. Iida, Y. Shimazaki, K. Isoda, Y. Suzuki, T. Sugaya, Y. Kumagai, M. Mizuno  RSC Advances 2 32 12101–12104 2012/12
  •  Differences of crystal structure and dynamics between soft porous nanocrystal and bulk crystal Y. Hijikata, S. Horike, D. Tanaka, J. Groll, M. Mizuno, J. Kim, M. Takata, S. Kitagawa CHEMICAL COMMUNICATIONS  47 7632-7634  2011/04
  •  Photoreactivity of The Crystal of a Rhodium Dithionite Complex with Ethyltetramethylcyclopentadienyl Ligands: Crystal Surface Morphology Changes and Degradation  H. Nakai, S. Uemura, Y. Miyano, M. Mizuno, M. Irie, K. Isobe 40 2177-2179 2011/01
  •  The First Example of Metallocene-like Coordination Mode of THBQ4−: A Mixed-valence Heptanucler Palladium Complex [Pd7(THBQ)2(tben)6](PF6)4  E. Asato, A. Kyan, T. Madanbashi, T. Tamura, M. Tadokoro, M. Mizuno CHEMICAL COMMUNICATIONS 46 1227-1228 2010/12
  •  Molecular-size-distribution-dependent aggregation of humic substances by Na(I), Ag(I), Ca(II), and Eu(III) S. Tamamura, R. Ohashi, S. Nagao, M. Yamamoto, M. Mizuno COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 434 9-15 2013/10
  •  Dynamic and static behaviors of CH4 and CO2 in small and large cavities of hydrate T. Ida, K. Endo, D. Matsumoto, N. Kato, M. Mizuno, Y. Suzuki, M. Tadokoro JOURNAL OF MOLECULAR STRUCTURE 1032 275–280 2013/01
  •  Molecular Dynamics of Octyl Urea Crystals Analyzed by Solid-state NMR R. Ohashi, G. Wakabayashi, M. Mizuno, T. Soeta, M. Hashimoto, K. Yamamura CHEMISTRY LETTERS 41 11 1433-1435 2012/11
  •  Immobilization of Sodium Ions on the Pore Surface of a Porous Coordination Polymer S. Horike, R. Matsuda, D. Tanaka, M. Mizuno, K. Endo, S. Kitagawa JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 128 4222-4223 2006/10
  •  Porous Coordination Polymer with π Lewis Acidic Pore Surface, D. Tanaka, S. Masaoka, S. Horike, S. Furukawa, M. Mizuno, K. Endo, S. Kitagawa ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 45 4628-4631 2006/10
  •  Dynamic Motion of Building Blocks in Porous Coordination Polymers S. Horike, R. Matsuda, D. Tanaka, S. Matsubara, M. Mizuno, K. Endo, S. Kitagawa ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 45 7226-7230 2006/10
  •  Direct Observation of Photochromic Dynamics in the Crystalline State of an Organorhodium Dithionite Complex H. Nakai, M. Mizuno, T. Nishioka, N. Koga, K. Shiomi, Y. Miyano, M. Irie, B. K. Breedlove, I. Kinoshita, Y. Hayashi, Y. Ozawa, T. Yonezawa, K. Toriumi, K. Isobe ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 45 6473-6476 2006/10
  •  Transesterification and Mechanical Properties of Blends of a Model Thermotropic Polyester and Polycarbonate C. Wu, C. D. Han, Y. Suzuki, M. Mizuno MACROMOLECULES 39 3865-3877 2006
  •  Study of Structural Phase Transitions in [Mg(H2O)6][SiF6] by Means of Single Crystal 2H NMR Zeitschrift fur Naturforschung 2002
  •  Water Molecular Motion and Hydrogen Bond in Paramagnetic [Cu(H2O)6][PtCl6] as Studied by Single Crystal 2H NMR Zeitschrift fur Naturforschung 55 178-182 2000/07
  •  Radical polymerisation of styrene in porous coordination polymers T. Uemura, K. Kitagawa, S. Horike, T. Kawamura, S. Kitagawa, M. Mizuno, K. Endo CHEMICAL COMMUNICATIONS 48 5968-5970 2005/10
  •  X-ray Photoelectron and Carbon Kα Emission Measurements and Calculations of O-, CO-, N-, and S-containing Substances S. Shimada, T. Hiroi, T. Ida, M. Mizuno, K. Endo, E. Z. Kurmaev, A. Moewes JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS 45 162-172 2007/10
  •  Electronic State of Small and Large Cavities for Methane Hydrate JOURNAL OF COMPUTATIONAL CHEMISTRY 2002
