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last modified：2025/04/02
Associate Professor HIROSE, Daisuke
Faculty, Affiliation
Faculty of Chemistry, Institute of Science and Engineering
Associate Professor
College and School Educational Field
Division of Material Chemistry, Graduate School of Natural Science and Technology
Course in Applied Chemistry, School of Chemistry, College of Science and Engineering
Laboratory
Academic Background
【Degree】
Ph.D
Career
Kanazawa University Institute of Science and Engineering, Faculty of Chemistry(2019/11-2024/10)
Kanazawa University Institute for Frontier Science Initiative(2019/01-2019/10)
金沢大学(2017/08-2018/12)
金沢大学(2017/04-2017/07)
(2016/04-2017/03)
(2014/04-2016/03)
Year & Month of Birth
1988/10
Academic Society
THE CHEMICAL SOCIETY OF JAPAN
THE SOCIETY OF POLYMER SCIENCE, JAPAN
Award
Specialities
Polymer chemistry
Speciality Keywords
biomass,organocatalyst,helix,polymer chemistry,organic synthesis
Research Themes
Books
- Daisuke Hirose,Naoki Wada,Kenji Takahashi Biomass Conversion Process Innovated by Ionic Liquid 2020/06
Papers
- Three-State Switchable Chiral Stationary Phase Based on Helicity Control of an Optically Active Poly(phenylacetylene) Derivative by Using Metal Cations in the Solid State Hirose Daisuke,Isobe Asahi,Quinoa Emilio,Freire Felix,Maeda Katsuhiro JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 141 21 8592 2019/05/29
- Helix-Sense-Selective Synthesis of Right- and Left-Handed Helical Luminescent Poly(diphenylacetylene)s with Memory of the Macromolecular Helicity and Their Helical Structures. Katsuhiro Maeda,Mai Nozaki,Kengo Hashimoto,Kouhei Shimomura,Daisuke Hirose,Tatsuya Nishimura,Go Watanabe,Eiji Yashima Journal of the American Chemical Society 142 16 7668 2020/04/22
- Helical springs as a color indicator for determining chirality and enantiomeric excess Katsuhiro Maeda,Daisuke Hirose,Mai Nozaki,Yoichi Shimizu,Taro Mori,Kentaro Yamanaka,Koji Ogino,Tatsuya Nishimura,Tsuyoshi Taniguchi,Munetsugu Moro,Eiji Yashima SCIENCE ADVANCES 7 27 2021/06
- Direct Detection of Hardly Detectable Hidden Chirality of Hydrocarbons and Deuterated Isotopomers by a Helical Polyacetylene through Chiral Amplification and Memory Katsuhiro Maeda,Daisuke Hirose,Natsuki Okoshi,Kouhei Shimomura,Yuya Wada,Tomoyuki Ikai,Shigeyoshi Kanoh,Eiji Yashima Journal of the American Chemical Society 140 9 3270 2018/03/07
- Direct one-step synthesis of a formally fully bio-based polymer from cellulose and cinnamon flavor Hirose Daisuke,Kusuma Samuel,Budi Wardhana,Ina Daiki,Wada Naoki,Takahashi Kenji GREEN CHEMISTRY 21 18 4927 2019/09/21
- Direct Synthesis of Full-Biobased Cellulose Esters from Essential Oil Component alpha,beta-Unsaturated Aldehydes Samuel Budi Wardhana Kusuma,Daisuke Hirose,Akina Yoshizawa,Laszlo Szabo,Daiki Ina,Naoki Wada,Kenji Takahashi ACS SUSTAINABLE CHEMISTRY & ENGINEERING 9 25 8450 2021/06
- Advances and mechanistic insight on the catalytic Mitsunobu reaction using recyclable azo reagents Daisuke Hirose,Martin Gazvoda,Janez Kosmrlj,Tsuyoshi Taniguchi CHEMICAL SCIENCE 7 8 5148 2016
- Esterification via Iron-Catalyzed Activation of Triphenylphosphine with Air Tsuyoshi Taniguchi,Daisuke Hirose,Hiroyuki Ishibashi ACS CATALYSIS 1 11 1469 2011/11
- Direct Synthesis of 1,4-Diols from Alkenes by Iron-Catalyzed Aerobic Hydration and C-H Hydroxylation Takuma Hashimoto,Daisuke Hirose,Tsuyoshi Taniguchi ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 53 10 2730 2014/03
- Recyclable Mitsunobu Reagents: Catalytic Mitsunobu Reactions with an Iron Catalyst and Atmospheric Oxygen Daisuke Hirose,Tsuyoshi Taniguchi,Hiroyuki Ishibashi ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 52 17 4613 2013
- Dehydrogenative silylation of cellulose in ionic liquid Daisuke Hirose,Samuel Budi Wardhana Kusuma,Akina Yoshizawa,Naoki Wada,Kenji Takahashi Green Chemistry 25 18 7062 2023/08/18
- Thermally stable and rewritable circularly polarized luminescent helical poly(diphenylacetylene)s: stabilization of macromolecular helicity memory via reversible ion-pair formation Shota Sona,Daisuke Hirose,Yuki Kurihara,Katsuhiro Maeda Journal of Materials Chemistry C 11 4 1271 2022/12/21
