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Researcher Information

last modified:2018/04/13

Professor AKINE, Shigehisa

Laboratory Website

Faculty, Affiliation

WPI Nano Life Science Institute

College and School Educational Field

Division of Material Chemistry, Graduate School of Natural Science and Technology
Division of Material Sciences, Graduate School of Natural Science and Technology

Laboratory

Coordination Chemistry Laboratory TEL:076-264-5701 FAX:076-264-5742

Academic Background

【Academic background(Doctoral/Master's Degree)】
The University of Tokyo Master Department of Chemistry 199703 Completed
The University of Tokyo Doctor Department of Chemistry 200003 Completed
【Academic background(Bachelor's Degree)】
The University of Tokyo Department of Chemistry 199503
【Degree】
PhD in Science

Career

University of Tsukuba Department of Chemistry Research Associate(2000/04/01-2004/03/31)
University of Tsukuba Grad School of Pure and Applied Sciences Research Associate(2004/04/01-2004/09/30)
University of Tsukuba Grad School of Pure and Applied Sciences Assistant Professor(2004/10/01-2008/03/31)
University of Tsukuba Grad School of Pure and Applied Sciences Associate Professor(2008/04/01-2011/09/30)
University of Tsukuba Faculty of Pure and Applied Sciences Associate Professor(2011/10/01-2013/09/30)
Kanazawa University Department of Material Chemistry Professor(2013/10/01-2017/10/05)
Kanazawa University Nano Life Science Institute Professor(2017/10/06-)

Year & Month of Birth

1972/06

Academic Society


Japan Society of Coordination Chemistry


Japan Society of Coordination Chemistry


Award



○HGCS Japan Award of Excellence 2010(2011/02/21)

Specialities

Inorganic chemistry、Organic chemistry

Speciality Keywords

Coordination Chemistry, Supramolecular Chemistry, Structural Organic Chemistry

Research Themes

- Development of dynamic structural conversion systems based on metal complexes - Synthesis of dynamic chiral complexes and the chirality inversion - Synthesis of metal-containing host molecules for new supramolecular structures

One of the important features of metal complexes is reversibility of metal-ligand coordination bonds. This enables the spontaneous formation of supramolecular structures and the dynamic conversions in response to external stimuli. In order to make and convert large-sized supramolecular structures in a desired fashion, it is important to place appropriate metal ions and organic ligand moieties in a suitable arrangement. Therefore, we need to select suitable metal ions and need to finely design organic molecules with appropriate ligating moieties.
Our group aims to develop novel dynamic functional metal complexes and responsive supramolecules by utilizing dynamic feature of metal ions and fine design of organic frameworks.

Books

  •  Akine, S. The Chemistry of Metal Phenolates, Volume 2 John Wiley and Sons Ltd 2018

Papers

  •  Separation of Linear and Branched Alkanes Using Host–Guest Complexation of Cyclic and Branched Alkane Vapors by Crystal State Pillar[6]arene Ogoshi, T.; Saito, K.; Sueto, R.; Kojima, R.; Hamada, Y.; Akine, S.; Moeljadi, A. M. P.; Hirao, H.; Kakuta, T.; Yamagishi, T.-a. Angew. Chem. Int. Ed.  57 6 1592-1595 2018
  •  Response speed control of helicity inversion based on a “regulatory enzyme”-like strategy Sairenji, S.; Akine, S.; Nabeshima, T.  Sci. Rep.  8 137 2018
  •  New mechanistic insights into intramolecular aromatic ligand hydroxylation and benzyl alcohol oxidation initiated by the well-defined (µ-peroxo)diiron(III) complex Sekino, M.; Furutachi, H.; Tojo, R.; Hishi, A.; Kajikawa, H.; Suzuki, T.; Suzuki, K.; Fujinami, S.; Akine, S.; Sakata, Y.; Ohta, T.; Hayami, S.; Suzuki, M. Chem. Commun.  53 63 8838-8841 2017
  •  Alkane-length sorting using activated pillar[5]arene crystals Ogoshi, T.; Sueto, R.; Hamada, Y.; Doitomi, K.; Hirao, H.; Sakata, Y.; Akine, S.; Kakuta, T.; Yamagishi, T. Chem. Commun. 53 61 8577-8580 2017
  •  Anion-capped metallohost allows extremely slow guest uptake and on-demand acceleration of guest exchange Sakata, Y.; Murata, C.; Akine, S. Nat. Commun. 8 16005 2017