  •  Two-dimensional wavepacket dynamics with quantum hydrodynamics D. Matsumoto, K. Hayashi, T. Ida, M. Mizuno, K. Endo, K. Nishikawa INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY 107 3169-3177 2007/10
  •  Phase Transitions, Hydrogen Bond and Crystal Dynamics of p-Methylbenzyl Alcohol as Studied by Single Crystal X-ray Diffraction and 2H NMR Zeitschrift fur Naturforschung 2002
  •  Study of Odd-Even Effect of Flexible Spacer Length on the Chain Dynamics of Main-Chain Thermotropic Liquid-Crystalline Polymers Using High-Resolution Solid-State 13C Nuclear Magnetic Resonance Spectroscopy MACROMOLECULES 35 2595-2601 2002/01
  •  Structural Analysis of AgxCu1-xI (0.75≤x<1.00) in the Superionic Phase Using Solid 63Cu NMR and X-ray Diffraction Methods CHEMICAL PHYSICS LETTERS 308 390-396 1999/07
  •  Studies of Successive Phase Transitions and Molecular Motions in [Mg(H2O)6][SiF6] by 1,2H and 19F NMR Zeitschrift fur Naturforschung 53 453-458 1998/07
  •  A Study of Electron Spin Dynamics and Phase Transition in [Co(H2O)6][SiF6] by Single Crystal 19F NMR Spin-Lattice Relaxation Time Measurements PHYSICAL CHEMISTRY CHEMICAL PHYSICS 1 4561-4564 1999/12
  •  2H NMR Study of Molecular and Electron Spin Dynamics in Paramagnetic [Co(H2O)6][SiF6] Zeitschrift fur Naturforschung 55 173-177 2000/07
  •  Deuterium NMR Study of Unstable Phenomena and Water Molecular Dynamics in Samarium Nitrate Hexahydrate Crystal JOURNAL OF PHYSICAL CHEMISTRY A 103 4981-4985 1999/07
  •  1H Nuclear Magnetic Resonance and Gd2+ Electron Spin Resonance Studies of Water Molecular and Electron Spin Dynamics in Sm(NO3)36H2O JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS 60 195-199 1999/02
  •  Simulation of resonant X-ray emission spectra of ethylene and benzene molecules T. Ida, N. Kato, D. Matsumoto, M. Mizuno, K. Endo CHINESE PHYSICS LETTERS 426 53-56 2006/10
  •  Local Structure Analysis of Smoky and Colorless Topaz Using Single Crystal 27Al NMR M. Mizuno, Y. Aoki, K. Endo, D. Greenidge JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS 67 705-709 2006
  •  Dynamical Structure of Paramagnetic [M(H2O)6][SiF6] (M=Fe2+,Ni2+) Crystal Studied by Means of 2H Nuclear Magnetic Resonance Journal of Physics Condensed Matter 12 7261-7273 2000/07
  •  Dynamical Structure of α-Ag0.99Cu0.01I Crystal by 63Cu NMR Chemical Shift, Spin-Lattice Relaxation time and Molecular Dynamics Simulation JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS 63 249-256 2001/01
  •  Molecular Dynamics and Phase Transitions in Paramagnetic [Mn(H2O)6][SiF6] Investigated by 2H NMR T. Iijima, K. Hamada, M. Mizuno, K. Endo, M. Suhara JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS 66 1101-1106 2005
  •  Analysis of 13C NMR Chemical Shielding and XPS for Cellulose and Chitosan by DFT Calculations Using the Model Molecules S. Danielache, M. Mizuno, S. Shimada, K. Endo, T. Ida, K. Takaoka, E. Z. Kurmaev POLYMER JOURNAL 37 21-29 2005/10
  •  Solid 63Cu and 127I NMR Studies of Dynamical Structure in the γPhase of AgxCu1-xI (x=0.05-0.40) JOURNAL OF MOLECULAR STRUCTURE 602-603 239-244 2002/01
  •  Analysis of UV-Visible Absorption Spectra for Quartz and Topaz in Silicate Minerals by MO Calculations Using the Cluster Model Molecules H. Goto, A. Niwa, D. C. Greenidge, N. Kato, T. Ida, M. Mizuno, K. Endo, T. Tada 12 249-253 2005/10
  •  Structural Analysis of AgxCu1-xI (0.0≤x≤0.5) by Solid 63Cu NMR and X-ray Diffraction Methods JOURNAL OF MOLECULAR STRUCTURE 522 61-69 2000/07
