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Researcher Information

last modified:2017/05/23

Associate Professor FURUTACHI Hideki

Mail Laboratory Website

Faculty, Affiliation

Faculty of Chemistry, Institute of Science and Engineering

College and School Educational Field

Division of Material Chemistry, Graduate School of Natural Science and Technology
Division of Material Sciences, Graduate School of Natural Science and Technology

Laboratory

coordination laboratry TEL:076-264-5703 FAX:076-264-5742

Academic Background

【Academic background(Doctoral/Master's Degree)】
Kyushu University Doctor 1998 Completed

Career

JSPS(1998/04/01-2000/10/31)
assistant prof(2000/11/01-2008/03/31)
University of Arkansas and Hawaii visiting researcher(2007/05/23-2008/03/23)

Year & Month of Birth

1971/03

Academic Society

Bulletin of Japan Society of Coordination Chemistry


Bulletin of Japan Society of Coordination Chemistry

Award

○BCSJ(2004/03/29)

Specialities

Coordination Chemistry、Inorganic chemistry

Speciality Keywords

Coordination Chemistry, Bioinorganic Chemistry

Research Themes

Model study for non-heme diiron enzymes

Model study for non-heme diiron enzymes

synthesis of metal complexes with thiolate ligands

synthesis of metal complexes with thiolate ligands

Synthetic model study of metalloenzymes

Synthetic model study of metalloenzymes

Books

Papers

  •  Polynuclear Zinc(II) Complexes of Phenol-Imine and -Amine Macrocycles J. Chem. Soc., Dalton Trans. 23 8 1995/06
  •  A Macrocyclic Co(II)Pb(II) Complex: Neighboring Pb(II) Effect upon Reversible Superoxo-cobalt Complex Formation in Solid State Chem. Lett. 11 2 1996/11
  •  Diphenoxo-bridged NiCo and CuCo Complexes of Macrocyclic Ligands: Synthesis, Structure and Electrochemical Behaviour J. Chem. Soc., Dalton Trans. 17 6 1997/09
  •  Migratory Transmetalation in Diphenoxo-Bridged CuIIMII Complexes of a Dinucleating Macrocycle with N(amine)2O2 and N(imine)2O2 Metal-Binding Sites Inorg. Chem. 36 13 7 1997/07
  •  (m-Phenoxo)2CoIIMII (M = Mn, Fe, Co) Core Complexes Having a "Co(salen)" Entity Embedded in a Macrocyclic Framework: Synthesis, Structure, and Properties Inorg. Chem. 36 18 8 1997/09