show all

  •  Two-step modulation of ion recognition using a bis(saloph)-macrocyclic host having a 24-crown-8-like cavity Sakata, Y.; Kobayashi, S.; Akine, S. Chem. Commun.  53 47 6363-6366 2017
  •  Alkane-Shape-Selective Vapochromic Behavior Based on Crystal-State Host–Guest Complexation of Pillar[5]arene Containing One Benzoquinone Unit Ogoshi, T.; Shimada, Y.; Sakata, Y.; Akine, S.; Yamagishi, T. J. Am. Chem. Soc. 139 16 5664-5667 2017
  •  A Metallo-molecular Cage That Can Close the Apertures with Coordination Bonds Akine, S.; Miyashita, M.; Nabeshima, T. J. Am. Chem. Soc. 139 13 4631-4634 2017
  •  Electronic perturbation of supramolecular conjugates of porphyrins and phthalocyanines Mihara, N.; Yamada, Y.; Akine, S.; Sugimoto, K.; Tanaka, K. Chem. Commun. 53 14 2230 2017
  •  Perfect encapsulation of guanidinium ion in a helical trinickel(II) metallocryptand for efficient regulation of helix inversion rate Akine, S.; Miyashita, M.; Piao, S.; Nabeshima, T. Inorg. Chem. Front. 1 1 53 2014
  •  Dynamic helicity control of single-helical oligooxime metal complexes by coordination of chiral carboxylate ions Sairenji, S.; Akine, S.; Nabeshima, T. Tetrahedron Lett. 55 12 1987 2014
  •  Dynamic helicity control of a single-helical oligooxime complex and acid-base triggered repeated helicity inversion mediated by amino acids Sairenji, S.; Akine, S.; Nabeshima, T. Chem. Lett. 43 7 1107 2014
  •  Increased Nuclearity of Saleln-Type Transition Metal Complexes by Incorporation of O-Alkyloxime Functionality Akine, S.; Nabeshima, T. Heteroatom Chem. 25 5 410 2014
  •  Oxidation Reactivity of a Structurally and Spectroscopically Well-Defined Mononuclear Peroxocarbonato-Iron(III) Complex Tsugawa, T.; Furutachi, H.; Marunaka, M.; Endo, T.; Hashimoto, K.; Fujinami, S.; Akine, S.; Sakata, Y.; Nagatomo, S.; Tosha, T.; Nomura, T.; Kitagawa, T.; Ogura, T.; Suzuki, M. Chem. Lett. 44 3 330 2015
  •  Host–Guest Complexation of Perethylated Pillar[5]arene with Alkanes in the Crystal State Ogoshi, T.; Sueto, R.; Yoshikoshi, K. Sakata, Y.; Akine, S.; Yamagishi, T. Angew. Chem. Int. Ed.  54 34 9849 2015
  •  Synthesis of tetrafunctionalized pentiptycenequinones for construction of cyclic dimers with a cylindrical shape by boronate ester formation Akine, S.; Kusama, D.; Takatsuki, Y.; Nabeshima, T. Tetrahedron Lett.  56 34 4880 2015
  •  Overcoming Statistical Complexity: Selective Coordination of Three Different Metal Ions to a Ligand with Three Different Coordination Sites Akine, S.; Matsumoto, T.; Nabeshima, T. Angew. Chem. Int. Ed. 55 3 960 2016
  •  π-Electron Systems That Form Planar and Interlocked Anion Complexes and Their Ion-Pairing Assemblies Yamakado, R.; Sakurai, T.; Matsuda, W.; Seki, S.; Yasuda, N.; Akine, S.; Maeda, H. Chem. Eur. J. 22 2 626 2016
  •  Solvent-Dependent Dual-Mode Photochromism between T- and P-Types in a Dipyrrinone Derivative Sakata, Y.; Fukushima, S.; Akine, S.; Setsune, J.-i. Chem. Commun.  52 6 1278 2016
  •  New mechanistic insight into intramolecular arene hydroxylation initiated by (μ-1,2-peroxo)diiron(III) complexes with dinucleating ligands Sekino, M.; Furutachi, H.; Tasaki, K.; Ishikawa, T.; Mori, S.; Fujinami, S.; Akine, S.; Sakata, Y.; Nomura, T.; Ogura, T.; Kitagawa, T.; Suzuki, M. Dalton Trans. 45 2 469 2016
  •  Synthesis, Ion Recognition Ability, and Metal-Assisted Aggregation Behavior of Dinuclear Metallohosts Having a Bis(Saloph) Macrocyclic Ligand Akine, S.; Utsuno, F.; Piao, S.; Orita, H.; Tsuzuki, S.; Nabeshima, T. Inorg. Chem. 55 2 810 2016
  •  Kinetically “locked” metallomacrocycle  Nishino, T.; Yamada, Y.; Akine, S.; Sugimoto K.; Tanaka, K. Dalton Trans. 45 9 3831 2016
  •  Multistep helicity inversion of helical metal complexes Shigehisa Akine Chemistry and Chemical Industry 68 1 25 2015
  •  Lanthanide contraction for helicity fine-tuning and helix-winding control of single-helical metal complexes  Sairenji, S.; Akine, S.; Nabeshima, T. Dalton Trans. 45 38 14902 2016