  •  X-Ray Photoelectron and Carbon Kα Emission Spectral Analysis of Polymers by DFT Calculations Using QM/MM Method Y. Kimura, T. Hiroi, S. Shimada, M. Mizuno, K. Endo, E. Z. Kurmaev, A. Moewes 12 213-217 2005/10
  •  Conformational phase transition of deuterated p-bromobenzyl alcohol as studied M. Mizuno, M. Hamada, M. Hashimoto, M. Harada, K. Eda, K. Yamamura, T. Kamiyama, K. Oikawa POWDER DIFFRACTION 19 149-152 2004
  •  2H and 195Pt NMR Studies of Molecular and Electron spin Dynamics in Paramagnetic [Cu(H2O)6][PtCl6] Zeitschrift fur Naturforschung 53 447-452 1998/07
  •  Effect of Molecular Dynamics and Modulated Structure on 2H NMR Spectrum Studied in [Mg(H2O)6][SiF6] T. Iijima, M. Mizuno CHEMICAL PHYSICS LETTERS 380 736-741 2003
  •  Ab initio MO approach to the magnetic interactions in chain structure of A2MnF5 T. Ida, N. Kato, M. Mizuno, K. Endo SYNTHETIC METALS 133 663-664 2003/10
  •  Substitution Effects of Cp Ring Benzyl Groups on Photoisomerization of a Rhodium Y. Miyano, H. Nakai, M. Mizuno, K. Isobe CHEMISTRY LETTERS 2008/06
  •  Ab initio Calculation of Chemical Shifts of NMR Chemical Shieldings for the Ionic and the Superionic AgI JOURNAL OF MOLECULAR STRUCTURE 602-603 313-319 2002/01
  •  Fragment Distribution of Thermal Decomposition for PS and PET with QMD Calculations by Considering the Excited and Charged Model Molecules K. Endo, C. Masumoto, D. Matsumoto, T. Ida, M. Mizuno, and N. Kato APPLIED SURFACE SCIENCE 255  856-859 2008/12
  •  Analysis of Incommensurate Structure in [N(CH3)4]2ZnCl4 Crystal PHASE TRANSITIONS 72 43-55 2000/07
  •  85,87Rb and 14N NMR Studies of Successive Phase Transitions and Incommensurate Phase in R2Pb[Cu(NO2)6] (R=Rb, NH4) Zeitschrift fur Naturforschung 2002
  •  13C NMR Chemical Shifts and Visible Absorption Spectra of Unsymmetrical Fluoran dye by MO Calculations JOURNAL OF MOLECULAR STRUCTURE 602-603 381-388 2002/01
  •  Fragment Distribution of Thermal Decomposition for Lignin Monomer by QMD Calculations using the Excited and Charged Model Molecules K. Endo, D. Matsumoto, K. Kato, Y. Takagi, T. Ida, M. Mizuno, K. Saito, K. Fukushima, N. Kato APPLIED SURFACE SCIENCE 255  1048-1051 2008/12
  •  2H NMR Study on Phase Transitions and Crystal Dynamics of p-Chloro- and p-Bromobenzyl Alcohols Zeitschrift fur Naturforschung 2002
  •  Theoretical analysis of Auger electron spectra of 2nd periodic element containing substances Y. Takagi, K, Takaoka, S. Shimada, K. Endo, K. Kato,T. Ida, and M. Mizuno 14  340-343 2008/12
  •  XPS Spectral Simulation of Chitosan in Thermal Decomposition Process K. Tamura, K. Endo, Y. Takagi, K. Kato, D. Matsumoto, T. Ida, M. Mizuno, Y. Suzuki, 14  344-347 2008/12
  •  X-Ray Photoelectron Spectral Analysis for Carbon Allotropes K. Endo, D. Matsumoto,Y. Takagi, S. Shimada, T. Ida, M. Mizuno, K. Goto, H.Okamura 14  348-351 2008/12
  •  NMR Study on the Mechanisms of Freezing and Melting of Water Confined in Spherically Mesoporous Silicas SBA-16 T. Miyatou, R. Ohashi, T. Ida, S. Kittaka, M. Mizuno Phys. Chem. Chem. Phys. 18 27 18555 – 18562 2016/07/27
  •  Proton Dynamics in One-dimensional Hydrogen-bonding System in Molecular Co-crystals TMP-D2ca and DMP-H2ca T. Asaji, D. Amino, N. Tago, M. Mizuno HYPERFINE INTERACTIONS 197 269-274 2011/01
  •  2H and 13C NMR Studies of Molecular Orientation and Dynamics in Liquid Crystal 6BA Y. Suzuki, T. Uta, T. Ida, M. Mizuno, M. Murakami, M. Tansho, T. Shimizu JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS 71 389-393 2010/01
  •  Spin-adaptation of open-shell electron propagator theory CHEMICAL PHYSICS LETTERS  486 171-177 2010/10