show all

  •  Dioxygen Oxidation of Coordinated Nitrosyl to Nitro on Dmf-Bridged CoPb Complex Bull. Chem. Soc. Jpn. 71 3 7 1998/02
  •  Dinuclear Nickel(II) Complexes of Phenol-Based "End-Off" Compartmental Ligands and Their Urea Adducts Relevant to the Urease Active Site Inorg. Chem. 37 5 8 1998/03
  •  Hydrolytic Function of a Hydroxo-ZnIIPbII Complex toward Tris-p-nitrophenyl Phosphate: A Functional Model of Heterobimetallic Phosphatases Chem. Lett. 3 2 1998/03
  •  Heterodinuclear Metal Complexes of Phenol-based Compartmental Macrocycles COORDINATION CHEMISTRY REVIEWS 174 51-75 1998/07
  •  Dinuclear Nickel(II) Complexes of an Unsymmetric "End-Off" Compartmental Ligand: Conversion of Urea into Cyanate at a Dinuclear Nickel Core Inorg. Chem. 37 24 7 1998/11
  •  Reversible Oxygenation of a m-Acetato-di(m-phenoxo)dicobalt(II) Core Complex and Crystal Structure of Its Oxygenated Complex Chem. Lett. 8 2 1998/08
  •  Macrocyclic Heterodinuclear ZnIIPbII Complexes: Synthesis, Structures, and Hydrolytic Function toward Tris(p-nitrophenyl) Phosphate Inorg. Chem. 37 26 7 1998/12
  •  FeIIPbII and FeIII Complexes of Macrocyclic Compartmental Ligands: Different Cyclization in Stepwise Template Synthesis Using FeII/PbII or FeIII/PbII Pairs J. Chem. Soc., Dalton Trans. 3 6 1999/02
  •  New Pyridine-modified Macrocycle and Its Ability to Encapsulate Four Divalent Metal Ions [Nickel(II), Manganese(II), and Zinc(II)] into the Ring Chem. Lett. 7 2 1999/07
  •  Oxygenation of Heterodinuclear Di(m-phenoxo)CoIIMII (M = Mn, Fe, Co) Complexes Having a "Co(salen)" Entity in a Macrocyclic Framework J. Chem. Soc., Dalton Trans. 13 7 1999/07
  •  Di(m-phenoxo)CoIIMII (M = Mn, Co, Zn) Complexes with 'Co(salen)' Entity in a Macrocyclic Framework: Core Structures and Neighboring MII Effect upon Oxygenation at the 'Co(salen)' Center Inorg. Chem. 38 18 8 1999/07
  •  A Rare m3-h1,h2 Peroxo Bridge between Two CoIIIPbII Dinuclear Units and Hydrolytic Conversion into a Hydroxo-Bridged CoIIIPbII Complex Chem. Lett. 8 2 1999/08
  •  Dinuclear CoIIMII (M = Pb, Co) Complexes Having a 'Co(salen)' Entity in a Macrocyclic Framework: Ligand Modulation Effect and Neighboring MII Effect upon Oxygenation at the 'Co(salen)' Center J. Chem. Soc., Dalton Trans. 16 9 2000/08
  •  Bis(m-oxo)(m-hydroxo)triiron(III) and (m-oxo)(m-hydroxo)diiron(III) Core Complexes with Tripodal Ligands Having a Terminal Carboxylate Group Chem. Lett. 10 2 2000/10
  •  A Heterodinuclear CoIICuI Complex with Co(salen) in a Macrocyclic Framework. Oxygenation Studies in Comparison with Analogous CuIICuI and CoIIPbII Complexes Inorg. Chem. 39 20 7 2000/08
  •  A New Mononuclear Iron(III) Complex Containing a Peroxocarbonate Ligand Angew. Chem. Int. Ed. Engl. 41 7 4 2002/04
  •  Modulation of Copper-Dioxygen Reactivity by Stereochemical Effect of Tetradentate Tripodal Ligands Chem. Lett. 3 2 2002/03
  •  Regioselective Hydroxylation of the Xylyl Linker in a Diiron(III) Complex having a Carboxylate-Rich Ligand with H2O2 CHEMICAL COMMUNICATIONS 15 1900-1901 2003/08
  •  Ligand Effect on Reversible Conversion between Copper(I) and Bis(m-oxo)Dicopper(III) Complex with a Sterically Hindered Tetradentate Tripodal Ligand and Monooxygenase Activity of Bis(m-oxo)Dicopper(III) Complex INORGANIC CHEMISTRY 42 25 8534-8544 2003/11
  •  Dioxygen Reactivity of Copper(I) Complexes with Tetradentate Tripodal Ligands Having Aliphatic Nitrogen Donors: Synthesis, Structures, and Properties of Peroxo and Superoxo Complexes BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 77 1 59-72 2004/04
  •  A Bis(m-alkylperoxo)dinickel(II) Complex as a Reaction Intermediate for the Oxidation of Methyl Groups of Me2-tpa Ligand to Carboxylate and Alkoxide Ligands ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 43 25 3300-3303 2004/06
  •  Synthesis and Reactivity of a (m-1,1-hydroperoxo)(m-hydroxo)dicopper(II) Complex: Ligand Oxidation by a Bridging Hydroperoxo Ligand JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 127 14 5212-5223 2005/04
  •  Structure and Dioxygen-reactivity of Copper(I) Complexes Supported by Bis(6-methylpyridin-2-ylmethyl)amine Tridentate Ligands T. Osako, S. Terada, T. Tosha, S. Nagatomo, H. Furutachi, S. Fujinami, T. Kitagawa, M. Suzuki, and S. Itoh Dalton Trans. 21 3514-3521 2005/09