  •  A Molecular Leverage for Helicity Control and Helix Inversion Akine, S.; Hotate, S.; Nabeshima, T. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 133 35 13868 2011/09
  •  Synthesis of Planar Metal Complexes and the Stacking Abilities of Naphthalenediol-Based Acyclic and Macrocyclic Salen-Type Ligands Akine, S.; Varadi, Z.; Nabeshima, T. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2013 35 5987 2013/12
  •  Spontaneous Enrichment of One-handed Helices by Dissolution of Quasiracemic Crystals of a Tetranuclear Single Helical Complex Akine, S.; Hotate, S.; Matsumoto, T.; Nabeshima, T. CHEMICAL COMMUNICATIONS 47 10 2925 2011/03
  •  Synthesis of Acyclic Tetrakis- and Pentakis(N2O2) Ligands for Single-helical Heterometallic Complexes with a Greater Number of Winding Turns Akine, S.; Matsumoto, T.; Sairenji, S.; Nabeshima, T. SUPRAMOLECULAR CHEMISTRY 23 1-2 106 2011/02
  •  Wheel-Shaped ErIIIZnII3 Single-Molecule Magnet: A Macrocyclic Approach to Designing Magnetic Anisotropy Yamashita, A.; Watanabe, A.; Akine, S.; Nabeshima, T.; Nakano, M.; Yamamura, T.; Kajiwara, T. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 50 17 4016 2011/04
  •  Multistep Oligometal Complexation of the Macrocyclic Tris(N2O2) Hexaoxime Ligand Akine, S.; Sunaga, S.; Nabeshima, T. CHEMISTRY-A EUROPEAN JOURNAL 17 24 6853 2011/06
  •  Nuclearity Control of a Trisaloph Zinc Cluster Complex Dependent on Minute Structural Differences in the Bridging Anions Yamamura, M.; Miyazaki, H.; Iida, M.; Akine, S.; Nabeshima, T. INORGANIC CHEMISTRY 50 12 5315 2011/06
  •  Highly Cooperative Double Metalation of a Bis(N2O2) Ligand Based on Bipyridine-Phenol Framework Driven by Intramolecular π-Stacking of Square Planar Nickel(II) Complex Moieties Akine, S.; Shimada, T.; Nagumo, H.; Nabeshima, T. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS 40 34 8507 2011/09
  •  Remarkably Selective Recognition of Iodobenzene Derivatives by a Macrocyclic Bis-PtII Metallohost Trokowski, R.; Akine, S.; Nabeshima, T. CHEMISTRY-A EUROPEAN JOURNAL 17 51 14420 2011/12
  •  Design and controlled emission properties of bioorganometallic compounds composed of uracils and organoplatinum(II) moieties Moriuchi, T.; Sakamoto, Y.; Noguchi, S.; Fujiwara, T.; Akine, S.; Nabeshima, T.; Hirao, T. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS 41 28 8524 2012/07
  •  Hierarchical Helix of Helix in the Crystal: Formation of Variable-Pitch Helical π-Stacked Array of Single-Helical Dinuclear Metal Complexes Akine, S.; Nagumo, H.; Nabeshima, T. INORGANIC CHEMISTRY 51 10 5506 2012/05
  •  Oligometallic Template Strategy for Synthesis of a Macrocyclic Dimer-Type Octaoxime Ligand for Its Cooperative Complexation Akine, S.; Tadokoro, T.; Nabeshima, T. INORGANIC CHEMISTRY 51 21 11478 2012/11
  •  Conformational control of electron-rich calix[6]arene skeleton by paraquat recognition Akine, S.; Kusama, D.; Nabeshima, T. TETRAHEDRON LETTERS 54 3 205 2013/01
  •  Ligand Modification of Cyclometalated Ruthenium Complexes in the Aerobic Oxidative Dehydrogenation of Imidazolines Aiki, S.; Kijima, Y.; Kuwabara, J.; Taketoshi, A.; Koizumi, T.; Akine, S.; Kanbara, T. ACS Catal. 3 5 812 2013/05
  •  Programmed multiple complexation for the creation of helical structures from acyclic phenol–bipyridine oligomer ligands Akine, S.; Nagumo, H.; Nabeshima, T. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS 42 45 15974 2013/12
  •  Stepwise Helicity Inversions by Multisequential Metal Exchange Akine, S.; Sairenji, S.; Taniguchi, T.; Nabeshima, T. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 135 35 12948 2013/09
  •  Cage-like tris(salen)-type metallocryptand for cooperative guest recognition Akine, S.; Piao, S.; Miyashita, M.; Nabeshima, T.  TETRAHEDRON LETTERS 54 48 6541 2013/11