Conference Presentations

Arts and Fieldwork

Patent

Theme to the desired joint research

Grant-in-Aid for Scientific Research

○「制限空間の水が受ける相互作用と相変化のダイナミクス」(2012-2014) 
○「固体電解質における分子ダイナミクスが関与した高プロトン伝導メカニズムの解明 」(2011-2013) 
○「固体核磁気共鳴シミュレーション解析法によるタンパク質結晶の水和構造の研究」(2007-2008) 
○「新規固体核磁気共鳴シミュレーション解析法による配位空間の研究」(2006-2007) 

Classes (Bachelors)

○Theoretical Chemistry I(2017)
○International Training A(2017)
○International Training A(2017)
○International Training A(2017)
○Experiments in Basic Chemistry C(2017)
○International Training A(2017)
○International Training B(2017)
○Magnetic Resonance(2017)
○International Training B(2017)
○International Training B(2017)
○International Training B(2017)
○Experiments in Basic Chemistry A(2017)
○Theoretical Chemistry II(2017)
○Theoretical Chemistry II(2016)
○International Training A(2016)
○International Training B(2016)
○International Training B(2016)
○International Training B(2016)
○International Training B(2016)
○International Training A(2016)
○International Training A(2016)
○International Training A(2016)
○Experiments in Basic Chemistry C(2016)
○Theoretical Chemistry I(2016)

Classes (Graduate Schools)

○Materials Physical Chemistry(2017)
○Materials Physical Chemistry(2017)
○Materials Physical Chemistry(2017)
○Seminar in Material Analysis(2017)
○Material Analysis Chemistry I(2017)
○Seminar in Material Analysis(2017)
○Quantum Chemistry(2017)
○International Presentation(2017)
○International Presentation(2017)
○Materials Physical Chemistry(2017)
○International Presentation(2017)
○Topics in Chemistry(2016)
○Seminar in Material Analysis(2016)
○Seminar in Material Analysis(2016)
○Materials Physical Chemistry(2016)
○International Presentation(2016)
○International Presentation(2016)
○International Presentation(2016)
○Quantum Chemistry(2016)
○Material Analysis Chemistry I(2016)

International Project

International Students

Lecture themes

Others (Social Activities)

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