- Macromolecular helicity control of poly(phenyl isocyanate)s with a single stimuli-responsive chiral switch Fukuda Mayu,Rodriguez Rafael,Fernandez Zulema,Nishimura Tatsuya,Hirose Daisuke,Watanabe Go,Quinoa Emilio,Freire Felix,Maeda Katsuhiro CHEMICAL COMMUNICATIONS 55 55 7906 2019/07/14
- Continuous process of cellulose dissolution and transesterification reaction catalysed by ionic liquid in twin screw extruder Romain Milotskyi,Gyanendra Sharma,Tetsuo Fujie,Daisuke Hirose,Naoki Wada,Kenji Takahashi Reaction Chemistry and Engineering 8 6 1395 2023/03/23
- Electron beam induced strengthening of a short carbon fiber reinforced green thermoplastic composite: Key factors determining materials performance László Szabó,Sari Imanishi,Fujie Tetsuo,Masaki Nishio,Daisuke Hirose,Takayuki Tsukegi,Kentaro Taki,Kazuaki Ninomiya,Kenji Takahashi Composites Part A: Applied Science and Manufacturing 121 386 2019/06
- Ultra-fast One-Handed Helix Induction and Its Static Helicity Memory in a Poly(biphenylylacetylene) with a Catalytic Amount of Chiral Ammonium Salts Mayu Fukuda,Mai Morikawa,Daisuke Hirose,Tsuyoshi Taniguchi,Tatsuya Nishimura,Eiji Yashima,Katsuhiro Maeda Angewandte Chemie - International Edition 62 15 e202217020 2023/04
- Visualisation of helical structures of poly(diphenylacetylene)s bearing chiral amide pendants by atomic force microscopy Ayhan Yurtsever,Sandip Das,Tatsuya Nishimura,Rafael Rodríguez,Daisuke Hirose,Kazuki Miyata,Ayumi Sumino,Takeshi Fukuma,Katsuhiro Maeda Chemical Communications 57 92 12266 2021/11/28
- Helicity induction and memory of a lipophilic Brønsted acid-type poly(phenylacetylene) in non-polar solvents Yuki Nishikawa,Daisuke Hirose,Shota Sona,Katsuhiro Maeda Chemical Communications 59 53 8226 2023/05/19
- Fully bio-based cellulose ester synthesis from natural aldehydes via aerobic oxidation Daisuke Hirose,Daiki Ina,Akina Yoshizawa,Samuel Budi Wardhana Kusuma,Masaki Nishio,Naoki Wada,Kenji Takahashi Chemical Communications 61 17 3484 2025/02
Conference Presentations
- Development of Helical Polymer-based Chiral Materials Focused on Non-privileged Host Structure(2024/03/18)
- Direct One-step Synthesis of Fully Bio-based Polymer from Polysaccharide and Natural Aldehyde in Ionic Liquid(conference：SEMINAR NASIONAL KIMIA DAN PENDIDIKAN KIMIA 2021)(2021/10/09)
- Esterification of Cellulose with Methyl Ester in Imidazolium-based Ionic Liquid(conference：255th ACS National Meeting & Exposition)(2018/03)
- Ionic Liquid Catalyst for Polysaccharide Modification(conference：7th International Conference on CATALYSIS AND CHEMICAL ENGINEERING (CCE-2023))(2023/02/24)
- Direct Synthesis of Fully Bio-based Polymer from Cellulose and Natural Aldehyde(conference：ICMSE 2022)(2022/10/05)
- Synthesis of Rh Complexes Bearing Poly(diphenylacetylene)s with Macromolecular Helicity Memory as Chiral Ligands and Their Use as Asymmetric Catalysts(conference：Molecular Chirality 2017; ISCD-29)(2017/07)
- Helicity Induction and Memory in a Poly(biphenylylacetylene) with Chiral Ammonium Salts and Its Chiral Amplification Behavior(conference：Molecular Chirality Asia 2018)(2018/07)
Others
Arts and Fieldwork
Patent
Theme to the desired joint research
Grant-in-Aid for Scientific Research
○「らせん高分子を用いた万能キラル可視化技術の開発と未可視キラリティへの挑戦」(2023-2025)
○「工業的利用を見据えた触媒的光延反応の開発研究」(2014-2017)
○「環境影響をポジティブに変える循環型オールバイオマス樹脂の高速製造技術の開発」(2022-2025)
○「ラセン高分子鎖の伸縮に由来する運動性を示す機能性マテリアルの創製」(2021-2023)
○「ヘリカルナノカーボン「ポリジフェニルアセチレン」の精密合成法の開発と機能の開拓」(2021-2024)
○「ラセン高分子の記憶操作技術に基づく高感度キラルセンシング」(2019-2020)
○「イオン液体を用いた連続的バイオマス直接変換プロセス」(2018-2021)
Competitive research funding,Contribution
Collaborative research,Consignment study
Classes (Bachelors)
○Organic Chemistry Laboratory C(2023)
○Organic Chemistry Laboratory C(2023)
○Laboratory Course V(2022)
○Laboratory Course V(2022)
○Laboratory Course V(2022)
○Laboratory Course V(2022)
○Laboratory Course V(2021)
○Laboratory Course V(2021)
○Laboratory Course V(2020)
○[Laboratory Course V](2020)
Classes (Graduate Schools)
○Fine Synthetic Polymer Chemistry(2023)
○Fine Synthetic Polymer Chemistry(2023)
○Laboratory Rotation I(2023)
○Fine Synthetic Polymer Chemistry(2022)
○Fine Synthetic Polymer Chemistry(2022)
○Fine Synthetic Polymer Chemistry(2021)
○Fine Synthetic Polymer Chemistry(2020)