Conference Presentations

  • Metallonanobelt: A Sufficiently Inert Shape-Persistent Molecular Belt Prepared by Reversible Self-Assembly Processes(conference:The 1st NanoLSI International Symposium - Towards Establishment of New Research Field: Nanoprobe Life Science-)(2018/02/21)
  • Open/close functions of host molecules based on coordination structures(conference:The 1st NanoLSI International Symposium - Towards Establishment of New Research Field: Nanoprobe Life Science-)(2018/02/21)
  • Metal-containing host molecules that can close their apertures(conference:Strasbourg-Kanazawa Universities Joint Symposium on Organic Synthesis)(2018/02/08)
  • Metal-containing Cage Compounds that can Close their Apertures(conference:Japan-Canada Mini Symposium on Supramolecular Science)(2018/01/08)
  • Metallocages and metallomacrocycles that can close their apertures(conference:Mini-symposium on innovative materials based on supramolecules)(2017/11/23)

show all

  • Metallocages and metallomacrocycles with Open/Close Features(conference:Kanazawa Supramolecular Symposium in Southampton)(2017/11/20)
  • Metalloreceptors with Open/Close Features(conference:3rd International Symposium on Center of Excellence for Innovative Material Sciences Based on Supramolecules)(2017/10/17)
  • Selective Formation of a Belt-shaped Metallomacrocycle by Template-directed Self-assembly of a Triptycene Based Ligand(conference:3rd International Symposium on Center of Excellence for Innovative Material Sciences Based on Supramolecules)(2017/10/16)
  • Unusual Helicity Inversion of Helical Cobalt(III) Metallocryptands by Multistep Ligand Exchange(conference:3rd International Symposium on Center of Excellence for Innovative Material Sciences Based on Supramolecules)(2017/10/16)
  • Selective Formation of Various Kinds of Stacking Structures by Metal Ion Recognition of Dinuclear Metallohosts(conference:3rd International Symposium on Center of Excellence for Innovative Material Sciences Based on Supramolecules)(2017/10/16)
  • Design and synthesis of cobalt(III)-based metallohosts for controlled guest recognition(conference:11th Japan-China Joint Symposium on Metal Cluster Compounds)(2017/10/09)
  • Design and synthesis of oligo(salen)-type complexes for function switching(conference:67th JSCC Symposium)(2017/09/16)
  • Control of Helicity and Helix Inversion Rates of Dynamic Helical Metal Complexes(conference:International Symposium on Pure and Applied Chemistry 2017 (ISPAC 2017))(2017/06/10)
  • Formation of Various Kinds of Stacking Structures Using 18-Crown-6 Type Metallohosts Having Different Bridging Scaffold(conference:2nd International Symposium on Center of Excellence for Innovative Material Sciences Based on Supramolecules)(2016/10/26)
  • Construction of Solvent Dependent Dynamic Rotaxane Using 24-crown-8 type Metallohost(conference:2nd International Symposium on Center of Excellence for Innovative Material Sciences Based on Supramolecules)(2016/10/26)
  • Control of Guest Recognition Ability of Cobalt(III) Metallohost by Site-selective Ligand Exchange(conference:2nd International Symposium on Center of Excellence for Innovative Material Sciences Based on Supramolecules)(2016/10/26)
  • Dynamic helicity control of helical tetranuclear complexes by chemical stimuli(conference:42nd International Conference on Coordination Chemistry)(2016/07/07)
  • Dynamic Structural Conversion of helical oligosalen complexes(conference:Mini-symposium "Innovative Material Science Based on Supramolecules")(2016/01/19)
  • Multi-step Helicity Inversion of Helical Multinuclear Complex by Stepwise Metal Exchange(conference:International Symposium on Coordination Programming (ISCP2014))(2014/01/20)
  • Formation of Pentacenequinone Dimer by Sandwich Complexation with Alkali Metal Ion(conference:CENIDE-CNMM-TIMS Joint Symposium on Interdisciplinary Nano-Science and Technology)(2014/01/06)
  • Development of a rational strategy for helicity inversion of helical metal complexes(conference:4th Asian Conference on Coordination Chemistry)(2013/11/04)
  • Multi-step helicity inversion of helical oligooxime complex by exchange of constituent metal ions(conference:4th Tetrahedron Symposium-Asian Edition)(2013/10/21)
  • Stepwise Helicity Inversion of Helical Complex by Exchange of Constituent Metal Ions(conference:The 3rd German-Japan Nanoworkshop ~ Energy Conversion and Storage ~)(2013/09/03)
  • Anion-Triggered Guest Exchange in a Cationic Metallohost(conference:The First International Symposium on Center of Excellence for Innovative Material Sciences Based on Supramolecules)(2016/03/10)
  • Development of New Metallo-Macrocycles Using a Rigid Bent Ligand Based on a Triptycene Scaffold(conference:The First International Symposium on Center of Excellence for Innovative Material Sciences Based on Supramolecules)(2016/03/10)
  • Site-selective Post-modification of Macrocyclic Cobalt(III) Dinuclear Metallohost(conference:The First International Symposium on Center of Excellence for Innovative Material Sciences Based on Supramolecules)(2016/03/10)
  • Cation Recognition Behavior of a New Macrocyclic Dinuclear Nickel(II) Metallohost Having a 24-crown-8-like Scaffold(conference:The First International Symposium on Center of Excellence for Innovative Material Sciences Based on Supramolecules)(2016/03/10)
  • Helix Inversion of Helical Multinuclear Complexes Controlled by Molecular Recognition(conference:The 9th Japan-China Joint Symposium on Functional Supramolecular Architectures)(2016/02/23)
  • Dynamic Structural Conversion of Oligo(salen) Metal Complexes(conference:Japan-Canada Symposium for International Exchange Initiative)(2016/01/08)
  • Synthesis of a helical trinickel(II) metallo-cryptand and regulation of its helix inversion rate by guest recognition(conference:International Chemical Congress of Pacific Basin Societies)(2015/12/08)
  • 日本化学会近畿支部 平成27年度北陸地区講演会と研究発表会(2015/11/27)
  • Control of helix inversion of helical multinuclear complexes by molecular recognition(2014/09/18)
  • A Helical Trinickel(II) Metallo-cryptand for Efficient Regulation of the Helix Inversion Rate(conference:41st International Conference on Coordination Chemistry)(2014/07/21)