  •  Reversible Cleavage and Reformation of a Peroxo O-O Bond in a Peroxocarbonate Group Mediated by an Iron(III) Complex H. Furutachi, K. Hashimoto, S. Nagatomo, T. Endo, S. Fujinami, Y. Watanabe, T. Kitagawa, and M. Suzuki JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 127 13 4550-4551 2005/04
  •  Structural and Spectroscopic Characterization of (m-Hydroxo or -Oxo)(m-peroxo)diiron(III) Complexes: Models for Peroxo Intermediates of Non-Heme Diiron Proteins X. Zhang, H. Furutachi, S. Fujinami, S. Nagatomo, Y. Maeda, Y. Watanabe, T. Kitagawa, and M. Suzuki JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 127 3 826-827 2005/01
  •  Mass Spectrometric and Spectroscopic Studies on Hydrolysis of Phosphoesters by Bis(m-acetato)-m-phenolato Dinuclear Metal(II) Complexes (Metal = Mn, Co, Ni, and Zn) R. Jikido, H. Shiraishi, K. Matsufuji, M. Ohba, H. Furutachi, M. Suzuki, and H. Okawa BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 78 10 1795-1803 2005/10
  •  Sequential Reaction Intermediates in Aliphatic C-H Bond Functionalization Intiated by a Bis(μ-oxo)dinicke(III) Complex J. Cho, H. Furutachi, S. Fujinami, T. Tosha, H. Ohtsu, O. Ikeda, A. Suzuki, M. Nomura, T. Uruga, H. Tanida, T. Kawai, K. Tanaka, T. Kitagawa, and M. Suzuki INORGANIC CHEMISTRY 45 7 2873-2885 2006/04
  •  Intramolecular Arene Hydroxylation versus Styrene Epoxidation by (μ-η2:η2-peroxo)dicopper(II) Complexes Supported by Dinucleating Ligands T. Matsumoto, H. Furutachi, M. Kobino, M. Tomii, S. Nagatomo, T. Tosha, T. Osako, S. Fujinami, S. Itoh, T. Kitagawa, and M. Suzuki JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 128 12 3874-3875 2006/04
  •  A Novel Mononuclear Ligand-based Alkylperoxo Copper(II) Complex as a Reaction Intermediate in the Oxidation of Methyl Groups of Supporting Ligand M. Mizuno, K. Honda, J. Cho, H. Furutachi, T. Tosha, T. Matsumoto, S. Fujinami, T. Kitagawa, and M. Suzuki ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 45 41 6911-6914 2006/10
  •  Synthesis and Reactivity of (μ-η2:η2-peroxo)dicopper(II) Complexes with Dinucleating Ligands: Hydroxylation of Xylyl Linker with a NIH Shift T. Matsumoto, H. Furutachi, S. Nagatomo, T. Tosha, S. Fujinami, T. Kitagawa, and M. Suzuki JOURNAL OF ORGANOMETALLIC CHEMISTRY 692 111-121 2007/01
  •  Regioselective Arene Hydroxylation Mediated by a (μ-Peroxo)diiron(III) Complex: A Functional Model for Toluene Monooxygenase M. Yamashita, H. Furutachi, T. Tosha, S. Fujinami, W. Saito, Y. Maeda, K. Takahashi, K. Tanaka, T. Kitagawa, and M. Suzuki JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 129 1 2-3 2007/01
  •  Active Trifluoromethylating Agents from Well-Defined Copper(I)-CF3 Complexes G. Dubinina, H. Furutachi, and D. A. Vic JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 130 27 8600-8601 2008/06
  •  Aliphatic C-H Bond Activation Initiated by a (μ-η²:η²-peroxo)dicopper(II) Complex in Comparison with Cumylperoxyl Radical T. Matsumoto, K. Ohkubo, K. Honda, A. Yazawa, H. Furutachi, S. Fujinami, S. Fukuzumi, and M. Suzuki JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 131 6 9258-9267 2009/06
  •  Oxidation Reactivity of Bis(μ-oxo) Dinickel(III) Complexes: Arene Hydroxylation of the Supporting Ligand K. Honda, J. Cho, T. Matsumoto, J. Roh, H. Furutachi, T. Tosha, M. Kubo, S. Fujinami, T. Ogura, T. Kitagawa, and M. Suzuki ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 48 18 3304-3307 2009/03
  •  A Mononuclear Peracetatoiron(III) Complex: Structural and Spectroscopic Characterization, and Oxidation Reactivity Chem. Lett. 40 4 515 2011/04
  •  Nuclear Resonance Vibrational Spectroscopy of Peroxo-bridged Biferric Complexes: Structural insight into Peroxy Intermediates of Binuclear Non-heme Iron Enzymes ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 52 4 1294-1298 2013/01
  •  Oxidation Reactivity of a Structurally and Spectroscopically Well-Defined Mononuclear Peroxocarbonato-Iron(III) Complex T. Tsugawa, H. Furutachi, M. Marunaka, T. Endo, K. Hashimoto, S. Fujinami, S. Akine, Y. Sakata, S. Nagatomo, T. Tosha, T. Nomura, T. Kitagawa, T. Ogura, and M. Suzuki Chem. Lett. 44 3 330-332 2015/03
  •  New mechanistic insight into intramolecular arene hydroxylation initiated by (μ-1,2-peroxo)diiron(III) complexes with dinucleating ligands M. Sekino, H. Furutachi, K. Tasaki, T. Ishikawa, S. Mori, S. Fujinami, S. Akine, Y. Sakata, T. Nomura, T. Ogura, T. Kitagawa, and M. Suzuki Dalton Trans. 45 469-473 2016