Arts and Fieldwork

Patent

Theme to the desired joint research

Grant-in-Aid for Scientific Research

○「円筒型配位子の配位プログラミングによる新規な物質移動および制御システムの開発」(2012-2013) 
○「配位キラリティーの動的変換とタイムプロファイル制御」(2016-2020) 
○「開閉機構をもつ新規なカゴ型錯体の合成と応答型物質捕捉・放出制御への応用」(2014-2017) 
○「多環芳香族パネリングによるπ電子系多面体の合成と新規巨大フラーレンの探索」(2015-2016) 
○「ジグザグ型カーボンナノチューブ部分構造としての環状アセンキノンの合成とその連結」(2013-2014)

Classes (Bachelors)

○Inorganic Chemistry III(2017)
○Experiments in Basic Chemistry B(2017)
○Inorganic Chemistry I(2017)
○Structural Coordination Chemistry(2017)
○Inorganic Chemistry I(2016)
○Fundamental Chemistry 2(2016)
○Inorganic Chemistry III(2016)
○Structural Coordination Chemistry(2016)
○Experiments in Basic Chemistry B(2016)

Classes (Graduate Schools)

○Advanced Coordination Chemistry(2017)
○Synthesis of Metal Complexes(2017)
○Seminar in Material Creation(2017)
○Material Creation Chemistry III(2017)
○Seminar in Material Creation(2017)
○Advanced Coordination Chemistry(2017)
○Advanced Coordination Chemistry(2017)
○Advanced Coordination Chemistry(2017)
○Material Creation Chemistry III(2016)
○Synthesis of Metal Complexes(2016)
○Seminar in Material Creation(2016)
○Seminar in Material Creation(2016)
○Advanced Coordination Chemistry(2016)

International Project

International Students

Lecture themes

Others (Social Activities)

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