Conference Presentations

Arts and Fieldwork

Patent

Theme to the desired joint research

Grant-in-Aid for Scientific Research

○「二核鉄ペルオキソ錯体のコア構造による反応性の制御」(2014-2016) 
○「様々なコア構造を持つ二核鉄ペルオキソ錯体の創製および酸化特異性の解明」(2011-2013) 
○「酸素活性種を含む金属錯体の合目的創製および精密機能制御」(2006-2007) 
○「酸素活性種を含む機能性金属錯体の創製」(2004-2005) 
○「ヘテロ金属多核錯体の特異的酸素化挙動」(1998-2000) 

Classes (Bachelors)

○Freshman Seminar I(2017)
○Fundamental Chemistry 2(2017)
○Experiments in Fundamental Chemistry(2017)
○Presentation and Debate (Freshman Seminar II)(2017)
○Synthetic Inorganic Chemistry(2017)
○Earth Sciences for Education(2017)
○Biology for Education(2017)
○Practical Seminar for Teaching Profession C / Junior High School・High School(2017)
○Physics for Education(2017)
○Structural Coordination Chemistry(2017)
○Experiments in Basic Chemistry B(2017)
○Chemistry for Education(2017)
○Chemistry for Education(2017)
○Physics for Education(2017)
○Presentation and Debate (Freshman Seminar II)(2017)
○Literature Survey in Chemistry(2016)
○Structural Coordination Chemistry(2016)
○Synthetic Inorganic Chemistry(2016)
○Presentation and Debate (Freshman Seminar II)(2016)
○Chemistry for Education(2016)
○Chemistry for Education(2016)
○Experiments in Basic Chemistry B(2016)
○Biology for Education(2016)
○Earth Sciences for Education(2016)
○Research Work in Chemistry(2016)
○Physics for Education(2016)
○Fundamental Chemistry 2(2016)
○Freshman Seminar I(2016)
○Practical Seminar for Teaching Profession C / Junior High School・High School(2016)

Classes (Graduate Schools)

○Seminar in Material Analysis(2017)
○Seminar in Material Analysis(2017)
○Synthesis of Metal Complexes(2017)
○Material Creation Chemistry III(2017)
○Seminar in Chemistry II(2017)
○Seminar in Chemistry III(2017)
○Seminar in Material Creation(2017)
○Biomimetic Coordination Chemistry(2017)
○Biomimetic Coordination Chemistry(2017)
○Biomimetic Coordination Chemistry(2017)
○Biomimetic Coordination Chemistry(2017)
○Seminar in Material Analysis(2016)
○Presentation IV(2016)
○Synthesis of Metal Complexes(2016)
○Advanced Chemistry(2016)
○Presentation I(2016)
○Material Creation Chemistry III(2016)
○Presentation II(2016)
○Presentation III(2016)
○Advanced Chemistry(2016)
○Seminar in Material Creation(2016)
○Seminar in Material Creation(2016)
○Biomimetic Coordination Chemistry(2016)

International Project

International Students

Lecture themes

Others (Social Activities)

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